Reduction of graphene oxide nanosheets by natural beta carotene and its potential use as supercapacitor electrode
A green, non-toxic and eco-friendly approach for the reduction of graphene oxide (GO) nanosheets using natural β-carotene is reported. The FTIR spectroscopy and thermogravimetric analyses reveal the oxygen scavenging property of β-carotene successfully removes oxygen functionalities on GO nanosheets...
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Format: | Article |
Language: | English |
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Elsevier
2015-07-01
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Series: | Arabian Journal of Chemistry |
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Online Access: | http://www.sciencedirect.com/science/article/pii/S187853521400313X |
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author | Rubaiyi M. Zaid Fui Chin Chong Ellie Yi Lih Teo Eng-Poh Ng Kwok Feng Chong |
author_facet | Rubaiyi M. Zaid Fui Chin Chong Ellie Yi Lih Teo Eng-Poh Ng Kwok Feng Chong |
author_sort | Rubaiyi M. Zaid |
collection | DOAJ |
description | A green, non-toxic and eco-friendly approach for the reduction of graphene oxide (GO) nanosheets using natural β-carotene is reported. The FTIR spectroscopy and thermogravimetric analyses reveal the oxygen scavenging property of β-carotene successfully removes oxygen functionalities on GO nanosheets. Complete GO reduction is achieved within 16 h with 10 mM β-carotene as confirmed by the UV spectroscopy results. The high resolution transmission electron microscopy images provide clear evidence for the formation of few layers of graphene nanosheets. Furthermore, the mechanism of GO reduction by β-carotene has been proposed in this study. The electrochemical testing shows good charge storage properties of β-carotene reduced GO (142 F/g at 10 mV/s; 149 F/g at 1 A/g in Na2SO4), with stable cycling (89%) for up to 1000 cycles. The findings suggest the reduction of GO nanosheets by β-carotene is a suitable approach in producing graphene nanosheets for supercapacitor electrode. |
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format | Article |
id | doaj.art-8aa86194dea047729a596a3904234f61 |
institution | Directory Open Access Journal |
issn | 1878-5352 |
language | English |
last_indexed | 2024-12-10T19:28:19Z |
publishDate | 2015-07-01 |
publisher | Elsevier |
record_format | Article |
series | Arabian Journal of Chemistry |
spelling | doaj.art-8aa86194dea047729a596a3904234f612022-12-22T01:36:19ZengElsevierArabian Journal of Chemistry1878-53522015-07-018456056910.1016/j.arabjc.2014.11.036Reduction of graphene oxide nanosheets by natural beta carotene and its potential use as supercapacitor electrodeRubaiyi M. Zaid0Fui Chin Chong1Ellie Yi Lih Teo2Eng-Poh Ng3Kwok Feng Chong4Faculty of Chemical and Natural Resources Engineering, Universiti Malaysia Pahang, 26300 Gambang, Kuantan, MalaysiaFaculty of Chemical and Natural Resources Engineering, Universiti Malaysia Pahang, 26300 Gambang, Kuantan, MalaysiaFaculty of Industrial Sciences & Technology, Universiti Malaysia Pahang, 26300 Gambang, Kuantan, MalaysiaSchool of Chemical Sciences, Universiti Sains Malaysia, 11800 Penang, MalaysiaFaculty of Industrial Sciences & Technology, Universiti Malaysia Pahang, 26300 Gambang, Kuantan, MalaysiaA green, non-toxic and eco-friendly approach for the reduction of graphene oxide (GO) nanosheets using natural β-carotene is reported. The FTIR spectroscopy and thermogravimetric analyses reveal the oxygen scavenging property of β-carotene successfully removes oxygen functionalities on GO nanosheets. Complete GO reduction is achieved within 16 h with 10 mM β-carotene as confirmed by the UV spectroscopy results. The high resolution transmission electron microscopy images provide clear evidence for the formation of few layers of graphene nanosheets. Furthermore, the mechanism of GO reduction by β-carotene has been proposed in this study. The electrochemical testing shows good charge storage properties of β-carotene reduced GO (142 F/g at 10 mV/s; 149 F/g at 1 A/g in Na2SO4), with stable cycling (89%) for up to 1000 cycles. The findings suggest the reduction of GO nanosheets by β-carotene is a suitable approach in producing graphene nanosheets for supercapacitor electrode.http://www.sciencedirect.com/science/article/pii/S187853521400313XBeta caroteneDeoxygenationReduced graphene oxideSupercapacitor |
spellingShingle | Rubaiyi M. Zaid Fui Chin Chong Ellie Yi Lih Teo Eng-Poh Ng Kwok Feng Chong Reduction of graphene oxide nanosheets by natural beta carotene and its potential use as supercapacitor electrode Arabian Journal of Chemistry Beta carotene Deoxygenation Reduced graphene oxide Supercapacitor |
title | Reduction of graphene oxide nanosheets by natural beta carotene and its potential use as supercapacitor electrode |
title_full | Reduction of graphene oxide nanosheets by natural beta carotene and its potential use as supercapacitor electrode |
title_fullStr | Reduction of graphene oxide nanosheets by natural beta carotene and its potential use as supercapacitor electrode |
title_full_unstemmed | Reduction of graphene oxide nanosheets by natural beta carotene and its potential use as supercapacitor electrode |
title_short | Reduction of graphene oxide nanosheets by natural beta carotene and its potential use as supercapacitor electrode |
title_sort | reduction of graphene oxide nanosheets by natural beta carotene and its potential use as supercapacitor electrode |
topic | Beta carotene Deoxygenation Reduced graphene oxide Supercapacitor |
url | http://www.sciencedirect.com/science/article/pii/S187853521400313X |
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