(Anilino{(Z)-2-[(E)-5-bromo-3-methoxy-2-oxidobenzylidene]hydrazin-1-ylidene-κ2O2,N2}methanethiolato-κS)(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)zinc N,N-dimethylformamide monosolvate
The asymmetric unit of the title compound, [Zn(C15H12BrN3O2S)(C12H12N2)]·C3H7NO, contains two independent molecules with a similar structure. The doubly deprotonated Schiff base ligand O,N,S-chelates to the metal atom, and the three coordinating atoms along with one N atom of the substi...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812031777 |
| Summary: | The asymmetric unit of the title compound, [Zn(C15H12BrN3O2S)(C12H12N2)]·C3H7NO, contains two independent molecules with a similar structure. The doubly deprotonated Schiff base ligand O,N,S-chelates to the metal atom, and the three coordinating atoms along with one N atom of the substituted 2,2′-bipyridine ligand constitute the square plane of the distorted square pyramid surrounding the metal atom. The apical site is occupied by the second N atom of the substituted 2,2′-bipyridine. The secondary amine group of the Schiff base dianion forms a hydrogen bond to the O atom of the dimethylformamide solvent. In the crystal, the phenyl ring of one of the two Schiff base anions is disordered over two positions in a 1:1 ratio. The crystal studied is a racemic twin. |
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| ISSN: | 1600-5368 |