NEW ENVIRONMENTALLY FRIENDLY COMPOSITIONS AS INHIBITORS OF METAL CORROSION
The development of effective and safe corrosion inhibitors of metal constructions remains an urgent problem. The aim of the present study is evaluation of inhibitory action of new compositions based on synthetic and biogenic surfactants, waste glycerol (a by-product of biodiesel) and low-toxic bioci...
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| Format: | Article |
| Language: | English |
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2023-03-01
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| Series: | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
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| Online Access: | https://pubs.ub.ro/?pg=revues&rev=cscc6&num=202301&vol=1&aid=5531 |
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| author | IHOR SEMENIUK OLENA KARPENKO АNDRIY BANYA VIRA LUBЕNETS SERGIY SHAPOVALENKO GUO PENGXIANG |
| author_facet | IHOR SEMENIUK OLENA KARPENKO АNDRIY BANYA VIRA LUBЕNETS SERGIY SHAPOVALENKO GUO PENGXIANG |
| author_sort | IHOR SEMENIUK |
| collection | DOAJ |
| description | The development of effective and safe corrosion inhibitors of metal constructions remains an urgent problem. The aim of the present study is evaluation of inhibitory action of new compositions based on synthetic and biogenic surfactants, waste glycerol (a by-product of biodiesel) and low-toxic biocides-thiosulfonates, on the corrosion of St3 steel in different concentrations of sodium chloride aqueous solutions, at various temperatures. It was shown, that at 20 °C in medium NaCl (0.1 and 1.0 wt %) the best protective properties have mixtures of biosurfactant BS-1 with Tween-80 (1:5 and 1:3, w/w) – protection degree in 0.1 % NaCl was 69 and 61 %, respectively. With temperature increased to 50 °C, the protection degree decreased to 63 and 48 %. Waste glycerol (5 g·dm-3) in 1% NaCl also proved effectiveness, increasing St3 steel protection up to 86 %. When using biosurfactants and waste glycerol, the film on the metal surface formed due to hydrogen bonds between inhibitors functional groups and iron ions probably decreased the corrosion rate of steel. Compositions of biosurfactant BS-2 with thiosulfonates TS-1, TS-2 (ratio 0.5 and 0.25 g·dm-3) at 20 °C contribute to steel protection 99 %. Thus, action synergism was observed, therefore for effective steel protection it is advisable to use additional synergists into composition. The results indicate new prospects of compositions of biosurfactants, products of biotechnology, for new "green" corrosion inhibitors. |
| first_indexed | 2024-04-09T13:36:14Z |
| format | Article |
| id | doaj.art-8c302d26b3a64a959e95626a5831c816 |
| institution | Directory Open Access Journal |
| issn | 1582-540X |
| language | English |
| last_indexed | 2024-04-09T13:36:14Z |
| publishDate | 2023-03-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
| spelling | doaj.art-8c302d26b3a64a959e95626a5831c8162023-05-09T08:22:09ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X2023-03-01241041048NEW ENVIRONMENTALLY FRIENDLY COMPOSITIONS AS INHIBITORS OF METAL CORROSIONIHOR SEMENIUK 0 OLENA KARPENKO1АNDRIY BANYA 2 VIRA LUBЕNETS3SERGIY SHAPOVALENKO 4GUO PENGXIANG 51. National Academy of Sciences of Ukraine, L. M. Lytvynenko Institute of Physical-Organic Chemistry and Coal Chemistry, Department of Physical Chemistry of Fossil Fuels, 3a Naukova str., 79060, Lviv, Ukraine 4. Foshan Tianheng New Material Technology Co., Ltd, No.143 Dongxiu Road, Nanhai District, Foshan City, 528200, Guangdong Province P.R. China1. National Academy of