Reduction of graphene oxide nanosheets by natural beta carotene and its potential use as supercapacitor electrode

A green, non-toxic and eco-friendly approach for the reduction of graphene oxide (GO) nanosheets using natural β-carotene is reported. The FTIR spectroscopy and thermogravimetric analyses reveal the oxygen scavenging property of β-carotene successfully removes oxygen functionalities on GO nanosheets...

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Main Authors: Rubaiyi M. Zaid, Fui Chin Chong, Ellie Yi Lih Teo, Eng-Poh Ng, Kwok Feng Chong
Format: Article
Language:English
Published: Elsevier 2015-07-01
Series:Arabian Journal of Chemistry
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S187853521400313X
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author Rubaiyi M. Zaid
Fui Chin Chong
Ellie Yi Lih Teo
Eng-Poh Ng
Kwok Feng Chong
author_facet Rubaiyi M. Zaid
Fui Chin Chong
Ellie Yi Lih Teo
Eng-Poh Ng
Kwok Feng Chong
author_sort Rubaiyi M. Zaid
collection DOAJ
description A green, non-toxic and eco-friendly approach for the reduction of graphene oxide (GO) nanosheets using natural β-carotene is reported. The FTIR spectroscopy and thermogravimetric analyses reveal the oxygen scavenging property of β-carotene successfully removes oxygen functionalities on GO nanosheets. Complete GO reduction is achieved within 16 h with 10 mM β-carotene as confirmed by the UV spectroscopy results. The high resolution transmission electron microscopy images provide clear evidence for the formation of few layers of graphene nanosheets. Furthermore, the mechanism of GO reduction by β-carotene has been proposed in this study. The electrochemical testing shows good charge storage properties of β-carotene reduced GO (142 F/g at 10 mV/s; 149 F/g at 1 A/g in Na2SO4), with stable cycling (89%) for up to 1000 cycles. The findings suggest the reduction of GO nanosheets by β-carotene is a suitable approach in producing graphene nanosheets for supercapacitor electrode.
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spelling doaj.art-8aa86194dea047729a596a3904234f612022-12-22T01:36:19ZengElsevierArabian Journal of Chemistry1878-53522015-07-018456056910.1016/j.arabjc.2014.11.036Reduction of graphene oxide nanosheets by natural beta carotene and its potential use as supercapacitor electrodeRubaiyi M. Zaid0Fui Chin Chong1Ellie Yi Lih Teo2Eng-Poh Ng3Kwok Feng Chong4Faculty of Chemical and Natural Resources Engineering, Universiti Malaysia Pahang, 26300 Gambang, Kuantan, MalaysiaFaculty of Chemical and Natural Resources Engineering, Universiti Malaysia Pahang, 26300 Gambang, Kuantan, MalaysiaFaculty of Industrial Sciences & Technology, Universiti Malaysia Pahang, 26300 Gambang, Kuantan, MalaysiaSchool of Chemical Sciences, Universiti Sains Malaysia, 11800 Penang, MalaysiaFaculty of Industrial Sciences & Technology, Universiti Malaysia Pahang, 26300 Gambang, Kuantan, MalaysiaA green, non-toxic and eco-friendly approach for the reduction of graphene oxide (GO) nanosheets using natural β-carotene is reported. The FTIR spectroscopy and thermogravimetric analyses reveal the oxygen scavenging property of β-carotene successfully removes oxygen functionalities on GO nanosheets. Complete GO reduction is achieved within 16 h with 10 mM β-carotene as confirmed by the UV spectroscopy results. The high resolution transmission electron microscopy images provide clear evidence for the formation of few layers of graphene nanosheets. Furthermore, the mechanism of GO reduction by β-carotene has been proposed in this study. The electrochemical testing shows good charge storage properties of β-carotene reduced GO (142 F/g at 10 mV/s; 149 F/g at 1 A/g in Na2SO4), with stable cycling (89%) for up to 1000 cycles. The findings suggest the reduction of GO nanosheets by β-carotene is a suitable approach in producing graphene nanosheets for supercapacitor electrode.http://www.sciencedirect.com/science/article/pii/S187853521400313XBeta caroteneDeoxygenationReduced graphene oxideSupercapacitor
spellingShingle Rubaiyi M. Zaid
Fui Chin Chong
Ellie Yi Lih Teo
Eng-Poh Ng
Kwok Feng Chong
Reduction of graphene oxide nanosheets by natural beta carotene and its potential use as supercapacitor electrode
Arabian Journal of Chemistry
Beta carotene
Deoxygenation
Reduced graphene oxide
Supercapacitor
title Reduction of graphene oxide nanosheets by natural beta carotene and its potential use as supercapacitor electrode
title_full Reduction of graphene oxide nanosheets by natural beta carotene and its potential use as supercapacitor electrode
title_fullStr Reduction of graphene oxide nanosheets by natural beta carotene and its potential use as supercapacitor electrode
title_full_unstemmed Reduction of graphene oxide nanosheets by natural beta carotene and its potential use as supercapacitor electrode
title_short Reduction of graphene oxide nanosheets by natural beta carotene and its potential use as supercapacitor electrode
title_sort reduction of graphene oxide nanosheets by natural beta carotene and its potential use as supercapacitor electrode
topic Beta carotene
Deoxygenation
Reduced graphene oxide
Supercapacitor
url http://www.sciencedirect.com/science/article/pii/S187853521400313X
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