Bis[1-phenyl-3-(1H-1,2,4-triazol-1-yl-κN4)propan-1-one]bis(thiocyanato-κN)copper(II)
The title compound, [Cu(NCS)2(C11H11N3O)2], contains two independent CuII atoms. Each CuII atom, lying on an inversion center, is coordinated by two N atoms from two NCS− anions and two N atoms from two monodentate 1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one ligands in a distorted s...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681203108X |
| Summary: | The title compound, [Cu(NCS)2(C11H11N3O)2], contains two independent CuII atoms. Each CuII atom, lying on an inversion center, is coordinated by two N atoms from two NCS− anions and two N atoms from two monodentate 1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one ligands in a distorted square-planar geometry. Two S atoms from adjacent molecules occupy the axial positions with long Cu...S distances [3.0495 (10) and 3.1045 (9) Å] and complete the overall distorted octahedral coordination sphere. Weak intermolecular C—H...O hydrogen bonds are present. |
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| ISSN: | 1600-5368 |