Acid-based hydrolysis processes for ethanol from lignocellulosic materials: A review

Bioethanol is nowadays one of the main actors in the fuel market. It is currently produced from sugars and starchy materials, but lignocelluloses can be expected to be major feedstocks for ethanol production in the future. Two processes are being developed in parallel for conversion of lignocellulos...

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Main Authors: Keikhosro Karimi, Mohammad J. Taherzadeh
Format: Article
Language:English
Published: North Carolina State University 2007-01-01
Series:BioResources
Subjects:
Online Access:http://ojs.cnr.ncsu.edu/index.php/BioRes/article/viewFile/BioRes_2_3_472_499_Taherzadeh_K_AcidHydrolysis_BioEthanol/62
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author Keikhosro Karimi
Mohammad J. Taherzadeh
author_facet Keikhosro Karimi
Mohammad J. Taherzadeh
author_sort Keikhosro Karimi
collection DOAJ
description Bioethanol is nowadays one of the main actors in the fuel market. It is currently produced from sugars and starchy materials, but lignocelluloses can be expected to be major feedstocks for ethanol production in the future. Two processes are being developed in parallel for conversion of lignocelluloses to ethanol, “acid-based” and “enzyme-based” processes. The current article is dedicated to review of progress in the “acid-based-hydrolysis” process. This process was used industrially in the 1940s, during wartime, but was not economically competitive afterward. However, intensive research and development on its technology during the last three decades, in addition to the expanding ethanol market, may revive the process in large scale once again. In this paper the ethanol market, the composition of lignocellulosic materials, concentrated- and dilute-acid pretreatment and hydrolysis, plug-flow, percolation, counter-current and shrinking-bed hydrolysis reactors, fermentation of hexoses and pentoses, effects of fermentation inhibitors, downstream processing, wastewater treatment, analytical methods used, and the current commercial status of the acid-based ethanol processes are reviewed.
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spelling doaj.art-8d208c5ed3a64dc6bfec3325513ca16a2022-12-21T22:51:15ZengNorth Carolina State UniversityBioResources1930-21262007-01-0123472499Acid-based hydrolysis processes for ethanol from lignocellulosic materials: A reviewKeikhosro KarimiMohammad J. TaherzadehBioethanol is nowadays one of the main actors in the fuel market. It is currently produced from sugars and starchy materials, but lignocelluloses can be expected to be major feedstocks for ethanol production in the future. Two processes are being developed in parallel for conversion of lignocelluloses to ethanol, “acid-based” and “enzyme-based” processes. The current article is dedicated to review of progress in the “acid-based-hydrolysis” process. This process was used industrially in the 1940s, during wartime, but was not economically competitive afterward. However, intensive research and development on its technology during the last three decades, in addition to the expanding ethanol market, may revive the process in large scale once again. In this paper the ethanol market, the composition of lignocellulosic materials, concentrated- and dilute-acid pretreatment and hydrolysis, plug-flow, percolation, counter-current and shrinking-bed hydrolysis reactors, fermentation of hexoses and pentoses, effects of fermentation inhibitors, downstream processing, wastewater treatment, analytical methods used, and the current commercial status of the acid-based ethanol processes are reviewed.http://ojs.cnr.ncsu.edu/index.php/BioRes/article/viewFile/BioRes_2_3_472_499_Taherzadeh_K_AcidHydrolysis_BioEthanol/62Lignocellulosic materialsDilute-acid hydrolysisEthanolFermentation
spellingShingle Keikhosro Karimi
Mohammad J. Taherzadeh
Acid-based hydrolysis processes for ethanol from lignocellulosic materials: A review
BioResources
Lignocellulosic materials
Dilute-acid hydrolysis
Ethanol
Fermentation
title Acid-based hydrolysis processes for ethanol from lignocellulosic materials: A review
title_full Acid-based hydrolysis processes for ethanol from lignocellulosic materials: A review
title_fullStr Acid-based hydrolysis processes for ethanol from lignocellulosic materials: A review
title_full_unstemmed Acid-based hydrolysis processes for ethanol from lignocellulosic materials: A review
title_short Acid-based hydrolysis processes for ethanol from lignocellulosic materials: A review
title_sort acid based hydrolysis processes for ethanol from lignocellulosic materials a review
topic Lignocellulosic materials
Dilute-acid hydrolysis
Ethanol
Fermentation
url http://ojs.cnr.ncsu.edu/index.php/BioRes/article/viewFile/BioRes_2_3_472_499_Taherzadeh_K_AcidHydrolysis_BioEthanol/62
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