Mechanical and Magnetic Properties of Double Layered Nanostructures of Tin and Zirconium Oxides Grown by Atomic Layer Deposition

Double layered stacks of ZrO<sub>2</sub> and SnO<sub>2</sub> films, aiming at the synthesis of thin magnetic and elastic material layers, were grown by atomic layer deposition to thicknesses in the range of 20–25 nm at 300 °C from ZrCl<sub>4</sub>, SnI<sub>4...

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Bibliographic Details
Main Authors: Aile Tamm, Helle-Mai Piirsoo, Taivo Jõgiaas, Aivar Tarre, Joosep Link, Raivo Stern, Kaupo Kukli
Format: Article
Language:English
Published: MDPI AG 2021-06-01
Series:Nanomaterials
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Online Access:https://www.mdpi.com/2079-4991/11/7/1633
Description
Summary:Double layered stacks of ZrO<sub>2</sub> and SnO<sub>2</sub> films, aiming at the synthesis of thin magnetic and elastic material layers, were grown by atomic layer deposition to thicknesses in the range of 20–25 nm at 300 °C from ZrCl<sub>4</sub>, SnI<sub>4</sub>, H<sub>2</sub>O, and O<sub>3</sub> as precursors. The as-deposited nanostructures consisted of a metastable tetragonal polymorph of ZrO<sub>2</sub>, and a stable tetragonal phase of SnO<sub>2</sub>, with complementary minor reflections from the orthorhombic polymorph of SnO<sub>2</sub>. The hardness and elastic modulus of the stacks depended on the order of the constituent oxide films, reaching 15 and 171 GPa, respectively, in the case of top SnO<sub>2</sub> layers. Nonlinear saturative magnetization could be induced in the stacks with coercive fields up to 130 Oe.
ISSN:2079-4991