Enhanced Electromagnetic Coupling in the Walnut-Shaped Nanostructure Array

It is a challenging yet valuable work to prepare a surface-enhanced Raman scattering (SERS) substrate with low cost and high performance by simple methods. In this study, the Ag nanoparticles were sputtered on PS spheres by the magnetron sputtering, which was used as the mask to create the nanostruc...

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Main Authors: Deyuan Mao, Xiaoyu Zhao, Jiahong Wen, Aofang Wang, Renxian Gao, Yaxin Wang
Format: Article
Language:English
Published: MDPI AG 2022-10-01
Series:Chemosensors
Subjects:
Online Access:https://www.mdpi.com/2227-9040/10/11/445
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author Deyuan Mao
Xiaoyu Zhao
Jiahong Wen
Aofang Wang
Renxian Gao
Yaxin Wang
author_facet Deyuan Mao
Xiaoyu Zhao
Jiahong Wen
Aofang Wang
Renxian Gao
Yaxin Wang
author_sort Deyuan Mao
collection DOAJ
description It is a challenging yet valuable work to prepare a surface-enhanced Raman scattering (SERS) substrate with low cost and high performance by simple methods. In this study, the Ag nanoparticles were sputtered on PS spheres by the magnetron sputtering, which was used as the mask to create the nanostructures by etching the spheres. Because of the heating effect in the etching process, the Ag nanoparticles gathered on the surfaces of PS spheres when the etching time was 60 s. Strong electromagnetic coupling was observed between the gathered Ag nanoparticles as confirmed by FDTD simulation and SERS signals from the probe molecule 4-mercaptobenzoic acid. This structure showed the detection limit for thiram down to 10<sup>−8</sup> M.
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spelling doaj.art-8a8e8707b148467bb2a5e9adffd9278e2023-11-24T04:10:20ZengMDPI AGChemosensors2227-90402022-10-01101144510.3390/chemosensors10110445Enhanced Electromagnetic Coupling in the Walnut-Shaped Nanostructure ArrayDeyuan Mao0Xiaoyu Zhao1Jiahong Wen2Aofang Wang3Renxian Gao4Yaxin Wang5School of Material and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, ChinaSchool of Material and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, ChinaThe College of Electronics and Information, Hangzhou Dianzi University, Hangzhou 310018, ChinaSchool of Medicine, Hangzhou Dianzi University, Hangzhou 310018, ChinaCollege of Physical Science and Technology, Xiamen University, Xiamen 361005, ChinaSchool of Material and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, ChinaIt is a challenging yet valuable work to prepare a surface-enhanced Raman scattering (SERS) substrate with low cost and high performance by simple methods. In this study, the Ag nanoparticles were sputtered on PS spheres by the magnetron sputtering, which was used as the mask to create the nanostructures by etching the spheres. Because of the heating effect in the etching process, the Ag nanoparticles gathered on the surfaces of PS spheres when the etching time was 60 s. Strong electromagnetic coupling was observed between the gathered Ag nanoparticles as confirmed by FDTD simulation and SERS signals from the probe molecule 4-mercaptobenzoic acid. This structure showed the detection limit for thiram down to 10<sup>−8</sup> M.https://www.mdpi.com/2227-9040/10/11/445SERSnano-gapthiram
spellingShingle Deyuan Mao
Xiaoyu Zhao
Jiahong Wen
Aofang Wang
Renxian Gao
Yaxin Wang
Enhanced Electromagnetic Coupling in the Walnut-Shaped Nanostructure Array
Chemosensors
SERS
nano-gap
thiram
title Enhanced Electromagnetic Coupling in the Walnut-Shaped Nanostructure Array
title_full Enhanced Electromagnetic Coupling in the Walnut-Shaped Nanostructure Array
title_fullStr Enhanced Electromagnetic Coupling in the Walnut-Shaped Nanostructure Array
title_full_unstemmed Enhanced Electromagnetic Coupling in the Walnut-Shaped Nanostructure Array
title_short Enhanced Electromagnetic Coupling in the Walnut-Shaped Nanostructure Array
title_sort enhanced electromagnetic coupling in the walnut shaped nanostructure array
topic SERS
nano-gap
thiram
url https://www.mdpi.com/2227-9040/10/11/445
work_keys_str_mv AT deyuanmao enhancedelectromagneticcouplinginthewalnutshapednanostructurearray
AT xiaoyuzhao enhancedelectromagneticcouplinginthewalnutshapednanostructurearray
AT jiahongwen enhancedelectromagneticcouplinginthewalnutshapednanostructurearray
AT aofangwang enhancedelectromagneticcouplinginthewalnutshapednanostructurearray
AT renxiangao enhancedelectromagneticcouplinginthewalnutshapednanostructurearray
AT yaxinwang enhancedelectromagneticcouplinginthewalnutshapednanostructurearray