Syntheses, Characterization, Crystal Structures and Antimicrobial Activity of Schiff Base Copper(II) Complexes Derived from 2-Bromo-6-((2-(isopropylamino)ethylimino)methyl)phenol
Three new copper(II) complexes, [Cu(LH)2]Br2 (1), [Cu(LH)2]NCS2 (2), and [Cu(LH)2](NO3)2 (3), where LH is the zwitterionic form of 2-bromo-6-((2-(isopropylamino)ethylimino)methyl)phenol (HL), were synthesized and characterized by elemental analysis, IR and UV-vis spectroscopy. The structures of the...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Slovenian Chemical Society
2021-12-01
|
| Series: | Acta Chimica Slovenica |
| Subjects: | |
| Online Access: | https://journals.matheo.si/index.php/ACSi/article/view/7070 |
| _version_ | 1819177861646385152 |
|---|---|
| author | Yong Yuan Xi-Kun Lu Gao-Qi Zhou Xiao-Yang Qiu |
| author_facet | Yong Yuan Xi-Kun Lu Gao-Qi Zhou Xiao-Yang Qiu |
| author_sort | Yong Yuan |
| collection | DOAJ |
| description | Three new copper(II) complexes, [Cu(LH)2]Br2 (1), [Cu(LH)2]NCS2 (2), and [Cu(LH)2](NO3)2 (3), where LH is the zwitterionic form of 2-bromo-6-((2-(isopropylamino)ethylimino)methyl)phenol (HL), were synthesized and characterized by elemental analysis, IR and UV-vis spectroscopy. The structures of the complexes were further confirmed by single crystal X-ray structure determination. All compounds are mononuclear copper(II) complexes. The Cu atoms in the complexes are coordinated by two imino N and two phenolate O atoms from two LH ligands, forming square planar coordination. The compounds were assayed for their antimicrobial activities. |
| first_indexed | 2024-12-22T21:33:23Z |
| format | Article |
| id | doaj.art-8c5ad04305b2486cb3c2ad2ea7a747f4 |
| institution | Directory Open Access Journal |
| issn | 1318-0207 1580-3155 |
| language | English |
| last_indexed | 2024-12-22T21:33:23Z |
| publishDate | 2021-12-01 |
| publisher | Slovenian Chemical Society |
| record_format | Article |
| series | Acta Chimica Slovenica |
| spelling | doaj.art-8c5ad04305b2486cb3c2ad2ea7a747f42022-12-21T18:11:51ZengSlovenian Chemical SocietyActa Chimica Slovenica1318-02071580-31552021-12-016841008101510.17344/acsi.2021.70701032Syntheses, Characterization, Crystal Structures and Antimicrobial Activity of Schiff Base Copper(II) Complexes Derived from 2-Bromo-6-((2-(isopropylamino)ethylimino)methyl)phenolYong Yuan0Xi-Kun Lu1Gao-Qi Zhou2Xiao-Yang Qiu3ZhouKou Vocational and Technical CollegeZhouKou Vocational and Technical CollegeNingbo UniversityNingbo UniversityThree new copper(II) complexes, [Cu(LH)2]Br2 (1), [Cu(LH)2]NCS2 (2), and [Cu(LH)2](NO3)2 (3), where LH is the zwitterionic form of 2-bromo-6-((2-(isopropylamino)ethylimino)methyl)phenol (HL), were synthesized and characterized by elemental analysis, IR and UV-vis spectroscopy. The structures of the complexes were further confirmed by single crystal X-ray structure determination. All compounds are mononuclear copper(II) complexes. The Cu atoms in the complexes are coordinated by two imino N and two phenolate O atoms from two LH ligands, forming square planar coordination. The compounds were assayed for their antimicrobial activities.https://journals.matheo.si/index.php/ACSi/article/view/7070schiff basecopper complexcrystal structureantimicrobial activity |
| spellingShingle | Yong Yuan Xi-Kun Lu Gao-Qi Zhou Xiao-Yang Qiu Syntheses, Characterization, Crystal Structures and Antimicrobial Activity of Schiff Base Copper(II) Complexes Derived from 2-Bromo-6-((2-(isopropylamino)ethylimino)methyl)phenol Acta Chimica Slovenica schiff base copper complex crystal structure antimicrobial activity |
| title | Syntheses, Characterization, Crystal Structures and Antimicrobial Activity of Schiff Base Copper(II) Complexes Derived from 2-Bromo-6-((2-(isopropylamino)ethylimino)methyl)phenol |
| title_full | Syntheses, Characterization, Crystal Structures and Antimicrobial Activity of Schiff Base Copper(II) Complexes Derived from 2-Bromo-6-((2-(isopropylamino)ethylimino)methyl)phenol |
| title_fullStr | Syntheses, Characterization, Crystal Structures and Antimicrobial Activity of Schiff Base Copper(II) Complexes Derived from 2-Bromo-6-((2-(isopropylamino)ethylimino)methyl)phenol |
| title_full_unstemmed | Syntheses, Characterization, Crystal Structures and Antimicrobial Activity of Schiff Base Copper(II) Complexes Derived from 2-Bromo-6-((2-(isopropylamino)ethylimino)methyl)phenol |
| title_short | Syntheses, Characterization, Crystal Structures and Antimicrobial Activity of Schiff Base Copper(II) Complexes Derived from 2-Bromo-6-((2-(isopropylamino)ethylimino)methyl)phenol |
| title_sort | syntheses characterization crystal structures and antimicrobial activity of schiff base copper ii complexes derived from 2 bromo 6 2 isopropylamino ethylimino methyl phenol |
| topic | schiff base copper complex crystal structure antimicrobial activity |
| url | https://journals.matheo.si/index.php/ACSi/article/view/7070 |
| work_keys_str_mv | AT yongyuan synthesescharacterizationcrystalstructuresandantimicrobialactivityofschiffbasecopperiicomplexesderivedfrom2bromo62isopropylaminoethyliminomethylphenol AT xikunlu synthesescharacterizationcrystalstructuresandantimicrobialactivityofschiffbasecopperiicomplexesderivedfrom2bromo62isopropylaminoethyliminomethylphenol AT gaoqizhou synthesescharacterizationcrystalstructuresandantimicrobialactivityofschiffbasecopperiicomplexesderivedfrom2bromo62isopropylaminoethyliminomethylphenol AT xiaoyangqiu synthesescharacterizationcrystalstructuresandantimicrobialactivityofschiffbasecopperiicomplexesderivedfrom2bromo62isopropylaminoethyliminomethylphenol |