Catalytic Hydrogenation of CO<sub>2</sub> to Methanol: A Review

High-efficiency utilization of CO<sub>2</sub> facilitates the reduction of CO<sub>2</sub> concentration in the global atmosphere and hence the alleviation of the greenhouse effect. The catalytic hydrogenation of CO<sub>2</sub> to produce value-added chemicals exhi...

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Main Authors: Menghao Ren, Yanmin Zhang, Xuan Wang, Hengshan Qiu
Format: Article
Language:English
Published: MDPI AG 2022-04-01
Series:Catalysts
Subjects:
Online Access:https://www.mdpi.com/2073-4344/12/4/403
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author Menghao Ren
Yanmin Zhang
Xuan Wang
Hengshan Qiu
author_facet Menghao Ren
Yanmin Zhang
Xuan Wang
Hengshan Qiu
author_sort Menghao Ren
collection DOAJ
description High-efficiency utilization of CO<sub>2</sub> facilitates the reduction of CO<sub>2</sub> concentration in the global atmosphere and hence the alleviation of the greenhouse effect. The catalytic hydrogenation of CO<sub>2</sub> to produce value-added chemicals exhibits attractive prospects by potentially building energy recycling loops. Particularly, methanol is one of the practically important objective products, and the catalytic hydrogenation of CO<sub>2</sub> to synthesize methanol has been extensively studied. In this review, we focus on some basic concepts on CO<sub>2</sub> activation, the recent research advances in the catalytic hydrogenation of CO<sub>2</sub> to methanol, the development of high-performance catalysts, and microscopic insight into the reaction mechanisms. Finally, some thinking on the present research and possible future trend is presented.
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spelling doaj.art-8b75403a25584442aabc925fa42f4d952023-12-01T01:11:12ZengMDPI AGCatalysts2073-43442022-04-0112440310.3390/catal12040403Catalytic Hydrogenation of CO<sub>2</sub> to Methanol: A ReviewMenghao Ren0Yanmin Zhang1Xuan Wang2Hengshan Qiu3Engineering Research Center of Advanced Functional Material Manufacturing of Ministry of Education, School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, ChinaEngineering Research Center of Advanced Functional Material Manufacturing of Ministry of Education, School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, ChinaEngineering Research Center of Advanced Functional Material Manufacturing of Ministry of Education, School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, ChinaEngineering Research Center of Advanced Functional Material Manufacturing of Ministry of Education, School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, ChinaHigh-efficiency utilization of CO<sub>2</sub> facilitates the reduction of CO<sub>2</sub> concentration in the global atmosphere and hence the alleviation of the greenhouse effect. The catalytic hydrogenation of CO<sub>2</sub> to produce value-added chemicals exhibits attractive prospects by potentially building energy recycling loops. Particularly, methanol is one of the practically important objective products, and the catalytic hydrogenation of CO<sub>2</sub> to synthesize methanol has been extensively studied. In this review, we focus on some basic concepts on CO<sub>2</sub> activation, the recent research advances in the catalytic hydrogenation of CO<sub>2</sub> to methanol, the development of high-performance catalysts, and microscopic insight into the reaction mechanisms. Finally, some thinking on the present research and possible future trend is presented.https://www.mdpi.com/2073-4344/12/4/403carbon dioxidehydrogenationheterogeneous catalysismethanol synthesiscatalystsreaction mechanism
spellingShingle Menghao Ren
Yanmin Zhang
Xuan Wang
Hengshan Qiu
Catalytic Hydrogenation of CO<sub>2</sub> to Methanol: A Review
Catalysts
carbon dioxide
hydrogenation
heterogeneous catalysis
methanol synthesis
catalysts
reaction mechanism
title Catalytic Hydrogenation of CO<sub>2</sub> to Methanol: A Review
title_full Catalytic Hydrogenation of CO<sub>2</sub> to Methanol: A Review
title_fullStr Catalytic Hydrogenation of CO<sub>2</sub> to Methanol: A Review
title_full_unstemmed Catalytic Hydrogenation of CO<sub>2</sub> to Methanol: A Review
title_short Catalytic Hydrogenation of CO<sub>2</sub> to Methanol: A Review
title_sort catalytic hydrogenation of co sub 2 sub to methanol a review
topic carbon dioxide
hydrogenation
heterogeneous catalysis
methanol synthesis
catalysts
reaction mechanism
url https://www.mdpi.com/2073-4344/12/4/403
work_keys_str_mv AT menghaoren catalytichydrogenationofcosub2subtomethanolareview
AT yanminzhang catalytichydrogenationofcosub2subtomethanolareview
AT xuanwang catalytichydrogenationofcosub2subtomethanolareview
AT hengshanqiu catalytichydrogenationofcosub2subtomethanolareview