[μ-1,2,3,4-Tetrakis(pyridin-4-yl)butane-κ2N1:N4]bis[trimethyl(thiocyanato-κN)tin(IV)]
In the title compound, [Sn2(CH3)6(NCS)2(C24H22N4)], the 1,2,3,4-tetrakis(pyridin-4-yl)butane ligand uses the pyridine N atoms at the ends of the butyl chain to coordinate to two trimethylthiocyanatotin(IV) units, forming a dinuclear structure. The SnIV atom in the molecule shows a distorted trans-tr...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681204737X |
| _version_ | 1819110679584440320 |
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| author | Ezzatollah Najafi Mostafa M. Amini Seik Weng Ng |
| author_facet | Ezzatollah Najafi Mostafa M. Amini Seik Weng Ng |
| author_sort | Ezzatollah Najafi |
| collection | DOAJ |
| description | In the title compound, [Sn2(CH3)6(NCS)2(C24H22N4)], the 1,2,3,4-tetrakis(pyridin-4-yl)butane ligand uses the pyridine N atoms at the ends of the butyl chain to coordinate to two trimethylthiocyanatotin(IV) units, forming a dinuclear structure. The SnIV atom in the molecule shows a distorted trans-trigonal–bipyramidal coordination with the methyl groups in equatorial positions. The molecule lies on a center of inversion, with the mid-point of the butyl chain coinciding with this symmetry element. In the crystal, weak C—H...π interactions occur between pyridine rings of adjacent molecules. |
| first_indexed | 2024-12-22T03:45:33Z |
| format | Article |
| id | doaj.art-8bbfaa2f91ed4613903595b3daa8b881 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T03:45:33Z |
| publishDate | 2012-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-8bbfaa2f91ed4613903595b3daa8b8812022-12-21T18:40:08ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-12-016812m1550m155010.1107/S160053681204737X[μ-1,2,3,4-Tetrakis(pyridin-4-yl)butane-κ2N1:N4]bis[trimethyl(thiocyanato-κN)tin(IV)]Ezzatollah NajafiMostafa M. AminiSeik Weng NgIn the title compound, [Sn2(CH3)6(NCS)2(C24H22N4)], the 1,2,3,4-tetrakis(pyridin-4-yl)butane ligand uses the pyridine N atoms at the ends of the butyl chain to coordinate to two trimethylthiocyanatotin(IV) units, forming a dinuclear structure. The SnIV atom in the molecule shows a distorted trans-trigonal–bipyramidal coordination with the methyl groups in equatorial positions. The molecule lies on a center of inversion, with the mid-point of the butyl chain coinciding with this symmetry element. In the crystal, weak C—H...π interactions occur between pyridine rings of adjacent molecules.http://scripts.iucr.org/cgi-bin/paper?S160053681204737X |
| spellingShingle | Ezzatollah Najafi Mostafa M. Amini Seik Weng Ng [μ-1,2,3,4-Tetrakis(pyridin-4-yl)butane-κ2N1:N4]bis[trimethyl(thiocyanato-κN)tin(IV)] Acta Crystallographica Section E |
| title | [μ-1,2,3,4-Tetrakis(pyridin-4-yl)butane-κ2N1:N4]bis[trimethyl(thiocyanato-κN)tin(IV)] |
| title_full | [μ-1,2,3,4-Tetrakis(pyridin-4-yl)butane-κ2N1:N4]bis[trimethyl(thiocyanato-κN)tin(IV)] |
| title_fullStr | [μ-1,2,3,4-Tetrakis(pyridin-4-yl)butane-κ2N1:N4]bis[trimethyl(thiocyanato-κN)tin(IV)] |
| title_full_unstemmed | [μ-1,2,3,4-Tetrakis(pyridin-4-yl)butane-κ2N1:N4]bis[trimethyl(thiocyanato-κN)tin(IV)] |
| title_short | [μ-1,2,3,4-Tetrakis(pyridin-4-yl)butane-κ2N1:N4]bis[trimethyl(thiocyanato-κN)tin(IV)] |
| title_sort | amp 956 1 2 3 4 tetrakis pyridin 4 yl butane amp 954 2n1 n4 bis trimethyl thiocyanato amp 954 n tin iv |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053681204737X |
| work_keys_str_mv | AT ezzatollahnajafi amp9561234tetrakispyridin4ylbutaneamp9542n1n4bistrimethylthiocyanatoamp954ntiniv AT mostafamamini amp9561234tetrakispyridin4ylbutaneamp9542n1n4bistrimethylthiocyanatoamp954ntiniv AT seikwengng amp9561234tetrakispyridin4ylbutaneamp9542n1n4bistrimethylthiocyanatoamp954ntiniv |