Degradation of glycerol to ethanol using x/Y zeolite (x=H, Ni, Mo, NiMo) catalyst by sonication method
The performance of the Y Zeolite (YZ) catalyst can be improved by metal impregnation. The purposes of this study were to determine the characteristics and effectenes of the H/YZ, Ni/YZ, Mo/YZ, and NiMo/YZ catalyst, and the effect of the time of sonication on the glycerol degradation reaction to eth...
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| Format: | Article |
| Language: | English |
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Turkish Chemical Society
2024-02-01
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| Series: | Journal of the Turkish Chemical Society, Section A: Chemistry |
| Subjects: | |
| Online Access: | https://dergipark.org.tr/tr/download/article-file/3004289 |
| _version_ | 1797215240431075328 |
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| author | Muhammad Roy Asrori Nazriati Nazriati Aman Santoso Siti Khoirun Nisak Sumari Sumari |
| author_facet | Muhammad Roy Asrori Nazriati Nazriati Aman Santoso Siti Khoirun Nisak Sumari Sumari |
| author_sort | Muhammad Roy Asrori |
| collection | DOAJ |
| description | The performance of the Y Zeolite (YZ) catalyst can be improved by metal impregnation. The purposes of this study were to determine the characteristics and effectenes of the H/YZ, Ni/YZ, Mo/YZ, and NiMo/YZ catalyst, and the effect of the time of sonication on the glycerol degradation reaction to ethanol using the sonication method. The study began with the preparation and activation of YZ using NH4Cl 1M solution. The activated YZ was then impregnated with nickel metal, molybdenum metal, and their mixtures. Catalyst characterization using XRD, XRF, acidity test, and surface area test. As a result, (a) nickel and molybdenum metals successfully impregnated into YZ, (b) H/YZ, Ni/YZ, Mo/YZ (Predictable), and NiMo/YZ (Predictable) catalysts had a crystalline phase, (c) the highest catalyst acidity value was NiMo/YZ of 1.0810 mmol/gram, (d) the largest catalyst surface area was H/YZ of 110.321 m2/g. The NiMo/YZ catalyst is more effective than the H/YZ, Ni/YZ, and NiMo/YZ, because it produced the highest %yield ethanol both at 4 hours (4.49%) and 6 hours (27.33%). The time of sonication greatly influenced the percentage of ethanol yield in the glycerol degradation reaction. The longer the time of sonication, the higher % the yield of ethanol produced. |
| first_indexed | 2024-04-24T11:26:55Z |
| format | Article |
| id | doaj.art-8c567ca7ce754e26b28a68db2329767f |
| institution | Directory Open Access Journal |
| issn | 2149-0120 |
| language | English |
| last_indexed | 2024-04-24T11:26:55Z |
| publishDate | 2024-02-01 |
| publisher | Turkish Chemical Society |
| record_format | Article |
| series | Journal of the Turkish Chemical Society, Section A: Chemistry |
| spelling | doaj.art-8c567ca7ce754e26b28a68db2329767f2024-04-10T16:03:42ZengTurkish Chemical SocietyJournal of the Turkish Chemical Society, Section A: Chemistry2149-01202024-02-0111193100182Degradation of glycerol to ethanol using x/Y zeolite (x=H, Ni, Mo, NiMo) catalyst by sonication methodMuhammad Roy Asrori0Nazriati Nazriati1Aman Santoso2Siti Khoirun Nisak3Sumari Sumari4Universitas Negeri MalangUniversitas Negeri MalangUniversitas Negeri MalangUniversitas Negeri MalangState University of MalangThe performance of the Y Zeolite (YZ) catalyst can be improved by metal impregnation. The purposes of this study were to determine the characteristics and effectenes of the H/YZ, Ni/YZ, Mo/YZ, and NiMo/YZ catalyst, and the effect of the time of sonication on the glycerol degradation reaction to ethanol using the sonication method. The study began with the preparation and activation of YZ using NH4Cl 1M solution. The activated YZ was then impregnated with nickel metal, molybdenum metal, and their mixtures. Catalyst characterization using XRD, XRF, acidity test, and surface area test. As a result, (a) nickel and molybdenum metals successfully impregnated into YZ, (b) H/YZ, Ni/YZ, Mo/YZ (Predictable), and NiMo/YZ (Predictable) catalysts had a crystalline phase, (c) the highest catalyst acidity value was NiMo/YZ of 1.0810 mmol/gram, (d) the largest catalyst surface area was H/YZ of 110.321 m2/g. The NiMo/YZ catalyst is more effective than the H/YZ, Ni/YZ, and NiMo/YZ, because it produced the highest %yield ethanol both at 4 hours (4.49%) and 6 hours (27.33%). The time of sonication greatly influenced the percentage of ethanol yield in the glycerol degradation reaction. The longer the time of sonication, the higher % the yield of ethanol produced.https://dergipark.org.tr/tr/download/article-file/3004289glycerolethanolimpregnationsonicationy zeolite |
| spellingShingle | Muhammad Roy Asrori Nazriati Nazriati Aman Santoso Siti Khoirun Nisak Sumari Sumari Degradation of glycerol to ethanol using x/Y zeolite (x=H, Ni, Mo, NiMo) catalyst by sonication method Journal of the Turkish Chemical Society, Section A: Chemistry glycerol ethanol impregnation sonication y zeolite |
| title | Degradation of glycerol to ethanol using x/Y zeolite (x=H, Ni, Mo, NiMo) catalyst by sonication method |
| title_full | Degradation of glycerol to ethanol using x/Y zeolite (x=H, Ni, Mo, NiMo) catalyst by sonication method |
| title_fullStr | Degradation of glycerol to ethanol using x/Y zeolite (x=H, Ni, Mo, NiMo) catalyst by sonication method |
| title_full_unstemmed | Degradation of glycerol to ethanol using x/Y zeolite (x=H, Ni, Mo, NiMo) catalyst by sonication method |
| title_short | Degradation of glycerol to ethanol using x/Y zeolite (x=H, Ni, Mo, NiMo) catalyst by sonication method |
| title_sort | degradation of glycerol to ethanol using x y zeolite x h ni mo nimo catalyst by sonication method |
| topic | glycerol ethanol impregnation sonication y zeolite |
| url | https://dergipark.org.tr/tr/download/article-file/3004289 |
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