Sciences of Ukraine, L. M. Lytvynenko Institute of Physical-Organic Chemistry and Coal Chemistry, Department of Physical Chemistry of Fossil Fuels, 3a Naukova str., 79060, Lviv, Ukraine 2. Lviv Polytechnic National University, 12 S. Bandery str., 79013, Lviv, Ukraine1. National Academy of Sciences of Ukraine, L. M. Lytvynenko Institute of Physical-Organic Chemistry and Coal Chemistry, Department of Physical Chemistry of Fossil Fuels, 3a Naukova str., 79060, Lviv, Ukraine2. Lviv Polytechnic National University, 12 S. Bandery str., 79013, Lviv, Ukraine3. Guangzhou Tianheng Innovation Technology Co., Ltd., Lihai Ivzhou Huayuan A5 A704, Baiyun district Guangzhou, 510000, Guangdong Province P.R. China3. Guangzhou Tianheng Innovation Technology Co., Ltd., Lihai Ivzhou Huayuan A5 A704, Baiyun district Guangzhou, 510000, Guangdong Province P.R. ChinaThe development of effective and safe corrosion inhibitors of metal constructions remains an urgent problem. The aim of the present study is evaluation of inhibitory action of new compositions based on synthetic and biogenic surfactants, waste glycerol (a by-product of biodiesel) and low-toxic biocides-thiosulfonates, on the corrosion of St3 steel in different concentrations of sodium chloride aqueous solutions, at various temperatures. It was shown, that at 20 °C in medium NaCl (0.1 and 1.0 wt %) the best protective properties have mixtures of biosurfactant BS-1 with Tween-80 (1:5 and 1:3, w/w) – protection degree in 0.1 % NaCl was 69 and 61 %, respectively. With temperature increased to 50 °C, the protection degree decreased to 63 and 48 %. Waste glycerol (5 g·dm-3) in 1% NaCl also proved effectiveness, increasing St3 steel protection up to 86 %. When using biosurfactants and waste glycerol, the film on the metal surface formed due to hydrogen bonds between inhibitors functional groups and iron ions probably decreased the corrosion rate of steel. Compositions of biosurfactant BS-2 with thiosulfonates TS-1, TS-2 (ratio 0.5 and 0.25 g·dm-3) at 20 °C contribute to steel protection 99 %. Thus, action synergism was observed, therefore for effective steel protection it is advisable to use additional synergists into composition. The results indicate new prospects of compositions of biosurfactants, products of biotechnology, for new "green" corrosion inhibitors.https://pubs.ub.ro/?pg=revues&rev=cscc6&num=202301&vol=1&aid=5531biosurfactantscorrosion inhibitorsrhamnolipidsthiosulfonatestrehalose lipidswaste glycerol. |
| spellingShingle | IHOR SEMENIUK OLENA KARPENKO АNDRIY BANYA VIRA LUBЕNETS SERGIY SHAPOVALENKO GUO PENGXIANG NEW ENVIRONMENTALLY FRIENDLY COMPOSITIONS AS INHIBITORS OF METAL CORROSION Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry biosurfactants corrosion inhibitors rhamnolipids thiosulfonates trehalose lipids waste glycerol. |
| title | NEW ENVIRONMENTALLY FRIENDLY COMPOSITIONS AS INHIBITORS OF METAL CORROSION |
| title_full | NEW ENVIRONMENTALLY FRIENDLY COMPOSITIONS AS INHIBITORS OF METAL CORROSION |
| title_fullStr | NEW ENVIRONMENTALLY FRIENDLY COMPOSITIONS AS INHIBITORS OF METAL CORROSION |
| title_full_unstemmed | NEW ENVIRONMENTALLY FRIENDLY COMPOSITIONS AS INHIBITORS OF METAL CORROSION |
| title_short | NEW ENVIRONMENTALLY FRIENDLY COMPOSITIONS AS INHIBITORS OF METAL CORROSION |
| title_sort | new environmentally friendly compositions as inhibitors of metal corrosion |
| topic | biosurfactants corrosion inhibitors rhamnolipids thiosulfonates trehalose lipids waste glycerol. |
| url | https://pubs.ub.ro/?pg=revues&rev=cscc6&num=202301&vol=1&aid=5531 |
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