Correlation between phase composition and exchange bias in CoFe/MnN and MnN/CoFe polycrystalline films

Magnetic properties and phase composition of both MnN/CoFe (MnN at top of bilayer) and CoFe/MnN films (MnN at bottom of bilayer) bilayers through annealing at various temperatures (Ta = 300-450 °C) and then cooling to room temperature under the application of an external magnetic field of 1.5 kOe ar...

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Main Authors: H. W. Chang, Y. H. Chien, F. T. Yuan, Y. R. Lai, C. R. Wang, Lance Horng, W. C. Chang
Format: Article
Language:English
Published: AIP Publishing LLC 2020-02-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/1.5129820
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author H. W. Chang
Y. H. Chien
F. T. Yuan
Y. R. Lai
C. R. Wang
Lance Horng
W. C. Chang
author_facet H. W. Chang
Y. H. Chien
F. T. Yuan
Y. R. Lai
C. R. Wang
Lance Horng
W. C. Chang
author_sort H. W. Chang
collection DOAJ
description Magnetic properties and phase composition of both MnN/CoFe (MnN at top of bilayer) and CoFe/MnN films (MnN at bottom of bilayer) bilayers through annealing at various temperatures (Ta = 300-450 °C) and then cooling to room temperature under the application of an external magnetic field of 1.5 kOe are compared. The exchange bias field (HE), the magnitude of magnetic hysteresis loop shift, of the studied films is highly related to phase composition of antiferromagnetic (AF) layer. The increase of HE with increasing Ta in the range of 300-375 °C possibly results from the improvement of magnetocrystalline anisotropy of AF related to the promoted crystallinity and stress relaxation of tetragonal face-centered θ-MnN phase. The reduction of HE at higher Ta is due to the decreased volume fraction or disappearance of θ-MnN phase and the formation of impurity phases, such as Mn4N and Mn. The induction of impurity phases is possibly related to the diffusion of part of N out of MnN phase at higher Ta. Higher HE for CoFe/MnN than MnN/CoFe at Ta = 300-375 °C might be attributed to larger amount and higher degree of stress relaxation for θ-MnN phase. For CoFe/MnN film annealed at 375 °C, the highest HE = 562 Oe is attained, and the corresponding interfacial exchange energy of 0.47 mJ/m2 in this study is comparable to that reported by Meinert et al. [Phys. Rev. B 92, 144408 (2015)].
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spelling doaj.art-8bab83b115ca49978f2abddedfb709962022-12-22T01:59:23ZengAIP Publishing LLCAIP Advances2158-32262020-02-01102025035025035-510.1063/1.5129820Correlation between phase composition and exchange bias in CoFe/MnN and MnN/CoFe polycrystalline filmsH. W. Chang0Y. H. Chien1F. T. Yuan2Y. R. Lai3C. R. Wang4Lance Horng5W. C. Chang6Department of Physics, National Chung Cheng University, Chia-Yi 621, TaiwanDepartment of Applied Physics, Tunghai University, Taichung 407, TaiwaniSentek, Inc. Advanced Sensor Laboratory, New Taipei City 22101, TaiwanDepartment of Applied Physics, Tunghai University, Taichung 407, TaiwanDepartment of Applied Physics, Tunghai University, Taichung 407, TaiwanDepartment of Physics, National Changhua University of Education, Changhua 500, TaiwanDepartment of Physics, National Chung Cheng University, Chia-Yi 621, TaiwanMagnetic properties and phase composition of both MnN/CoFe (MnN at top of bilayer) and CoFe/MnN films (MnN at bottom of bilayer) bilayers through annealing at various temperatures (Ta = 300-450 °C) and then cooling to room temperature under the application of an external magnetic field of 1.5 kOe are compared. The exchange bias field (HE), the magnitude of magnetic hysteresis loop shift, of the studied films is highly related to phase composition of antiferromagnetic (AF) layer. The increase of HE with increasing Ta in the range of 300-375 °C possibly results from the improvement of magnetocrystalline anisotropy of AF related to the promoted crystallinity and stress relaxation of tetragonal face-centered θ-MnN phase. The reduction of HE at higher Ta is due to the decreased volume fraction or disappearance of θ-MnN phase and the formation of impurity phases, such as Mn4N and Mn. The induction of impurity phases is possibly related to the diffusion of part of N out of MnN phase at higher Ta. Higher HE for CoFe/MnN than MnN/CoFe at Ta = 300-375 °C might be attributed to larger amount and higher degree of stress relaxation for θ-MnN phase. For CoFe/MnN film annealed at 375 °C, the highest HE = 562 Oe is attained, and the corresponding interfacial exchange energy of 0.47 mJ/m2 in this study is comparable to that reported by Meinert et al. [Phys. Rev. B 92, 144408 (2015)].http://dx.doi.org/10.1063/1.5129820
spellingShingle H. W. Chang
Y. H. Chien
F. T. Yuan
Y. R. Lai
C. R. Wang
Lance Horng
W. C. Chang
Correlation between phase composition and exchange bias in CoFe/MnN and MnN/CoFe polycrystalline films
AIP Advances
title Correlation between phase composition and exchange bias in CoFe/MnN and MnN/CoFe polycrystalline films
title_full Correlation between phase composition and exchange bias in CoFe/MnN and MnN/CoFe polycrystalline films
title_fullStr Correlation between phase composition and exchange bias in CoFe/MnN and MnN/CoFe polycrystalline films
title_full_unstemmed Correlation between phase composition and exchange bias in CoFe/MnN and MnN/CoFe polycrystalline films
title_short Correlation between phase composition and exchange bias in CoFe/MnN and MnN/CoFe polycrystalline films
title_sort correlation between phase composition and exchange bias in cofe mnn and mnn cofe polycrystalline films
url http://dx.doi.org/10.1063/1.5129820
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