trans-Dichloridobis[tris(4-methoxylphenyl)phosphane-κP]platinum(II) acetone disolvate
In the title compound, [PtCl2(C21H21O3P)2]·2C3H6O, the asymmetric unit contains a PtII ion situated on an inversion center, one chloride anion, one tris(4-methoxylphenyl)phosphane (L) ligand and one acetone solvent molecule. The PtII ion is coordinated by two P atoms [Pt—P...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812045643 |
| _version_ | 1819002700242616320 |
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| author | Alfred Muller |
| author_facet | Alfred Muller |
| author_sort | Alfred Muller |
| collection | DOAJ |
| description | In the title compound, [PtCl2(C21H21O3P)2]·2C3H6O, the asymmetric unit contains a PtII ion situated on an inversion center, one chloride anion, one tris(4-methoxylphenyl)phosphane (L) ligand and one acetone solvent molecule. The PtII ion is coordinated by two P atoms [Pt—P = 2.3196 (5) Å] from two L ligands and two chloride anions [Pt—Cl = 2.3075 (5) Å] in a distorted square-planar geometry with P—Pt—Cl angles of 88.016 (16) and 91.984 (16)°. The effective cone angle of the phosphane ligand was calculated to be 156°. Weak C—H...O and C—H...Cl hydrogen bonds hold molecules together. |
| first_indexed | 2024-12-20T23:09:16Z |
| format | Article |
| id | doaj.art-8ce82428fd84405bbba12cce71830889 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T23:09:16Z |
| publishDate | 2012-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-8ce82428fd84405bbba12cce718308892022-12-21T19:23:47ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-12-016812m1475m147510.1107/S1600536812045643trans-Dichloridobis[tris(4-methoxylphenyl)phosphane-κP]platinum(II) acetone disolvateAlfred MullerIn the title compound, [PtCl2(C21H21O3P)2]·2C3H6O, the asymmetric unit contains a PtII ion situated on an inversion center, one chloride anion, one tris(4-methoxylphenyl)phosphane (L) ligand and one acetone solvent molecule. The PtII ion is coordinated by two P atoms [Pt—P = 2.3196 (5) Å] from two L ligands and two chloride anions [Pt—Cl = 2.3075 (5) Å] in a distorted square-planar geometry with P—Pt—Cl angles of 88.016 (16) and 91.984 (16)°. The effective cone angle of the phosphane ligand was calculated to be 156°. Weak C—H...O and C—H...Cl hydrogen bonds hold molecules together.http://scripts.iucr.org/cgi-bin/paper?S1600536812045643 |
| spellingShingle | Alfred Muller trans-Dichloridobis[tris(4-methoxylphenyl)phosphane-κP]platinum(II) acetone disolvate Acta Crystallographica Section E |
| title | trans-Dichloridobis[tris(4-methoxylphenyl)phosphane-κP]platinum(II) acetone disolvate |
| title_full | trans-Dichloridobis[tris(4-methoxylphenyl)phosphane-κP]platinum(II) acetone disolvate |
| title_fullStr | trans-Dichloridobis[tris(4-methoxylphenyl)phosphane-κP]platinum(II) acetone disolvate |
| title_full_unstemmed | trans-Dichloridobis[tris(4-methoxylphenyl)phosphane-κP]platinum(II) acetone disolvate |
| title_short | trans-Dichloridobis[tris(4-methoxylphenyl)phosphane-κP]platinum(II) acetone disolvate |
| title_sort | trans dichloridobis tris 4 methoxylphenyl phosphane amp 954 p platinum ii acetone disolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812045643 |
| work_keys_str_mv | AT alfredmuller transdichloridobistris4methoxylphenylphosphaneamp954pplatinumiiacetonedisolvate |