Summary: | Sodium-22 (<sup>22</sup>Na, half-life 2.603 years) is a cosmogenic radionuclide mainly produced in the stratosphere by nuclear spallation reactions of cosmic rays on <sup>40</sup>Ar. Due to the very low concentration levels normally reached in the environment, <sup>22</sup>Na poses no significant radioprotection threats: actually, the effective doses delivered to humans can hardly exceed a few nSv per year, a very negligible value. However, the measurements of this radionuclides can be very interesting for atmospheric circulation and climatic studies. Unfortunately, the difficulty of <sup>22</sup>Na detection, due to its very low concentration levels, has prevented the gathering of large and widespread time series of this radionuclide. In this paper, a method for the retrospective measurements of <sup>22</sup>Na in the atmosphere, starting from the gamma spectra (hyperpure germanium detectors (HPGe) detectors) of wet and dry deposition samples stored in our databases is proposed and validated. The method was applied to spectra samples gathered in the context of the Italian National Radioactivity Monitoring Network (RESORAD) and allowed the detection of the very low atmospheric activity concentration values of <sup>22</sup>Na present at ground level. The results obtained with the new method are discussed and compared for validation with the available experimental values. Finally, some possible applications to environmental studies are also highlighted and suggested.
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