(5-Methylpyrazine-2-carboxylato-κ2N1,O)bis[2-(4-methylpyridin-2-yl-κN)-3,5-bis(trifluoromethyl)phenyl-κC1]iridium(III) chloroform hemisolvate
In the title complex, [Ir(C14H8F6N)2(C6H5N2O2)]·0.5CHCl3, the IrIII atom adopts a distorted octahedral geometry, being coordinated by three N atoms (arranged meridionally), two C atoms and one O atom of three bidentate ligands. The complex molecules pack with no specific intermolecular interactions...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813034727 |
| _version_ | 1798031480895569920 |
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| author | Young-Inn Kim Young-Kwang Song Sung Kwon Kang |
| author_facet | Young-Inn Kim Young-Kwang Song Sung Kwon Kang |
| author_sort | Young-Inn Kim |
| collection | DOAJ |
| description | In the title complex, [Ir(C14H8F6N)2(C6H5N2O2)]·0.5CHCl3, the IrIII atom adopts a distorted octahedral geometry, being coordinated by three N atoms (arranged meridionally), two C atoms and one O atom of three bidentate ligands. The complex molecules pack with no specific intermolecular interactions between them. The SQUEEZE procedure in PLATON [Spek (2009). Acta Cryst. D65, 148–155] was used to model a disordered chloroform solvent molecule; the calculated unit-cell data allow for the presence of half of this molecule in the asymmetric unit. |
| first_indexed | 2024-04-11T19:58:13Z |
| format | Article |
| id | doaj.art-8c625a1d0013493191cdb9c3f78fcd44 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T19:58:13Z |
| publishDate | 2014-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-8c625a1d0013493191cdb9c3f78fcd442022-12-22T04:05:50ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-02-01702m34m3410.1107/S1600536813034727tk5282(5-Methylpyrazine-2-carboxylato-κ2N1,O)bis[2-(4-methylpyridin-2-yl-κN)-3,5-bis(trifluoromethyl)phenyl-κC1]iridium(III) chloroform hemisolvateYoung-Inn Kim0Young-Kwang Song1Sung Kwon Kang2Department of Chemistry Education and Department of Chemical Materials, Graduate School, Pusan National University, Busan 609-735, Republic of KoreaDepartment of Chemistry Education and Department of Chemical Materials, Graduate School, Pusan National University, Busan 609-735, Republic of KoreaDepartment of Chemistry, Chungnam National University, Daejeon 305-764, Republic of KoreaIn the title complex, [Ir(C14H8F6N)2(C6H5N2O2)]·0.5CHCl3, the IrIII atom adopts a distorted octahedral geometry, being coordinated by three N atoms (arranged meridionally), two C atoms and one O atom of three bidentate ligands. The complex molecules pack with no specific intermolecular interactions between them. The SQUEEZE procedure in PLATON [Spek (2009). Acta Cryst. D65, 148–155] was used to model a disordered chloroform solvent molecule; the calculated unit-cell data allow for the presence of half of this molecule in the asymmetric unit.http://scripts.iucr.org/cgi-bin/paper?S1600536813034727 |
| spellingShingle | Young-Inn Kim Young-Kwang Song Sung Kwon Kang (5-Methylpyrazine-2-carboxylato-κ2N1,O)bis[2-(4-methylpyridin-2-yl-κN)-3,5-bis(trifluoromethyl)phenyl-κC1]iridium(III) chloroform hemisolvate Acta Crystallographica Section E |
| title | (5-Methylpyrazine-2-carboxylato-κ2N1,O)bis[2-(4-methylpyridin-2-yl-κN)-3,5-bis(trifluoromethyl)phenyl-κC1]iridium(III) chloroform hemisolvate |
| title_full | (5-Methylpyrazine-2-carboxylato-κ2N1,O)bis[2-(4-methylpyridin-2-yl-κN)-3,5-bis(trifluoromethyl)phenyl-κC1]iridium(III) chloroform hemisolvate |
| title_fullStr | (5-Methylpyrazine-2-carboxylato-κ2N1,O)bis[2-(4-methylpyridin-2-yl-κN)-3,5-bis(trifluoromethyl)phenyl-κC1]iridium(III) chloroform hemisolvate |
| title_full_unstemmed | (5-Methylpyrazine-2-carboxylato-κ2N1,O)bis[2-(4-methylpyridin-2-yl-κN)-3,5-bis(trifluoromethyl)phenyl-κC1]iridium(III) chloroform hemisolvate |
| title_short | (5-Methylpyrazine-2-carboxylato-κ2N1,O)bis[2-(4-methylpyridin-2-yl-κN)-3,5-bis(trifluoromethyl)phenyl-κC1]iridium(III) chloroform hemisolvate |
| title_sort | 5 methylpyrazine 2 carboxylato κ2n1 o bis 2 4 methylpyridin 2 yl κn 3 5 bis trifluoromethyl phenyl κc1 iridium iii chloroform hemisolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813034727 |
| work_keys_str_mv | AT younginnkim 5methylpyrazine2carboxylatok2n1obis24methylpyridin2ylkn35bistrifluoromethylphenylkc1iridiumiiichloroformhemisolvate AT youngkwangsong 5methylpyrazine2carboxylatok2n1obis24methylpyridin2ylkn35bistrifluoromethylphenylkc1iridiumiiichloroformhemisolvate AT sungkwonkang 5methylpyrazine2carboxylatok2n1obis24methylpyridin2ylkn35bistrifluoromethylphenylkc1iridiumiiichloroformhemisolvate |