Bis(μ-hydroxido-κ2O:O)bis[bis(5-carboxypyridine-2-carboxylato-κ2N,O2)iron(III)] dihydrate
The complete binuclear complex in [Fe2(C7H4NO4)4(OH)2]·2H2O, is generated by the application twofold symmetry. The FeIII atom is coordinated by the O atoms of two bridging hydroxyl groups and by two N and two O atoms from two pyridine-2,5-dicarboxylato ligands, forming a distorted octahedra...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2013-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813029449 |
| _version_ | 1831707647176343552 |
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| author | Wenhai Cao |
| author_facet | Wenhai Cao |
| author_sort | Wenhai Cao |
| collection | DOAJ |
| description | The complete binuclear complex in [Fe2(C7H4NO4)4(OH)2]·2H2O, is generated by the application twofold symmetry. The FeIII atom is coordinated by the O atoms of two bridging hydroxyl groups and by two N and two O atoms from two pyridine-2,5-dicarboxylato ligands, forming a distorted octahedral geometry. The Fe...Fe separation within the dinuclear complex is 3.0657 (4) Å. In the crystal, O—H...O and C—H...O hydrogen-bonding interactions connect the molecules into a three-dimensional supramolecular network. |
| first_indexed | 2024-12-20T21:44:55Z |
| format | Article |
| id | doaj.art-8afa46b0027b43e6b437548d68da4214 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T21:44:55Z |
| publishDate | 2013-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-8afa46b0027b43e6b437548d68da42142022-12-21T19:25:43ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-11-016911m625m62510.1107/S1600536813029449Bis(μ-hydroxido-κ2O:O)bis[bis(5-carboxypyridine-2-carboxylato-κ2N,O2)iron(III)] dihydrateWenhai CaoThe complete binuclear complex in [Fe2(C7H4NO4)4(OH)2]·2H2O, is generated by the application twofold symmetry. The FeIII atom is coordinated by the O atoms of two bridging hydroxyl groups and by two N and two O atoms from two pyridine-2,5-dicarboxylato ligands, forming a distorted octahedral geometry. The Fe...Fe separation within the dinuclear complex is 3.0657 (4) Å. In the crystal, O—H...O and C—H...O hydrogen-bonding interactions connect the molecules into a three-dimensional supramolecular network.http://scripts.iucr.org/cgi-bin/paper?S1600536813029449 |
| spellingShingle | Wenhai Cao Bis(μ-hydroxido-κ2O:O)bis[bis(5-carboxypyridine-2-carboxylato-κ2N,O2)iron(III)] dihydrate Acta Crystallographica Section E |
| title | Bis(μ-hydroxido-κ2O:O)bis[bis(5-carboxypyridine-2-carboxylato-κ2N,O2)iron(III)] dihydrate |
| title_full | Bis(μ-hydroxido-κ2O:O)bis[bis(5-carboxypyridine-2-carboxylato-κ2N,O2)iron(III)] dihydrate |
| title_fullStr | Bis(μ-hydroxido-κ2O:O)bis[bis(5-carboxypyridine-2-carboxylato-κ2N,O2)iron(III)] dihydrate |
| title_full_unstemmed | Bis(μ-hydroxido-κ2O:O)bis[bis(5-carboxypyridine-2-carboxylato-κ2N,O2)iron(III)] dihydrate |
| title_short | Bis(μ-hydroxido-κ2O:O)bis[bis(5-carboxypyridine-2-carboxylato-κ2N,O2)iron(III)] dihydrate |
| title_sort | bis 956 hydroxido 954 2o o bis bis 5 carboxypyridine 2 carboxylato 954 2n o2 iron iii dihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813029449 |
| work_keys_str_mv | AT wenhaicao bis956hydroxido9542oobisbis5carboxypyridine2carboxylato9542no2ironiiidihydrate |