Studies of Indium Tin Oxide-Based Sensing Electrodes in Potentiometric Zirconia Solid Electrolyte Gas Sensors

A zirconia-based potentiometric solid electrolyte gas sensor with internal solid state reference was used to study the response behavior of platinum cermet and indium tin oxide sensing electrodes. Target gases included both oxygen and carbon monoxide in nitrogen-based sample gas mixtures. It was fou...

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Main Authors: Stefan Dietrich, Mihails Kusnezoff, Alexander Michaelis
Format: Article
Language:English
Published: MDPI AG 2021-03-01
Series:Sensors
Subjects:
Online Access:https://www.mdpi.com/1424-8220/21/7/2345
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author Stefan Dietrich
Mihails Kusnezoff
Alexander Michaelis
author_facet Stefan Dietrich
Mihails Kusnezoff
Alexander Michaelis
author_sort Stefan Dietrich
collection DOAJ
description A zirconia-based potentiometric solid electrolyte gas sensor with internal solid state reference was used to study the response behavior of platinum cermet and indium tin oxide sensing electrodes. Target gases included both oxygen and carbon monoxide in nitrogen-based sample gas mixtures. It was found that with the indium tin oxide sensing electrode, the low-temperature behavior is mainly a result of incomplete equilibration due to contaminations of the electrode surface. On the other hand, some of these contaminant species have been identified as being pivotal for the higher carbon monoxide sensitivity of the indium tin oxide sensing electrode as compared to platinum cermet electrodes.
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spelling doaj.art-8abfb972829b4b97844df498e89c211d2023-11-21T13:06:12ZengMDPI AGSensors1424-82202021-03-01217234510.3390/s21072345Studies of Indium Tin Oxide-Based Sensing Electrodes in Potentiometric Zirconia Solid Electrolyte Gas SensorsStefan Dietrich0Mihails Kusnezoff1Alexander Michaelis2Fraunhofer Institute for Ceramic Technologies and Systems IKTS, Winterbergstr. 28, 01277 Dresden, GermanyFraunhofer Institute for Ceramic Technologies and Systems IKTS, Winterbergstr. 28, 01277 Dresden, GermanyInstitute of Materials Science, Technische Universität Dresden, 01069 Dresden, GermanyA zirconia-based potentiometric solid electrolyte gas sensor with internal solid state reference was used to study the response behavior of platinum cermet and indium tin oxide sensing electrodes. Target gases included both oxygen and carbon monoxide in nitrogen-based sample gas mixtures. It was found that with the indium tin oxide sensing electrode, the low-temperature behavior is mainly a result of incomplete equilibration due to contaminations of the electrode surface. On the other hand, some of these contaminant species have been identified as being pivotal for the higher carbon monoxide sensitivity of the indium tin oxide sensing electrode as compared to platinum cermet electrodes.https://www.mdpi.com/1424-8220/21/7/2345potentiometric solid electrolyte sensormixed potentialindium tin oxideinternal reference gas sensor
spellingShingle Stefan Dietrich
Mihails Kusnezoff
Alexander Michaelis
Studies of Indium Tin Oxide-Based Sensing Electrodes in Potentiometric Zirconia Solid Electrolyte Gas Sensors
Sensors
potentiometric solid electrolyte sensor
mixed potential
indium tin oxide
internal reference gas sensor
title Studies of Indium Tin Oxide-Based Sensing Electrodes in Potentiometric Zirconia Solid Electrolyte Gas Sensors
title_full Studies of Indium Tin Oxide-Based Sensing Electrodes in Potentiometric Zirconia Solid Electrolyte Gas Sensors
title_fullStr Studies of Indium Tin Oxide-Based Sensing Electrodes in Potentiometric Zirconia Solid Electrolyte Gas Sensors
title_full_unstemmed Studies of Indium Tin Oxide-Based Sensing Electrodes in Potentiometric Zirconia Solid Electrolyte Gas Sensors
title_short Studies of Indium Tin Oxide-Based Sensing Electrodes in Potentiometric Zirconia Solid Electrolyte Gas Sensors
title_sort studies of indium tin oxide based sensing electrodes in potentiometric zirconia solid electrolyte gas sensors
topic potentiometric solid electrolyte sensor
mixed potential
indium tin oxide
internal reference gas sensor
url https://www.mdpi.com/1424-8220/21/7/2345
work_keys_str_mv AT stefandietrich studiesofindiumtinoxidebasedsensingelectrodesinpotentiometriczirconiasolidelectrolytegassensors
AT mihailskusnezoff studiesofindiumtinoxidebasedsensingelectrodesinpotentiometriczirconiasolidelectrolytegassensors
AT alexandermichaelis studiesofindiumtinoxidebasedsensingelectrodesinpotentiometriczirconiasolidelectrolytegassensors