New oscillating reaction – phenylacetylene oxidative carbonylation to anhydride of phenylmaleic acid

In area of the catalytic reactions with metal complexes new oscillatory process - reaction of phenylacetylene oxidative carbonylation to anhydride of phenylmaleic acid in the system LiBr-PdBr2-CO-O2-(CH3)2CO is found. Independence of a oscillations mode of a gases mixture composition is shown at the...

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Main Authors: S. N. Gorodsky, O. V. Kasatkina, L. G. Bruk, O. N. Temkin
Format: Article
Language:Russian
Published: MIREA - Russian Technological University 2006-04-01
Series:Тонкие химические технологии
Online Access:https://www.finechem-mirea.ru/jour/article/view/1388
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author S. N. Gorodsky
O. V. Kasatkina
L. G. Bruk
O. N. Temkin
author_facet S. N. Gorodsky
O. V. Kasatkina
L. G. Bruk
O. N. Temkin
author_sort S. N. Gorodsky
collection DOAJ
description In area of the catalytic reactions with metal complexes new oscillatory process - reaction of phenylacetylene oxidative carbonylation to anhydride of phenylmaleic acid in the system LiBr-PdBr2-CO-O2-(CH3)2CO is found. Independence of a oscillations mode of a gases mixture composition is shown at the percentage of CO no more than 50 %. The preliminary mechanism of process was proposed.
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spelling doaj.art-8b9272412128417a9717c38a3818e7a82023-03-13T07:25:27ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752006-04-011273761383New oscillating reaction – phenylacetylene oxidative carbonylation to anhydride of phenylmaleic acidS. N. Gorodsky0O. V. Kasatkina1L. G. Bruk2O. N. Temkin3M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571In area of the catalytic reactions with metal complexes new oscillatory process - reaction of phenylacetylene oxidative carbonylation to anhydride of phenylmaleic acid in the system LiBr-PdBr2-CO-O2-(CH3)2CO is found. Independence of a oscillations mode of a gases mixture composition is shown at the percentage of CO no more than 50 %. The preliminary mechanism of process was proposed.https://www.finechem-mirea.ru/jour/article/view/1388
spellingShingle S. N. Gorodsky
O. V. Kasatkina
L. G. Bruk
O. N. Temkin
New oscillating reaction – phenylacetylene oxidative carbonylation to anhydride of phenylmaleic acid
Тонкие химические технологии
title New oscillating reaction – phenylacetylene oxidative carbonylation to anhydride of phenylmaleic acid
title_full New oscillating reaction – phenylacetylene oxidative carbonylation to anhydride of phenylmaleic acid
title_fullStr New oscillating reaction – phenylacetylene oxidative carbonylation to anhydride of phenylmaleic acid
title_full_unstemmed New oscillating reaction – phenylacetylene oxidative carbonylation to anhydride of phenylmaleic acid
title_short New oscillating reaction – phenylacetylene oxidative carbonylation to anhydride of phenylmaleic acid
title_sort new oscillating reaction phenylacetylene oxidative carbonylation to anhydride of phenylmaleic acid
url https://www.finechem-mirea.ru/jour/article/view/1388
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AT ovkasatkina newoscillatingreactionphenylacetyleneoxidativecarbonylationtoanhydrideofphenylmaleicacid
AT lgbruk newoscillatingreactionphenylacetyleneoxidativecarbonylationtoanhydrideofphenylmaleicacid
AT ontemkin newoscillatingreactionphenylacetyleneoxidativecarbonylationtoanhydrideofphenylmaleicacid