CONVERSION OF FRUCTOSE TO 5-HYDROXYMETHYLFURFURAL WITH A FUNCTIONALIZED IONIC LIQUID
Fructose can be efficiently converted to 5-hydroxymethylfurfural by using the functionalized ionic liquid 3-(2-chloroethyl)-1-methylimidazolium chloride as both solvent and catalyst in the presence of water. This work advances the field and is distinct from earlier efforts in the sense that the obse...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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North Carolina State University
2011-11-01
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| Series: | BioResources |
| Subjects: | |
| Online Access: | http://ojs.cnr.ncsu.edu/index.php/BioRes/article/view/BioRes_07_1_0533_Ma_ZLA_Conversion_Fructose_Furfural_Ionic_Liquid/1323 |
| _version_ | 1818499822594818048 |
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| author | Hao Ma, Bo Zhou, Yiqun Li, Dimitris S. Argyropoulos |
| author_facet | Hao Ma, Bo Zhou, Yiqun Li, Dimitris S. Argyropoulos |
| author_sort | Hao Ma, |
| collection | DOAJ |
| description | Fructose can be efficiently converted to 5-hydroxymethylfurfural by using the functionalized ionic liquid 3-(2-chloroethyl)-1-methylimidazolium chloride as both solvent and catalyst in the presence of water. This work advances the field and is distinct from earlier efforts in the sense that the observed yields of HMF from fructose are rather high and the reaction conditions rather mild and neutral in the complete absence of acidic additives (HMF yield 76% at 100 oC in 40 minutes). |
| first_indexed | 2024-12-10T20:34:48Z |
| format | Article |
| id | doaj.art-8c931189d934405997534181562f6bab |
| institution | Directory Open Access Journal |
| issn | 1930-2126 |
| language | English |
| last_indexed | 2024-12-10T20:34:48Z |
| publishDate | 2011-11-01 |
| publisher | North Carolina State University |
| record_format | Article |
| series | BioResources |
| spelling | doaj.art-8c931189d934405997534181562f6bab2022-12-22T01:34:35ZengNorth Carolina State UniversityBioResources1930-21262011-11-0171533544CONVERSION OF FRUCTOSE TO 5-HYDROXYMETHYLFURFURAL WITH A FUNCTIONALIZED IONIC LIQUIDHao Ma,Bo Zhou,Yiqun Li,Dimitris S. ArgyropoulosFructose can be efficiently converted to 5-hydroxymethylfurfural by using the functionalized ionic liquid 3-(2-chloroethyl)-1-methylimidazolium chloride as both solvent and catalyst in the presence of water. This work advances the field and is distinct from earlier efforts in the sense that the observed yields of HMF from fructose are rather high and the reaction conditions rather mild and neutral in the complete absence of acidic additives (HMF yield 76% at 100 oC in 40 minutes).http://ojs.cnr.ncsu.edu/index.php/BioRes/article/view/BioRes_07_1_0533_Ma_ZLA_Conversion_Fructose_Furfural_Ionic_Liquid/1323D-Fructose5-Hydroxymethylfurfural1-(2-Chloroethyl)-3-methylimidazolium chlorideCatalytic conversionIonic liquid |
| spellingShingle | Hao Ma, Bo Zhou, Yiqun Li, Dimitris S. Argyropoulos CONVERSION OF FRUCTOSE TO 5-HYDROXYMETHYLFURFURAL WITH A FUNCTIONALIZED IONIC LIQUID BioResources D-Fructose 5-Hydroxymethylfurfural 1-(2-Chloroethyl)-3-methylimidazolium chloride Catalytic conversion Ionic liquid |
| title | CONVERSION OF FRUCTOSE TO 5-HYDROXYMETHYLFURFURAL WITH A FUNCTIONALIZED IONIC LIQUID |
| title_full | CONVERSION OF FRUCTOSE TO 5-HYDROXYMETHYLFURFURAL WITH A FUNCTIONALIZED IONIC LIQUID |
| title_fullStr | CONVERSION OF FRUCTOSE TO 5-HYDROXYMETHYLFURFURAL WITH A FUNCTIONALIZED IONIC LIQUID |
| title_full_unstemmed | CONVERSION OF FRUCTOSE TO 5-HYDROXYMETHYLFURFURAL WITH A FUNCTIONALIZED IONIC LIQUID |
| title_short | CONVERSION OF FRUCTOSE TO 5-HYDROXYMETHYLFURFURAL WITH A FUNCTIONALIZED IONIC LIQUID |
| title_sort | conversion of fructose to 5 hydroxymethylfurfural with a functionalized ionic liquid |
| topic | D-Fructose 5-Hydroxymethylfurfural 1-(2-Chloroethyl)-3-methylimidazolium chloride Catalytic conversion Ionic liquid |
| url | http://ojs.cnr.ncsu.edu/index.php/BioRes/article/view/BioRes_07_1_0533_Ma_ZLA_Conversion_Fructose_Furfural_Ionic_Liquid/1323 |
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