The Influence of CTAB-Capped Seeds and Their Aging Time on the Morphologies of Silver Nanoparticles

Abstract Contrast to the polydisperse nanorods formed by common seed-mediated growth method without the presence of cetyltrimethylammonium bromide (CTAB) in seed solution, we successfully obtained silver nanoparticles with different morphologies in the same reaction system by addition of CTAB in the...

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Main Authors: Wenxiu Jin, Guorun Liang, Yuanzhi Zhong, Yongcong Yuan, Zhichao Jian, Zhixiong Wu, Wanzhong Zhang
Format: Article
Language:English
Published: SpringerOpen 2019-03-01
Series:Nanoscale Research Letters
Subjects:
Online Access:http://link.springer.com/article/10.1186/s11671-019-2898-x
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author Wenxiu Jin
Guorun Liang
Yuanzhi Zhong
Yongcong Yuan
Zhichao Jian
Zhixiong Wu
Wanzhong Zhang
author_facet Wenxiu Jin
Guorun Liang
Yuanzhi Zhong
Yongcong Yuan
Zhichao Jian
Zhixiong Wu
Wanzhong Zhang
author_sort Wenxiu Jin
collection DOAJ
description Abstract Contrast to the polydisperse nanorods formed by common seed-mediated growth method without the presence of cetyltrimethylammonium bromide (CTAB) in seed solution, we successfully obtained silver nanoparticles with different morphologies in the same reaction system by addition of CTAB in the seed solution. In this work, an appropriate amount of CTAB was added into the solution to prepare silver seed crystals. The results show that the aging time of silver seeds have a great influence on the sizes and morphologies of silver nanoparticles and thus the shape-controllable silver nanoparticles can be easily achieved by simply changing the seed aging time. The results also support that the selective adsorption ability or adsorption behavior of TSC can be adjusted by adding CTAB in the preparation procedure of silver seeds. We suggest that different aging times generate different effects on the competitive adsorption between CTAB and citrate to induce the orientation growth of silver seeds. As a result, silver nanospheres, nanorods, and triangular nanoplates can be easily prepared in the same system. In addition, we overcome the time limitation about the use of the seeds by adding CTAB into seed solution and make the synthesis of silver or other metal nanoparticles with different morphologies more easily and more efficiently.
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spelling doaj.art-8c8a6f4813e34f38b6c4dc0109e47c7e2023-08-02T04:01:21ZengSpringerOpenNanoscale Research Letters1931-75731556-276X2019-03-0114111110.1186/s11671-019-2898-xThe Influence of CTAB-Capped Seeds and Their Aging Time on the Morphologies of Silver NanoparticlesWenxiu Jin0Guorun Liang1Yuanzhi Zhong2Yongcong Yuan3Zhichao Jian4Zhixiong Wu5Wanzhong Zhang6Guangdong Provincial Key Laboratory of New Drug Screening, School of Pharmaceutical Sciences, Southern Medical UniversityGuangdong Provincial Key Laboratory of New Drug Screening, School of Pharmaceutical Sciences, Southern Medical UniversityGuangdong Provincial Key Laboratory of New Drug Screening, School of Pharmaceutical Sciences, Southern Medical UniversityGuangdong Provincial Key Laboratory of New Drug Screening, School of Pharmaceutical Sciences, Southern Medical UniversityGuangdong Provincial Key Laboratory of New Drug Screening, School of Pharmaceutical Sciences, Southern Medical UniversityGuangdong Provincial Key Laboratory of New Drug Screening, School of Pharmaceutical Sciences, Southern Medical UniversityGuangdong Provincial Key Laboratory of New Drug Screening, School of Pharmaceutical Sciences, Southern Medical UniversityAbstract Contrast to the polydisperse nanorods formed by common seed-mediated growth method without the presence of cetyltrimethylammonium bromide (CTAB) in seed solution, we successfully obtained silver nanoparticles with different morphologies in the same reaction system by addition of CTAB in the seed solution. In this work, an appropriate amount of CTAB was added into the solution to prepare silver seed crystals. The results show that the aging time of silver seeds have a great influence on the sizes and morphologies of silver nanoparticles and thus the shape-controllable silver nanoparticles can be easily achieved by simply changing the seed aging time. The results also support that the selective adsorption ability or adsorption behavior of TSC can be adjusted by adding CTAB in the preparation procedure of silver seeds. We suggest that different aging times generate different effects on the competitive adsorption between CTAB and citrate to induce the orientation growth of silver seeds. As a result, silver nanospheres, nanorods, and triangular nanoplates can be easily prepared in the same system. In addition, we overcome the time limitation about the use of the seeds by adding CTAB into seed solution and make the synthesis of silver or other metal nanoparticles with different morphologies more easily and more efficiently.http://link.springer.com/article/10.1186/s11671-019-2898-xSilver nanoparticlesSize and morphology controlSeed crystalsAging timeCetyltrimethylammonium bromide
spellingShingle Wenxiu Jin
Guorun Liang
Yuanzhi Zhong
Yongcong Yuan
Zhichao Jian
Zhixiong Wu
Wanzhong Zhang
The Influence of CTAB-Capped Seeds and Their Aging Time on the Morphologies of Silver Nanoparticles
Nanoscale Research Letters
Silver nanoparticles
Size and morphology control
Seed crystals
Aging time
Cetyltrimethylammonium bromide
title The Influence of CTAB-Capped Seeds and Their Aging Time on the Morphologies of Silver Nanoparticles
title_full The Influence of CTAB-Capped Seeds and Their Aging Time on the Morphologies of Silver Nanoparticles
title_fullStr The Influence of CTAB-Capped Seeds and Their Aging Time on the Morphologies of Silver Nanoparticles
title_full_unstemmed The Influence of CTAB-Capped Seeds and Their Aging Time on the Morphologies of Silver Nanoparticles
title_short The Influence of CTAB-Capped Seeds and Their Aging Time on the Morphologies of Silver Nanoparticles
title_sort influence of ctab capped seeds and their aging time on the morphologies of silver nanoparticles
topic Silver nanoparticles
Size and morphology control
Seed crystals
Aging time
Cetyltrimethylammonium bromide
url http://link.springer.com/article/10.1186/s11671-019-2898-x
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