Efficient Visible-Light Photocatalysis of TiO<sub>2-δ</sub> Nanobelts Utilizing Self-Induced Defects and Carbon Doping

Efficient visible-light photocatalysis was realized by exploring self-induced defect states, including the abundant surface states of TiO<sub>2-δ</sub> nanobelts synthesized through metal–organic chemical vapor deposition (MOCVD). The TiO<sub>2-δ</sub> nanobelts exhibited two...

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Bibliographic Details
Main Authors: Dong-Bum Seo, Sung-Su Bae, Eui-Tae Kim
Format: Article
Language:English
Published: MDPI AG 2021-05-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/11/6/1377
Description
Summary:Efficient visible-light photocatalysis was realized by exploring self-induced defect states, including the abundant surface states of TiO<sub>2-δ</sub> nanobelts synthesized through metal–organic chemical vapor deposition (MOCVD). The TiO<sub>2-δ</sub> nanobelts exhibited two strong defect-induced absorption peaks at 2.91 and 1.92 eV, overlapping with the conduction band states so that photoexcited carriers can contribute effectively for the photocatalysis reaction. To further enhance visible-light photocatalytic activity, carbon atoms, the by-product of the MOCVD reaction, were self-doped at the judiciously determined growth conditions. The resulting visible-light photocatalysis suggests that the large surface area and consequent high concentration of the surface states of the TiO<sub>2-δ</sub> nanobelts can be effectively utilized in a wide range of photocatalysis applications.
ISSN:2079-4991