Mn4+-Doped Magnesium Titanate—A Promising Phosphor for Self-Referenced Optical Temperature Sensing

Phosphors based on magnesium titanate activated with Mn 4 + ions are of great interest because, when excited with blue light, they display a strong red-emitting luminescence. They are characterized by a luminescence decay which is strongly temperature dependent in the range from −50 ∘...

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Main Authors: Francesca Venturini, Michael Baumgartner, Sergey M. Borisov
Format: Article
Language:English
Published: MDPI AG 2018-02-01
Series:Sensors
Subjects:
Online Access:http://www.mdpi.com/1424-8220/18/2/668
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author Francesca Venturini
Michael Baumgartner
Sergey M. Borisov
author_facet Francesca Venturini
Michael Baumgartner
Sergey M. Borisov
author_sort Francesca Venturini
collection DOAJ
description Phosphors based on magnesium titanate activated with Mn 4 + ions are of great interest because, when excited with blue light, they display a strong red-emitting luminescence. They are characterized by a luminescence decay which is strongly temperature dependent in the range from −50 ∘ C to 150 ∘ C, making these materials very promising for temperature sensing in the biochemical field. In this work, the optical and thermal properties of the luminescence of Mg 2 TiO 4 are investigated for different Mn 4 + doping concentrations. The potential of this material for temperature sensing is demonstrated by fabricating a fiber optic temperature microsensor and by comparing its performance against a standard resistance thermometer. The response of the fiber optic sensor is exceptionally fast, with a response time below 1 s in the liquid phase and below 1.1 s in the gas phase.
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spelling doaj.art-8b8df5e307f647ae83e155669b7251192022-12-22T02:56:29ZengMDPI AGSensors1424-82202018-02-0118266810.3390/s18020668s18020668Mn4+-Doped Magnesium Titanate—A Promising Phosphor for Self-Referenced Optical Temperature SensingFrancesca Venturini0Michael Baumgartner1Sergey M. Borisov2Institute of Applied Mathematics and Physics, Zurich University of Applied Sciences, Winterthur 8401, SwitzerlandInstitute of Applied Mathematics and Physics, Zurich University of Applied Sciences, Winterthur 8401, SwitzerlandInstitute of Analytical Chemistry and Food Chemistry, Graz University of Technology, Stremayrgasse 9, 8010 Graz, AustriaPhosphors based on magnesium titanate activated with Mn 4 + ions are of great interest because, when excited with blue light, they display a strong red-emitting luminescence. They are characterized by a luminescence decay which is strongly temperature dependent in the range from −50 ∘ C to 150 ∘ C, making these materials very promising for temperature sensing in the biochemical field. In this work, the optical and thermal properties of the luminescence of Mg 2 TiO 4 are investigated for different Mn 4 + doping concentrations. The potential of this material for temperature sensing is demonstrated by fabricating a fiber optic temperature microsensor and by comparing its performance against a standard resistance thermometer. The response of the fiber optic sensor is exceptionally fast, with a response time below 1 s in the liquid phase and below 1.1 s in the gas phase.http://www.mdpi.com/1424-8220/18/2/668phosphoroptical sensortemperature sensormanganese, luminescence
spellingShingle Francesca Venturini
Michael Baumgartner
Sergey M. Borisov
Mn4+-Doped Magnesium Titanate—A Promising Phosphor for Self-Referenced Optical Temperature Sensing
Sensors
phosphor
optical sensor
temperature sensor
manganese, luminescence
title Mn4+-Doped Magnesium Titanate—A Promising Phosphor for Self-Referenced Optical Temperature Sensing
title_full Mn4+-Doped Magnesium Titanate—A Promising Phosphor for Self-Referenced Optical Temperature Sensing
title_fullStr Mn4+-Doped Magnesium Titanate—A Promising Phosphor for Self-Referenced Optical Temperature Sensing
title_full_unstemmed Mn4+-Doped Magnesium Titanate—A Promising Phosphor for Self-Referenced Optical Temperature Sensing
title_short Mn4+-Doped Magnesium Titanate—A Promising Phosphor for Self-Referenced Optical Temperature Sensing
title_sort mn4 doped magnesium titanate a promising phosphor for self referenced optical temperature sensing
topic phosphor
optical sensor
temperature sensor
manganese, luminescence
url http://www.mdpi.com/1424-8220/18/2/668
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AT michaelbaumgartner mn4dopedmagnesiumtitanateapromisingphosphorforselfreferencedopticaltemperaturesensing
AT sergeymborisov mn4dopedmagnesiumtitanateapromisingphosphorforselfreferencedopticaltemperaturesensing