Ethyl 5-oxo-2,3-diphenylcyclopentane-1-carboxylate

The title compound, C20H20O3, was prepared by an acyloin-type condensation reaction in the presence of sodium sand and dry ether using ethyl cinnamate as the starting material. The C—O bond lengths for the carbonyl groups are 1.191 (2) and 1.198 (2)&...

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Bibliographic Details
Main Authors: Claude N. Lamb, Zerihun Assefa, Richard E. Sykora
Format: Article
Language:English
Published: International Union of Crystallography 2010-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810014728
Description
Summary:The title compound, C20H20O3, was prepared by an acyloin-type condensation reaction in the presence of sodium sand and dry ether using ethyl cinnamate as the starting material. The C—O bond lengths for the carbonyl groups are 1.191 (2) and 1.198 (2) Å, while the C—O bond in the ester group is 1.335 (2) Å. The C—C bond lengths in the phenyl groups average 1.375 Å, while the C—C bonds in the cyclopentanone ring average 1.525 Å, indicating single C—C bonds in the latter.
ISSN:1600-5368