1-Bromo-1′-(diphenylthiophosphoryl)ferrocene
The title compound, [Fe(C5H4Br)(C17H14PS)], crystallizes with two practically undistiguishable molecules in the asymmetric unit, which are related by a non-space-group inversion. The ferrocene-1,1′-diyl units exhibit a regular geometry with negligible tilting and balanced Fe&#8...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809036459 |
| _version_ | 1819280168403861504 |
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| author | Petr Štěpnička Jiří Schulz Ivana Císařová |
| author_facet | Petr Štěpnička Jiří Schulz Ivana Císařová |
| author_sort | Petr Štěpnička |
| collection | DOAJ |
| description | The title compound, [Fe(C5H4Br)(C17H14PS)], crystallizes with two practically undistiguishable molecules in the asymmetric unit, which are related by a non-space-group inversion. The ferrocene-1,1′-diyl units exhibit a regular geometry with negligible tilting and balanced Fe–ring centroid distances, and with the attached substituents assuming conformations close to ideal synclinal eclipsed. |
| first_indexed | 2024-12-24T00:39:30Z |
| format | Article |
| id | doaj.art-8aaafd0912d844c7a5dbbb8e27c6e2af |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:39:30Z |
| publishDate | 2009-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-8aaafd0912d844c7a5dbbb8e27c6e2af2022-12-21T17:24:00ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-10-016510m1210m121010.1107/S16005368090364591-Bromo-1′-(diphenylthiophosphoryl)ferrocenePetr ŠtěpničkaJiří SchulzIvana CísařováThe title compound, [Fe(C5H4Br)(C17H14PS)], crystallizes with two practically undistiguishable molecules in the asymmetric unit, which are related by a non-space-group inversion. The ferrocene-1,1′-diyl units exhibit a regular geometry with negligible tilting and balanced Fe–ring centroid distances, and with the attached substituents assuming conformations close to ideal synclinal eclipsed.http://scripts.iucr.org/cgi-bin/paper?S1600536809036459 |
| spellingShingle | Petr Štěpnička Jiří Schulz Ivana Císařová 1-Bromo-1′-(diphenylthiophosphoryl)ferrocene Acta Crystallographica Section E |
| title | 1-Bromo-1′-(diphenylthiophosphoryl)ferrocene |
| title_full | 1-Bromo-1′-(diphenylthiophosphoryl)ferrocene |
| title_fullStr | 1-Bromo-1′-(diphenylthiophosphoryl)ferrocene |
| title_full_unstemmed | 1-Bromo-1′-(diphenylthiophosphoryl)ferrocene |
| title_short | 1-Bromo-1′-(diphenylthiophosphoryl)ferrocene |
| title_sort | 1 bromo 1 amp 8242 diphenylthiophosphoryl ferrocene |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809036459 |
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