The Influence of CTAB-Capped Seeds and Their Aging Time on the Morphologies of Silver Nanoparticles
Abstract Contrast to the polydisperse nanorods formed by common seed-mediated growth method without the presence of cetyltrimethylammonium bromide (CTAB) in seed solution, we successfully obtained silver nanoparticles with different morphologies in the same reaction system by addition of CTAB in the...
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SpringerOpen
2019-03-01
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Series: | Nanoscale Research Letters |
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Online Access: | http://link.springer.com/article/10.1186/s11671-019-2898-x |
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author | Wenxiu Jin Guorun Liang Yuanzhi Zhong Yongcong Yuan Zhichao Jian Zhixiong Wu Wanzhong Zhang |
author_facet | Wenxiu Jin Guorun Liang Yuanzhi Zhong Yongcong Yuan Zhichao Jian Zhixiong Wu Wanzhong Zhang |
author_sort | Wenxiu Jin |
collection | DOAJ |
description | Abstract Contrast to the polydisperse nanorods formed by common seed-mediated growth method without the presence of cetyltrimethylammonium bromide (CTAB) in seed solution, we successfully obtained silver nanoparticles with different morphologies in the same reaction system by addition of CTAB in the seed solution. In this work, an appropriate amount of CTAB was added into the solution to prepare silver seed crystals. The results show that the aging time of silver seeds have a great influence on the sizes and morphologies of silver nanoparticles and thus the shape-controllable silver nanoparticles can be easily achieved by simply changing the seed aging time. The results also support that the selective adsorption ability or adsorption behavior of TSC can be adjusted by adding CTAB in the preparation procedure of silver seeds. We suggest that different aging times generate different effects on the competitive adsorption between CTAB and citrate to induce the orientation growth of silver seeds. As a result, silver nanospheres, nanorods, and triangular nanoplates can be easily prepared in the same system. In addition, we overcome the time limitation about the use of the seeds by adding CTAB into seed solution and make the synthesis of silver or other metal nanoparticles with different morphologies more easily and more efficiently. |
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spelling | doaj.art-8c8a6f4813e34f38b6c4dc0109e47c7e2023-08-02T04:01:21ZengSpringerOpenNanoscale Research Letters1931-75731556-276X2019-03-0114111110.1186/s11671-019-2898-xThe Influence of CTAB-Capped Seeds and Their Aging Time on the Morphologies of Silver NanoparticlesWenxiu Jin0Guorun Liang1Yuanzhi Zhong2Yongcong Yuan3Zhichao Jian4Zhixiong Wu5Wanzhong Zhang6Guangdong Provincial Key Laboratory of New Drug Screening, School of Pharmaceutical Sciences, Southern Medical UniversityGuangdong Provincial Key Laboratory of New Drug Screening, School of Pharmaceutical Sciences, Southern Medical UniversityGuangdong Provincial Key Laboratory of New Drug Screening, School of Pharmaceutical Sciences, Southern Medical UniversityGuangdong Provincial Key Laboratory of New Drug Screening, School of Pharmaceutical Sciences, Southern Medical UniversityGuangdong Provincial Key Laboratory of New Drug Screening, School of Pharmaceutical Sciences, Southern Medical UniversityGuangdong Provincial Key Laboratory of New Drug Screening, School of Pharmaceutical Sciences, Southern Medical UniversityGuangdong Provincial Key Laboratory of New Drug Screening, School of Pharmaceutical Sciences, Southern Medical UniversityAbstract Contrast to the polydisperse nanorods formed by common seed-mediated growth method without the presence of cetyltrimethylammonium bromide (CTAB) in seed solution, we successfully obtained silver nanoparticles with different morphologies in the same reaction system by addition of CTAB in the seed solution. In this work, an appropriate amount of CTAB was added into the solution to prepare silver seed crystals. The results show that the aging time of silver seeds have a great influence on the sizes and morphologies of silver nanoparticles and thus the shape-controllable silver nanoparticles can be easily achieved by simply changing the seed aging time. The results also support that the selective adsorption ability or adsorption behavior of TSC can be adjusted by adding CTAB in the preparation procedure of silver seeds. We suggest that different aging times generate different effects on the competitive adsorption between CTAB and citrate to induce the orientation growth of silver seeds. As a result, silver nanospheres, nanorods, and triangular nanoplates can be easily prepared in the same system. In addition, we overcome the time limitation about the use of the seeds by adding CTAB into seed solution and make the synthesis of silver or other metal nanoparticles with different morphologies more easily and more efficiently.http://link.springer.com/article/10.1186/s11671-019-2898-xSilver nanoparticlesSize and morphology controlSeed crystalsAging timeCetyltrimethylammonium bromide |
spellingShingle | Wenxiu Jin Guorun Liang Yuanzhi Zhong Yongcong Yuan Zhichao Jian Zhixiong Wu Wanzhong Zhang The Influence of CTAB-Capped Seeds and Their Aging Time on the Morphologies of Silver Nanoparticles Nanoscale Research Letters Silver nanoparticles Size and morphology control Seed crystals Aging time Cetyltrimethylammonium bromide |
title | The Influence of CTAB-Capped Seeds and Their Aging Time on the Morphologies of Silver Nanoparticles |
title_full | The Influence of CTAB-Capped Seeds and Their Aging Time on the Morphologies of Silver Nanoparticles |
title_fullStr | The Influence of CTAB-Capped Seeds and Their Aging Time on the Morphologies of Silver Nanoparticles |
title_full_unstemmed | The Influence of CTAB-Capped Seeds and Their Aging Time on the Morphologies of Silver Nanoparticles |
title_short | The Influence of CTAB-Capped Seeds and Their Aging Time on the Morphologies of Silver Nanoparticles |
title_sort | influence of ctab capped seeds and their aging time on the morphologies of silver nanoparticles |
topic | Silver nanoparticles Size and morphology control Seed crystals Aging time Cetyltrimethylammonium bromide |
url | http://link.springer.com/article/10.1186/s11671-019-2898-x |
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