Zintl Salts Ba2P7X (X = Cl, Br, and I): Synthesis, Crystal, and Electronic Structures

Zintl Salts Ba2P7X (X = Cl, Br, and I): Synthesis, Crystal, and Electronic Structures

Two barium phosphide halides, Ba2P7Br and Ba2P7I, were synthesized and structurally characterized by single crystal X-ray diffraction. Both compounds crystallize in the monoclinic space group P21/m (No. 11) and are isostructural to Ba2P7Cl. The crystal structures of Ba2P7X (X = Cl, Br, I) feature th...

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Bibliographic Details
Main Authors:	Juli-Anna Dolyniuk, Kirill Kovnir
Format:	Article
Language:	English
Published:	MDPI AG 2013-08-01
Series:	Crystals
Subjects:	Zintl phase crystal structure P7 cluster heptaphosphanortricyclane electronic structure electron localization function
Online Access:	http://www.mdpi.com/2073-4352/3/3/431

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