Co-Pyrolysis of Peat and Petroleum Containing Waste on Ni and Co Containing Catalysts

The goal of this research is the development of the method of oil-slime recycling. In this work the influence of natural and synthetic aluminosilicates, metal chlorides of iron subgroup on the peat low-temperature pyrolysis and co-pyrolysis of peat with oil-slime and polymeric waste was studied in a...

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Main Authors: Y.Y. Kosivtsov, K.V. Chalov, Y.V. Lugovoy, E.M. Sulman, A.A. Stepacheva
Format: Article
Language:English
Published: AIDIC Servizi S.r.l. 2015-09-01
Series:Chemical Engineering Transactions
Online Access:https://www.cetjournal.it/index.php/cet/article/view/4519
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author Y.Y. Kosivtsov
K.V. Chalov
Y.V. Lugovoy
E.M. Sulman
A.A. Stepacheva
author_facet Y.Y. Kosivtsov
K.V. Chalov
Y.V. Lugovoy
E.M. Sulman
A.A. Stepacheva
author_sort Y.Y. Kosivtsov
collection DOAJ
description The goal of this research is the development of the method of oil-slime recycling. In this work the influence of natural and synthetic aluminosilicates, metal chlorides of iron subgroup on the peat low-temperature pyrolysis and co-pyrolysis of peat with oil-slime and polymeric waste was studied in a variety of conditions (t = 350 – 650 °C, catalyst loading: from 1 up to 30 % wt.). The use of bentonite clay (30 % wt.) at 460 °C as a catalyst in peat pyrolysis resulted in the increase in weight of gaseous and liquid products from 23 up to 30 % wt. and from 32 up to 45 % wt. Co-pyrolysis of peat and oil-slime in the presence of bentonite clay resulted in the increase in gaseous product weight from 18 up to 26 % wt. and liquid fraction yield from 45 up to 55 % wt. in comparison with precalculated value. The use of metal chlorides of iron subgroup (2 % wt. concentration) at 500 °? in the co-pyrolysis of peat and polymeric waste led to optimal conversion of substrate in desired products, 15 % increase of total weight of gaseous and liquid products formed during the pyrolysis process and simultaneous decrease of char formation.
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spelling doaj.art-8cb0ff20ff9947359fd8cdd8ea0a61472022-12-21T20:18:30ZengAIDIC Servizi S.r.l.Chemical Engineering Transactions2283-92162015-09-014510.3303/CET1545112Co-Pyrolysis of Peat and Petroleum Containing Waste on Ni and Co Containing CatalystsY.Y. KosivtsovK.V. ChalovY.V. LugovoyE.M. SulmanA.A. StepachevaThe goal of this research is the development of the method of oil-slime recycling. In this work the influence of natural and synthetic aluminosilicates, metal chlorides of iron subgroup on the peat low-temperature pyrolysis and co-pyrolysis of peat with oil-slime and polymeric waste was studied in a variety of conditions (t = 350 – 650 °C, catalyst loading: from 1 up to 30 % wt.). The use of bentonite clay (30 % wt.) at 460 °C as a catalyst in peat pyrolysis resulted in the increase in weight of gaseous and liquid products from 23 up to 30 % wt. and from 32 up to 45 % wt. Co-pyrolysis of peat and oil-slime in the presence of bentonite clay resulted in the increase in gaseous product weight from 18 up to 26 % wt. and liquid fraction yield from 45 up to 55 % wt. in comparison with precalculated value. The use of metal chlorides of iron subgroup (2 % wt. concentration) at 500 °? in the co-pyrolysis of peat and polymeric waste led to optimal conversion of substrate in desired products, 15 % increase of total weight of gaseous and liquid products formed during the pyrolysis process and simultaneous decrease of char formation.https://www.cetjournal.it/index.php/cet/article/view/4519
spellingShingle Y.Y. Kosivtsov
K.V. Chalov
Y.V. Lugovoy
E.M. Sulman
A.A. Stepacheva
Co-Pyrolysis of Peat and Petroleum Containing Waste on Ni and Co Containing Catalysts
Chemical Engineering Transactions
title Co-Pyrolysis of Peat and Petroleum Containing Waste on Ni and Co Containing Catalysts
title_full Co-Pyrolysis of Peat and Petroleum Containing Waste on Ni and Co Containing Catalysts
title_fullStr Co-Pyrolysis of Peat and Petroleum Containing Waste on Ni and Co Containing Catalysts
title_full_unstemmed Co-Pyrolysis of Peat and Petroleum Containing Waste on Ni and Co Containing Catalysts
title_short Co-Pyrolysis of Peat and Petroleum Containing Waste on Ni and Co Containing Catalysts
title_sort co pyrolysis of peat and petroleum containing waste on ni and co containing catalysts
url https://www.cetjournal.it/index.php/cet/article/view/4519
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AT kvchalov copyrolysisofpeatandpetroleumcontainingwasteonniandcocontainingcatalysts
AT yvlugovoy copyrolysisofpeatandpetroleumcontainingwasteonniandcocontainingcatalysts
AT emsulman copyrolysisofpeatandpetroleumcontainingwasteonniandcocontainingcatalysts
AT aastepacheva copyrolysisofpeatandpetroleumcontainingwasteonniandcocontainingcatalysts