Selected Physicochemical, Thermal, and Rheological Properties of Barley Starch Depending on the Type of Soil and Fertilization with Ash from Biomass Combustion

The following study analyzed the impact of fertilizing barley with fly ash from biomass combustion grown on two types of soil, Haplic Luvisol (HL) and Gleyic Chernozem (GC), on the properties of starch. The experiment was conducted in 2019 (A) and 2020 (B), and barley was fertilized with ash doses (...

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Main Authors: Karolina Pycia, Ewa Szpunar-Krok, Małgorzata Szostek, Renata Pawlak, Lesław Juszczak
Format: Article
Language:English
Published: MDPI AG 2023-12-01
Series:Foods
Subjects:
Online Access:https://www.mdpi.com/2304-8158/13/1/49
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author Karolina Pycia
Ewa Szpunar-Krok
Małgorzata Szostek
Renata Pawlak
Lesław Juszczak
author_facet Karolina Pycia
Ewa Szpunar-Krok
Małgorzata Szostek
Renata Pawlak
Lesław Juszczak
author_sort Karolina Pycia
collection DOAJ
description The following study analyzed the impact of fertilizing barley with fly ash from biomass combustion grown on two types of soil, Haplic Luvisol (HL) and Gleyic Chernozem (GC), on the properties of starch. The experiment was conducted in 2019 (A) and 2020 (B), and barley was fertilized with ash doses (D1–D6) differing in mineral content. In the tested barley starch samples, the amylose content, the clarity of the paste, and the content of selected minerals were determined. The thermodynamic characteristics of gelatinization and retrogradation were determined using the DSC method. Pasting characteristics, flow curves, and viscoelastic properties of starch pastes were performed. Starches differed in amylose content and paste clarity. The highest gelatinization and retrogradation enthalpy (ΔH<sub>G</sub> and ΔH<sub>R</sub>) values were recorded for samples GCD1A and HLD5B. None of the tested factors significantly affected the pasting temperature (PT), but they had a significant impact on the remaining parameters of the pasting characteristics. The average PT value of barley starches was 90.9 °C. However, GCD2A starch had the highest maximum viscosity and the highest rheological stability during heating. GCD2A paste was characterized by the highest apparent viscosity. It was shown that all pastes showed non-Newtonian flow and shear-thinning and had a predominance of elastic features over viscous ones. The resulting gels had the characteristics of weak gels. Ash from burning wood biomass is an innovative alternative to mineral fertilizers. It was shown that the use of such soil fertilization influenced the properties of barley starch.
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spelling doaj.art-8b996a3b7be64defb0761dec1f5d1a6d2024-01-10T14:56:43ZengMDPI AGFoods2304-81582023-12-011314910.3390/foods13010049Selected Physicochemical, Thermal, and Rheological Properties of Barley Starch Depending on the Type of Soil and Fertilization with Ash from Biomass CombustionKarolina Pycia0Ewa Szpunar-Krok1Małgorzata Szostek2Renata Pawlak3Lesław Juszczak4Department of Food Technology and Human Nutrition, Institute of Food Technology, College of Natural Science, University of Rzeszow, Zelwerowicza 4 St., 35-601 Rzeszow, PolandDepartment of Plant Production, Institute of Agricultural Sciences, and Environmental Protection, College of Natural Science, University of Rzeszow, Zelwerowicza 4 St., 35-601 Rzeszow, PolandDepartment of Soil Science, Environmental Chemistry and Hydrology, College of Natural Sciences, University of Rzeszow, Zelwerowicza 8b St., 35-601 Rzeszow, PolandRENAGRO Renata Pawlak, PolandDepartment of Food Analysis and Evaluation of Food Quality, University of Agriculture in Krakow, Balicka 122, 30-149 Krakow, PolandThe following study analyzed the impact of fertilizing barley with fly ash from biomass combustion grown on two types of soil, Haplic Luvisol (HL) and Gleyic Chernozem (GC), on the properties of starch. The experiment was conducted in 2019 (A) and 2020 (B), and barley was fertilized with ash doses (D1–D6) differing in mineral content. In the tested barley starch samples, the amylose content, the clarity of the paste, and the content of selected minerals were determined. The thermodynamic characteristics of gelatinization and retrogradation were determined using the DSC method. Pasting characteristics, flow curves, and viscoelastic properties of starch pastes were performed. Starches differed in amylose content and paste clarity. The highest gelatinization and retrogradation enthalpy (ΔH<sub>G</sub> and ΔH<sub>R</sub>) values were recorded for samples GCD1A and HLD5B. None of the tested factors significantly affected the pasting temperature (PT), but they had a significant impact on the remaining parameters of the pasting characteristics. The average PT value of barley starches was 90.9 °C. However, GCD2A starch had the highest maximum viscosity and the highest rheological stability during heating. GCD2A paste was characterized by the highest apparent viscosity. It was shown that all pastes showed non-Newtonian flow and shear-thinning and had a predominance of elastic features over viscous ones. The resulting gels had the characteristics of weak gels. Ash from burning wood biomass is an innovative alternative to mineral fertilizers. It was shown that the use of such soil fertilization influenced the properties of barley starch.https://www.mdpi.com/2304-8158/13/1/49barley starchfertilizationash from biomass combustionsoilthermal propertiesrheological properties
spellingShingle Karolina Pycia
Ewa Szpunar-Krok
Małgorzata Szostek
Renata Pawlak
Lesław Juszczak
Selected Physicochemical, Thermal, and Rheological Properties of Barley Starch Depending on the Type of Soil and Fertilization with Ash from Biomass Combustion
Foods
barley starch
fertilization
ash from biomass combustion
soil
thermal properties
rheological properties
title Selected Physicochemical, Thermal, and Rheological Properties of Barley Starch Depending on the Type of Soil and Fertilization with Ash from Biomass Combustion
title_full Selected Physicochemical, Thermal, and Rheological Properties of Barley Starch Depending on the Type of Soil and Fertilization with Ash from Biomass Combustion
title_fullStr Selected Physicochemical, Thermal, and Rheological Properties of Barley Starch Depending on the Type of Soil and Fertilization with Ash from Biomass Combustion
title_full_unstemmed Selected Physicochemical, Thermal, and Rheological Properties of Barley Starch Depending on the Type of Soil and Fertilization with Ash from Biomass Combustion
title_short Selected Physicochemical, Thermal, and Rheological Properties of Barley Starch Depending on the Type of Soil and Fertilization with Ash from Biomass Combustion
title_sort selected physicochemical thermal and rheological properties of barley starch depending on the type of soil and fertilization with ash from biomass combustion
topic barley starch
fertilization
ash from biomass combustion
soil
thermal properties
rheological properties
url https://www.mdpi.com/2304-8158/13/1/49
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