A multi-analytical study of the palette of impressionist and post-impressionist Puerto Rican artists

Abstract This paper presents the pigment characterization in six impressionist and post-impressionist paintings by three leading Puerto Rican artists: Francisco Oller (1833–1917), José Cuchí y Arnau (1857–1925), and Ramón Frade (1875–1954). The paintings, belonging to the Corporación de las Artes Mu...

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Main Authors: Marc Vermeulen, Annette S. Ortiz Miranda, Diego Tamburini, Sol E. Rivera Delgado, Marc Walton
Format: Article
Language:English
Published: SpringerOpen 2022-04-01
Series:Heritage Science
Subjects:
Online Access:https://doi.org/10.1186/s40494-022-00683-9
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author Marc Vermeulen
Annette S. Ortiz Miranda
Diego Tamburini
Sol E. Rivera Delgado
Marc Walton
author_facet Marc Vermeulen
Annette S. Ortiz Miranda
Diego Tamburini
Sol E. Rivera Delgado
Marc Walton
author_sort Marc Vermeulen
collection DOAJ
description Abstract This paper presents the pigment characterization in six impressionist and post-impressionist paintings by three leading Puerto Rican artists: Francisco Oller (1833–1917), José Cuchí y Arnau (1857–1925), and Ramón Frade (1875–1954). The paintings, belonging to the Corporación de las Artes Musicales and Museo de Arte de Puerto Rico (San Juan, Puerto Rico), were investigated through a combination of complementary non- and micro-invasive scientific techniques. The use of non-invasive macro-X-ray fluorescence (MA-XRF) and reflectance imaging spectroscopy (RIS) was applied for the first time to characterize Puerto Rican artists’ palette. The non-invasive approach was integrated with spectroscopic techniques such as Raman and/or Fourier-transform infrared (FTIR) spectroscopy, as well as high pressure liquid chromatography coupled to diode array detector and tandem mass spectrometry (HPLC-DAD-MS/MS), when sampling was possible. While this technical investigation reveals pigments that are typical for late 19th/early twentieth century paintings, it also emphasizes some unexpected findings, including the use of cobalt green and synthetic yellow lakes, which enabled the date given to some of the paintings to be refined to post 1910 rather than their current dates of ca. 1890. This study confirms that the Puerto Rican artist’s palettes are very similar to their European contemporaries, underscoring both their European training and their attempt to adapt these methods of painting to a new Caribbean identity emerging from the Spanish American War.
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spelling doaj.art-8ceece25dda34c978fc40c3126db201f2022-12-21T17:57:27ZengSpringerOpenHeritage Science2050-74452022-04-0110112210.1186/s40494-022-00683-9A multi-analytical study of the palette of impressionist and post-impressionist Puerto Rican artistsMarc Vermeulen0Annette S. Ortiz Miranda1Diego Tamburini2Sol E. Rivera Delgado3Marc Walton4Northwestern University, Art Institute of Chicago Center for Scientific Studies in the Arts (NU-ACCESS)Northwestern University, Art Institute of Chicago Center for Scientific Studies in the Arts (NU-ACCESS)Department of Scientific Research, The British MuseumMuseo de Arte de Puerto RicoNorthwestern University, Art Institute of Chicago Center for Scientific Studies in the Arts (NU-ACCESS)Abstract This paper presents the pigment characterization in six impressionist and post-impressionist paintings by three leading Puerto Rican artists: Francisco Oller (1833–1917), José Cuchí y Arnau (1857–1925), and Ramón Frade (1875–1954). The paintings, belonging to the Corporación de las Artes Musicales and Museo de Arte de Puerto Rico (San Juan, Puerto Rico), were investigated through a combination of complementary non- and micro-invasive scientific techniques. The use of non-invasive macro-X-ray fluorescence (MA-XRF) and reflectance imaging spectroscopy (RIS) was applied for the first time to characterize Puerto Rican artists’ palette. The non-invasive approach was integrated with spectroscopic techniques such as Raman and/or Fourier-transform infrared (FTIR) spectroscopy, as well as high pressure liquid chromatography coupled to diode array detector and tandem mass spectrometry (HPLC-DAD-MS/MS), when sampling was possible. While this technical investigation reveals pigments that are typical for late 19th/early twentieth century paintings, it also emphasizes some unexpected findings, including the use of cobalt green and synthetic yellow lakes, which enabled the date given to some of the paintings to be refined to post 1910 rather than their current dates of ca. 1890. This study confirms that the Puerto Rican artist’s palettes are very similar to their European contemporaries, underscoring both their European training and their attempt to adapt these methods of painting to a new Caribbean identity emerging from the Spanish American War.https://doi.org/10.1186/s40494-022-00683-9Caribbean artMA-XRFReflectance imaging spectroscopyHPLC-DAD-MS/MSSynthetic organic pigmentsFrancisco Oller
spellingShingle Marc Vermeulen
Annette S. Ortiz Miranda
Diego Tamburini
Sol E. Rivera Delgado
Marc Walton
A multi-analytical study of the palette of impressionist and post-impressionist Puerto Rican artists
Heritage Science
Caribbean art
MA-XRF
Reflectance imaging spectroscopy
HPLC-DAD-MS/MS
Synthetic organic pigments
Francisco Oller
title A multi-analytical study of the palette of impressionist and post-impressionist Puerto Rican artists
title_full A multi-analytical study of the palette of impressionist and post-impressionist Puerto Rican artists
title_fullStr A multi-analytical study of the palette of impressionist and post-impressionist Puerto Rican artists
title_full_unstemmed A multi-analytical study of the palette of impressionist and post-impressionist Puerto Rican artists
title_short A multi-analytical study of the palette of impressionist and post-impressionist Puerto Rican artists
title_sort multi analytical study of the palette of impressionist and post impressionist puerto rican artists
topic Caribbean art
MA-XRF
Reflectance imaging spectroscopy
HPLC-DAD-MS/MS
Synthetic organic pigments
Francisco Oller
url https://doi.org/10.1186/s40494-022-00683-9
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