Efficient Synthesis and Characterization of Polyaniline@Aluminium–Succinate Metal-Organic Frameworks Nanocomposite and Its Application for Zn(II) Ion Sensing
A new class of conductive metal-organic framework (MOF), polyaniline- aluminum succinate (PANI@Al-SA) nanocomposite was prepared by oxidative polymerization of aniline monomer using potassium persulfate as an oxidant. Several analytical techniques such as FTIR, FE-SEM, EDX, XRD, XPS and TGA-DTA were...
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2021-09-01
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author | Amjad E. Alsafrani Waheed A. Adeosun Hadi M. Marwani Imran Khan Mohammad Jawaid Abdullah M. Asiri Anish Khan |
author_facet | Amjad E. Alsafrani Waheed A. Adeosun Hadi M. Marwani Imran Khan Mohammad Jawaid Abdullah M. Asiri Anish Khan |
author_sort | Amjad E. Alsafrani |
collection | DOAJ |
description | A new class of conductive metal-organic framework (MOF), polyaniline- aluminum succinate (PANI@Al-SA) nanocomposite was prepared by oxidative polymerization of aniline monomer using potassium persulfate as an oxidant. Several analytical techniques such as FTIR, FE-SEM, EDX, XRD, XPS and TGA-DTA were utilized to characterize the obtained MOFs nanocomposite. DC electrical conductivity of polymer-MOFs was determined by four probe method. A bare glassy carbon electrode (GCE) was modified by nafion/PANI@Al-SA, and examined for Zn (II) ion detection. Modified electrode showed improved efficiency by 91.9%. The modified electrode (PANI@Al-SA/nafion/GCE) exhibited good catalytic property and highly selectivity towards Zn(II) ion. A linear dynamic range of 2.8–228.6 µM was obtained with detection limit of LOD 0.59 µM and excellent sensitivity of 7.14 µA µM<sup>−1</sup> cm<sup>−2</sup>. The designed procedure for Zn (II) ion detection in real sample exhibited good stability in terms of repeatability, reproducibility and not affected by likely interferents. Therefore, the developed procedure is promising for quantification of Zn(II) ion in real samples. |
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language | English |
last_indexed | 2024-03-10T06:53:10Z |
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spelling | doaj.art-8c6d8dd058024cc090deafba981103e82023-11-22T16:39:50ZengMDPI AGPolymers2073-43602021-09-011319338310.3390/polym13193383Efficient Synthesis and Characterization of Polyaniline@Aluminium–Succinate Metal-Organic Frameworks Nanocomposite and Its Application for Zn(II) Ion SensingAmjad E. Alsafrani0Waheed A. Adeosun1Hadi M. Marwani2Imran Khan3Mohammad Jawaid4Abdullah M. Asiri5Anish Khan6Chemistry Department, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi ArabiaChemistry Department, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi ArabiaChemistry Department, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi ArabiaApplied Sciences and Humanities Section, Faculty of Engineering and Technology, University Polytechnic, Aligarh Muslim University, Aligarh 202002, IndiaLaboratory of Biocomposite Technology, Institute of Tropical Forestry and Forest Products (INTROP), University Putra Malaysia (UPM), Serdang 43400, Selangor, MalaysiaChemistry Department, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi ArabiaChemistry Department, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi ArabiaA new class of conductive metal-organic framework (MOF), polyaniline- aluminum succinate (PANI@Al-SA) nanocomposite was prepared by oxidative polymerization of aniline monomer using potassium persulfate as an oxidant. Several analytical techniques such as FTIR, FE-SEM, EDX, XRD, XPS and TGA-DTA were utilized to characterize the obtained MOFs nanocomposite. DC electrical conductivity of polymer-MOFs was determined by four probe method. A bare glassy carbon electrode (GCE) was modified by nafion/PANI@Al-SA, and examined for Zn (II) ion detection. Modified electrode showed improved efficiency by 91.9%. The modified electrode (PANI@Al-SA/nafion/GCE) exhibited good catalytic property and highly selectivity towards Zn(II) ion. A linear dynamic range of 2.8–228.6 µM was obtained with detection limit of LOD 0.59 µM and excellent sensitivity of 7.14 µA µM<sup>−1</sup> cm<sup>−2</sup>. The designed procedure for Zn (II) ion detection in real sample exhibited good stability in terms of repeatability, reproducibility and not affected by likely interferents. Therefore, the developed procedure is promising for quantification of Zn(II) ion in real samples.https://www.mdpi.com/2073-4360/13/19/3383PANI@Al-SA modified electrodeMOFscompositelinear sweep voltammetry |
spellingShingle | Amjad E. Alsafrani Waheed A. Adeosun Hadi M. Marwani Imran Khan Mohammad Jawaid Abdullah M. Asiri Anish Khan Efficient Synthesis and Characterization of Polyaniline@Aluminium–Succinate Metal-Organic Frameworks Nanocomposite and Its Application for Zn(II) Ion Sensing Polymers PANI@Al-SA modified electrode MOFs composite linear sweep voltammetry |
title | Efficient Synthesis and Characterization of Polyaniline@Aluminium–Succinate Metal-Organic Frameworks Nanocomposite and Its Application for Zn(II) Ion Sensing |
title_full | Efficient Synthesis and Characterization of Polyaniline@Aluminium–Succinate Metal-Organic Frameworks Nanocomposite and Its Application for Zn(II) Ion Sensing |
title_fullStr | Efficient Synthesis and Characterization of Polyaniline@Aluminium–Succinate Metal-Organic Frameworks Nanocomposite and Its Application for Zn(II) Ion Sensing |
title_full_unstemmed | Efficient Synthesis and Characterization of Polyaniline@Aluminium–Succinate Metal-Organic Frameworks Nanocomposite and Its Application for Zn(II) Ion Sensing |
title_short | Efficient Synthesis and Characterization of Polyaniline@Aluminium–Succinate Metal-Organic Frameworks Nanocomposite and Its Application for Zn(II) Ion Sensing |
title_sort | efficient synthesis and characterization of polyaniline aluminium succinate metal organic frameworks nanocomposite and its application for zn ii ion sensing |
topic | PANI@Al-SA modified electrode MOFs composite linear sweep voltammetry |
url | https://www.mdpi.com/2073-4360/13/19/3383 |
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