Dilead(II) trimanganese(II) bis(hydrogenphosphate) bis(phosphate)
The title compound, Pb2Mn3(HPO4)2(PO4)2, was synthesized by a hydrothermal method. All atoms are in general positions except for one Mn atom which is located on an inversion center. The framework of the structure is built up from PO4 tetrahedra and two types of MnO6 octahedra, one almost ideal and t...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812033259 |
| _version_ | 1819002761420734464 |
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| author | Abderrazzak Assani Mohamed Saadi Mohammed Zriouil Lahcen El Ammari |
| author_facet | Abderrazzak Assani Mohamed Saadi Mohammed Zriouil Lahcen El Ammari |
| author_sort | Abderrazzak Assani |
| collection | DOAJ |
| description | The title compound, Pb2Mn3(HPO4)2(PO4)2, was synthesized by a hydrothermal method. All atoms are in general positions except for one Mn atom which is located on an inversion center. The framework of the structure is built up from PO4 tetrahedra and two types of MnO6 octahedra, one almost ideal and the other very distorted with one very long Mn—O bond [2.610 (4) Å compared an average of 2.161 Å for the other bonds]. The centrosymetric octahedron is linked to two distorted MnO6 octahedra by an edge common, forming infinite zigzag Mn3O14 chains running along the b axis. Adjacent chains are linked by PO4 and PO3(OH) tetrahedra through vertices or by edge sharing, forming sheets perpendicular to [100]. The Pb2+ cations are sandwiched between the layers and ensure the cohesion of the crystal structure. O—H...O hydrogen bonding between the layers is also observed. |
| first_indexed | 2024-12-20T23:10:15Z |
| format | Article |
| id | doaj.art-8c0dc30512e54f039c375f313463bea5 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T23:10:15Z |
| publishDate | 2012-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-8c0dc30512e54f039c375f313463bea52022-12-21T19:23:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-08-01688i66i6610.1107/S1600536812033259Dilead(II) trimanganese(II) bis(hydrogenphosphate) bis(phosphate)Abderrazzak AssaniMohamed SaadiMohammed ZriouilLahcen El AmmariThe title compound, Pb2Mn3(HPO4)2(PO4)2, was synthesized by a hydrothermal method. All atoms are in general positions except for one Mn atom which is located on an inversion center. The framework of the structure is built up from PO4 tetrahedra and two types of MnO6 octahedra, one almost ideal and the other very distorted with one very long Mn—O bond [2.610 (4) Å compared an average of 2.161 Å for the other bonds]. The centrosymetric octahedron is linked to two distorted MnO6 octahedra by an edge common, forming infinite zigzag Mn3O14 chains running along the b axis. Adjacent chains are linked by PO4 and PO3(OH) tetrahedra through vertices or by edge sharing, forming sheets perpendicular to [100]. The Pb2+ cations are sandwiched between the layers and ensure the cohesion of the crystal structure. O—H...O hydrogen bonding between the layers is also observed.http://scripts.iucr.org/cgi-bin/paper?S1600536812033259 |
| spellingShingle | Abderrazzak Assani Mohamed Saadi Mohammed Zriouil Lahcen El Ammari Dilead(II) trimanganese(II) bis(hydrogenphosphate) bis(phosphate) Acta Crystallographica Section E |
| title | Dilead(II) trimanganese(II) bis(hydrogenphosphate) bis(phosphate) |
| title_full | Dilead(II) trimanganese(II) bis(hydrogenphosphate) bis(phosphate) |
| title_fullStr | Dilead(II) trimanganese(II) bis(hydrogenphosphate) bis(phosphate) |
| title_full_unstemmed | Dilead(II) trimanganese(II) bis(hydrogenphosphate) bis(phosphate) |
| title_short | Dilead(II) trimanganese(II) bis(hydrogenphosphate) bis(phosphate) |
| title_sort | dilead ii trimanganese ii bis hydrogenphosphate bis phosphate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812033259 |
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