Fine-Tuning of the Optical and Electrochemical Properties of Ruthenium(II) Complexes with 2-Arylbenzimidazoles and 4,4′-Dimethoxycarbonyl-2,2′-bipyridine

Fine-Tuning of the Optical and Electrochemical Properties of Ruthenium(II) Complexes with 2-Arylbenzimidazoles and 4,4′-Dimethoxycarbonyl-2,2′-bipyridine

A series of cyclometalated complexes of ruthenium (II) with four different substituents in the aryl fragment of benzimidazole was synthesized in order to study the effect of substituent donation on the electronic structure of the substances. The resulting complexes were studied using X-ray diffracti...

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Bibliographic Details
Main Authors: Maria A. Lavrova, Stepan A. Verzun, Sergey A. Mishurinskiy, Maxim A. Sirotin, Sofya K. Bykova, Victoria E. Gontcharenko, Sofia S. Mariasina, Vladislav M. Korshunov, Ilya V. Taydakov, Yury A. Belousov, Vladimir D. Dolzhenko
Format: Article
Language:English
Published: MDPI AG 2023-09-01
Series:Molecules
Subjects:
cyclometalated complexes
photosensitizers
thiocyanate-free ruthenium dyes
bipyridine ruthenium complexes
benzimidazoles
Online Access:https://www.mdpi.com/1420-3049/28/18/6541

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