Extremely Fast and Cheap Densification of Cu<sub>2</sub>S by Induction Melting Method

The aim of this work was to obtain dense Cu<sub>2</sub>S superionic thermoelectric materials, homogeneous in terms of phase and chemical composition, using a very fast and cheap induction-melting technique. The chemical composition was investigated via scanning electron microscopy (SEM)...

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Bibliographic Details
Main Authors: Paweł Nieroda, Krzysztof Ziewiec, Juliusz Leszczyński, Paweł Rutkowski, Andrzej Koleżyński
Format: Article
Language:English
Published: MDPI AG 2021-11-01
Series:Materials
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Online Access:https://www.mdpi.com/1996-1944/14/23/7311
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Summary:The aim of this work was to obtain dense Cu<sub>2</sub>S superionic thermoelectric materials, homogeneous in terms of phase and chemical composition, using a very fast and cheap induction-melting technique. The chemical composition was investigated via scanning electron microscopy (SEM) combined with an energy-dispersive spectroscopy (EDS) method, and the phase composition was established by X-ray diffraction (XRD). The thermoelectric figure of merit <i>ZT</i> was determined on the basis of thermoelectric transport properties, i.e., Seebeck coefficient, electrical and thermal conductivity in the temperature range of 300–923 K. The obtained values of the <i>ZT</i> parameter are comparable with those obtained using the induction hot pressing (IHP) technique and about 30–45% higher in the temperature range of 773–923 K in comparison with Cu<sub>2</sub>S samples densified with the spark plasma sintering (SPS) technique.
ISSN:1996-1944