| Summary: | The structure and composition of nanofillers have a significant influence on polyamide nanofiltration (NF) membranes. In this work, an asymmetric organic nanobowl containing a concave cavity was synthesized and incorporated into a polyamide layer to prepare thin film nanocomposite (TFN) membranes via an interfacial polymerization process. Benefiting from the hydrophilicity, hollow cavity and charge property of the compatible organic nanobowls, the separation performance of the developed TFN membrane was significantly improved. The corresponding water fluxes increased to 119.44 ± 5.56, 141.82 ± 3.24 and 130.27 ± 2.05 L/(m<sup>2</sup>·h) toward Na<sub>2</sub>SO<sub>4</sub>, MgCl<sub>2</sub> and NaCl solutions, respectively, with higher rejections, compared with the control thin film composite (TFC) and commercial (CM) membranes. Besides this, the modified TFN membrane presented a satisfying purification performance toward tap water, municipal effluent and heavy metal wastewater. More importantly, a better antifouling property of the TFN membrane than TFC and CM membranes was achieved with the assistance of organic nanobowls. These results indicate that the separation performance of the TFN membrane can be elevated by the incorporation of organic nanobowls.
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