Cu-Mediated trifluoromethylation of benzyl, allyl and propargyl methanesulfonates with TMSCF3

A Cu-mediated trifluoromethylation of benzyl, allyl and propargyl methanesulfonates with TMSCF3 was developed for the first time. This method offers a convenient and economical approach to various trifluoroethyl-containing compounds.

Bibliographic Details
Main Authors: Xueliang Jiang, Feng-Ling Qing
Format: Article
Language:English
Published: Beilstein-Institut 2013-12-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.9.322
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author Xueliang Jiang
Feng-Ling Qing
author_facet Xueliang Jiang
Feng-Ling Qing
author_sort Xueliang Jiang
collection DOAJ
description A Cu-mediated trifluoromethylation of benzyl, allyl and propargyl methanesulfonates with TMSCF3 was developed for the first time. This method offers a convenient and economical approach to various trifluoroethyl-containing compounds.
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spelling doaj.art-8adcfce679754aee91d2a79f52f7cdff2022-12-21T23:03:47ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972013-12-01912862286510.3762/bjoc.9.3221860-5397-9-322Cu-Mediated trifluoromethylation of benzyl, allyl and propargyl methanesulfonates with TMSCF3Xueliang Jiang0Feng-Ling Qing1Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, ChinaKey Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, ChinaA Cu-mediated trifluoromethylation of benzyl, allyl and propargyl methanesulfonates with TMSCF3 was developed for the first time. This method offers a convenient and economical approach to various trifluoroethyl-containing compounds.https://doi.org/10.3762/bjoc.9.322coppermethanesulfonatesorgano-fluorinetrifluoromethylation
spellingShingle Xueliang Jiang
Feng-Ling Qing
Cu-Mediated trifluoromethylation of benzyl, allyl and propargyl methanesulfonates with TMSCF3
Beilstein Journal of Organic Chemistry
copper
methanesulfonates
organo-fluorine
trifluoromethylation
title Cu-Mediated trifluoromethylation of benzyl, allyl and propargyl methanesulfonates with TMSCF3
title_full Cu-Mediated trifluoromethylation of benzyl, allyl and propargyl methanesulfonates with TMSCF3
title_fullStr Cu-Mediated trifluoromethylation of benzyl, allyl and propargyl methanesulfonates with TMSCF3
title_full_unstemmed Cu-Mediated trifluoromethylation of benzyl, allyl and propargyl methanesulfonates with TMSCF3
title_short Cu-Mediated trifluoromethylation of benzyl, allyl and propargyl methanesulfonates with TMSCF3
title_sort cu mediated trifluoromethylation of benzyl allyl and propargyl methanesulfonates with tmscf3
topic copper
methanesulfonates
organo-fluorine
trifluoromethylation
url https://doi.org/10.3762/bjoc.9.322
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