The Enhancement of Overall Performance of Lubricating Grease by Adding Layered Double Hydroxides

In this work, MgAl-layered double hydroxides (LDH) were synthesized by co-precipitation method using a colloid mill and characterized by XRD and SEM. It was found that the environmentally friendly LDHs had greater performance than the traditional antioxidant. By adding LDHs into large electric shove...

Full description

Bibliographic Details
Main Authors: Yong Li, Weidong Zhou, Wanan Xue, Yongwang Huang, Qiang Zhang, Jingbin Han
Format: Article
Language:English
Published: MDPI AG 2023-06-01
Series:Lubricants
Subjects:
Online Access:https://www.mdpi.com/2075-4442/11/6/260
_version_ 1797593802003709952
author Yong Li
Weidong Zhou
Wanan Xue
Yongwang Huang
Qiang Zhang
Jingbin Han
author_facet Yong Li
Weidong Zhou
Wanan Xue
Yongwang Huang
Qiang Zhang
Jingbin Han
author_sort Yong Li
collection DOAJ
description In this work, MgAl-layered double hydroxides (LDH) were synthesized by co-precipitation method using a colloid mill and characterized by XRD and SEM. It was found that the environmentally friendly LDHs had greater performance than the traditional antioxidant. By adding LDHs into large electric shovel grease (GRK-A) in open-pit coal mine, the service lifetime of grease was extended by 20%. With the increase in LDH addition, the grease sample attains greater activation energy, and the thermal oxidation and decomposition resistance become stronger. Comparing the energy storage modulus and flow transition index at different temperatures, adding the right amount of LDHs needs close attention for the system oxidation resistance and viscoelasticity. For the electric shovel grease, the best oxidation resistance and rheological properties can be achieved by adding 2% of LDHs. The rheological viscosity–temperature curves show that the grease samples with different ratios of solid LDHs have better low-temperature properties than the mine grease. This work outlines a simple method for creating an environmentally sustainable lubricant additive with the use of LDH. LDH serves as a novel inorganic antioxidant additive that is optimal for open gear lubrication and sliding friction.
first_indexed 2024-03-11T02:13:36Z
format Article
id doaj.art-8b9d0611ae41414fbda0ca3d618467ef
institution Directory Open Access Journal
issn 2075-4442
language English
last_indexed 2024-03-11T02:13:36Z
publishDate 2023-06-01
publisher MDPI AG
record_format Article
series Lubricants
spelling doaj.art-8b9d0611ae41414fbda0ca3d618467ef2023-11-18T11:19:57ZengMDPI AGLubricants2075-44422023-06-0111626010.3390/lubricants11060260The Enhancement of Overall Performance of Lubricating Grease by Adding Layered Double HydroxidesYong Li0Weidong Zhou1Wanan Xue2Yongwang Huang3Qiang Zhang4Jingbin Han5State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, ChinaState Key Laboratory of Engines, Tianjin University, Tianjin 300350, ChinaGuoneng Beidian Shengli Energy Co., Ltd., Xilinhot 026000, ChinaGrease Branch, Sinopec Lubricant, Co., Ltd., Binhai New Area, Tianjin 300480, ChinaState Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, ChinaState Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, ChinaIn this work, MgAl-layered double hydroxides (LDH) were synthesized by co-precipitation method using a colloid mill and characterized by XRD and SEM. It was found that the environmentally friendly LDHs had greater performance than the traditional antioxidant. By adding LDHs into large electric shovel grease (GRK-A) in open-pit coal mine, the service lifetime of grease was extended by 20%. With the increase in LDH addition, the grease sample attains greater activation energy, and the thermal oxidation and decomposition resistance become stronger. Comparing the energy storage modulus and flow transition index at different temperatures, adding the right amount of LDHs needs close attention for the system oxidation resistance and viscoelasticity. For the electric shovel grease, the best oxidation resistance and rheological properties can be achieved by adding 2% of LDHs. The rheological viscosity–temperature curves show that the grease samples with different ratios of solid LDHs have better low-temperature properties than the mine grease. This work outlines a simple method for creating an environmentally sustainable lubricant additive with the use of LDH. LDH serves as a novel inorganic antioxidant additive that is optimal for open gear lubrication and sliding friction.https://www.mdpi.com/2075-4442/11/6/260layered double hydroxidesgreaseantioxidantoxidative induction time
spellingShingle Yong Li
Weidong Zhou
Wanan Xue
Yongwang Huang
Qiang Zhang
Jingbin Han
The Enhancement of Overall Performance of Lubricating Grease by Adding Layered Double Hydroxides
Lubricants
layered double hydroxides
grease
antioxidant
oxidative induction time
title The Enhancement of Overall Performance of Lubricating Grease by Adding Layered Double Hydroxides
title_full The Enhancement of Overall Performance of Lubricating Grease by Adding Layered Double Hydroxides
title_fullStr The Enhancement of Overall Performance of Lubricating Grease by Adding Layered Double Hydroxides
title_full_unstemmed The Enhancement of Overall Performance of Lubricating Grease by Adding Layered Double Hydroxides
title_short The Enhancement of Overall Performance of Lubricating Grease by Adding Layered Double Hydroxides
title_sort enhancement of overall performance of lubricating grease by adding layered double hydroxides
topic layered double hydroxides
grease
antioxidant
oxidative induction time
url https://www.mdpi.com/2075-4442/11/6/260
work_keys_str_mv AT yongli theenhancementofoverallperformanceoflubricatinggreasebyaddinglayereddoublehydroxides
AT weidongzhou theenhancementofoverallperformanceoflubricatinggreasebyaddinglayereddoublehydroxides
AT wananxue theenhancementofoverallperformanceoflubricatinggreasebyaddinglayereddoublehydroxides
AT yongwanghuang theenhancementofoverallperformanceoflubricatinggreasebyaddinglayereddoublehydroxides
AT qiangzhang theenhancementofoverallperformanceoflubricatinggreasebyaddinglayereddoublehydroxides
AT jingbinhan theenhancementofoverallperformanceoflubricatinggreasebyaddinglayereddoublehydroxides
AT yongli enhancementofoverallperformanceoflubricatinggreasebyaddinglayereddoublehydroxides
AT weidongzhou enhancementofoverallperformanceoflubricatinggreasebyaddinglayereddoublehydroxides
AT wananxue enhancementofoverallperformanceoflubricatinggreasebyaddinglayereddoublehydroxides
AT yongwanghuang enhancementofoverallperformanceoflubricatinggreasebyaddinglayereddoublehydroxides
AT qiangzhang enhancementofoverallperformanceoflubricatinggreasebyaddinglayereddoublehydroxides
AT jingbinhan enhancementofoverallperformanceoflubricatinggreasebyaddinglayereddoublehydroxides