Synthesis, Characterization and Antibacterial activities of Uracil and Uracil–Oxalate Complexes with Cr(III) and Fe(III)
New complexes of the some trivalent transition metal ions of the uracil such as [M(Ura)3Cl3] and mixed ligand metal complexes with uracil and oxalic acid [M(Ura)2(OA)(OH2)Cl].H2O type, where (Ura)=Uracil, (OA= Oxalic acid dihydrate, (M= Cr+3 and Fe+3) were synthesized and characterized by the elemen...
| Main Author: | |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Unviversity of Technology- Iraq
2019-04-01
|
| Series: | Engineering and Technology Journal |
| Subjects: | |
| Online Access: | https://etj.uotechnology.edu.iq/article_168824_cafb9cdfb9b3147d70ac93f7d5d6844a.pdf |
| _version_ | 1797326090026352640 |
|---|---|
| author | Shatha Obaid |
| author_facet | Shatha Obaid |
| author_sort | Shatha Obaid |
| collection | DOAJ |
| description | New complexes of the some trivalent transition metal ions of the uracil such as [M(Ura)3Cl3] and mixed ligand metal complexes with uracil and oxalic acid [M(Ura)2(OA)(OH2)Cl].H2O type, where (Ura)=Uracil, (OA= Oxalic acid dihydrate, (M= Cr+3 and Fe+3) were synthesized and characterized by the elemental analysis, FT.IR, electronic spectra, mass spectra and magnetic susceptibility as well as the conductivity measurements. Six–coordinated metal complexes were suggested for the isolated complexes of Cr+3 and Fe+3 with molecular formulas dependent on the nature of uracil and oxalic acid present. The proposed molecular structure for all complexes with their ions is octahedral geometries. The antibacterial efficiency was tested of metal salts, ligands and metal complexes to the pathogenic bacteria activity have been studied. |
| first_indexed | 2024-03-08T06:18:33Z |
| format | Article |
| id | doaj.art-8c58db5a22364d00933cb48850a12d51 |
| institution | Directory Open Access Journal |
| issn | 1681-6900 2412-0758 |
| language | English |
| last_indexed | 2024-03-08T06:18:33Z |
| publishDate | 2019-04-01 |
| publisher | Unviversity of Technology- Iraq |
| record_format | Article |
| series | Engineering and Technology Journal |
| spelling | doaj.art-8c58db5a22364d00933cb48850a12d512024-02-04T17:11:15ZengUnviversity of Technology- IraqEngineering and Technology Journal1681-69002412-07582019-04-01371B61610.30684/etj.37.1B.2168824Synthesis, Characterization and Antibacterial activities of Uracil and Uracil–Oxalate Complexes with Cr(III) and Fe(III)Shatha Obaid0Chemistry DepartmentEducation College of Pure Sciences - Ibn AlHaitham, University of Baghdad, Baghdad - IraqNew complexes of the some trivalent transition metal ions of the uracil such as [M(Ura)3Cl3] and mixed ligand metal complexes with uracil and oxalic acid [M(Ura)2(OA)(OH2)Cl].H2O type, where (Ura)=Uracil, (OA= Oxalic acid dihydrate, (M= Cr+3 and Fe+3) were synthesized and characterized by the elemental analysis, FT.IR, electronic spectra, mass spectra and magnetic susceptibility as well as the conductivity measurements. Six–coordinated metal complexes were suggested for the isolated complexes of Cr+3 and Fe+3 with molecular formulas dependent on the nature of uracil and oxalic acid present. The proposed molecular structure for all complexes with their ions is octahedral geometries. The antibacterial efficiency was tested of metal salts, ligands and metal complexes to the pathogenic bacteria activity have been studied.https://etj.uotechnology.edu.iq/article_168824_cafb9cdfb9b3147d70ac93f7d5d6844a.pdfuraciloxalic acid dihydratemixed ligand complexeselemental analysisspectral studiesbiological efficiency |
| spellingShingle | Shatha Obaid Synthesis, Characterization and Antibacterial activities of Uracil and Uracil–Oxalate Complexes with Cr(III) and Fe(III) Engineering and Technology Journal uracil oxalic acid dihydrate mixed ligand complexes elemental analysis spectral studies biological efficiency |
| title | Synthesis, Characterization and Antibacterial activities of Uracil and Uracil–Oxalate Complexes with Cr(III) and Fe(III) |
| title_full | Synthesis, Characterization and Antibacterial activities of Uracil and Uracil–Oxalate Complexes with Cr(III) and Fe(III) |
| title_fullStr | Synthesis, Characterization and Antibacterial activities of Uracil and Uracil–Oxalate Complexes with Cr(III) and Fe(III) |
| title_full_unstemmed | Synthesis, Characterization and Antibacterial activities of Uracil and Uracil–Oxalate Complexes with Cr(III) and Fe(III) |
| title_short | Synthesis, Characterization and Antibacterial activities of Uracil and Uracil–Oxalate Complexes with Cr(III) and Fe(III) |
| title_sort | synthesis characterization and antibacterial activities of uracil and uracil oxalate complexes with cr iii and fe iii |
| topic | uracil oxalic acid dihydrate mixed ligand complexes elemental analysis spectral studies biological efficiency |
| url | https://etj.uotechnology.edu.iq/article_168824_cafb9cdfb9b3147d70ac93f7d5d6844a.pdf |
| work_keys_str_mv | AT shathaobaid synthesischaracterizationandantibacterialactivitiesofuracilanduraciloxalatecomplexeswithcriiiandfeiii |