Thermal Decomposition of Methane in Capillary Tubes of Different Materials: Corundum, Titanium, Nickel, and Stainless Steel

The effect of capillary tube material on the process of thermal decomposition of methane at 1100 °C and methane supply at a rate of 2 L/h without the use of catalysts was studied. The materials used were corundum, titanium, nickel, and stainless steel. The reactor was a capillary tube, which was hea...

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Main Authors: Mikhail S. Vlaskin, Anatoly V. Grigorenko, Aleksandr O. Dudoladov, Matvey S. Galtsov-Tsientsiala, Vinod Kumar, George E. Valyano
Format: Article
Language:English
Published: MDPI AG 2023-11-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/13/23/12663
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author Mikhail S. Vlaskin
Anatoly V. Grigorenko
Aleksandr O. Dudoladov
Matvey S. Galtsov-Tsientsiala
Vinod Kumar
George E. Valyano
author_facet Mikhail S. Vlaskin
Anatoly V. Grigorenko
Aleksandr O. Dudoladov
Matvey S. Galtsov-Tsientsiala
Vinod Kumar
George E. Valyano
author_sort Mikhail S. Vlaskin
collection DOAJ
description The effect of capillary tube material on the process of thermal decomposition of methane at 1100 °C and methane supply at a rate of 2 L/h without the use of catalysts was studied. The materials used were corundum, titanium, nickel, and stainless steel. The reactor was a capillary tube, which was heated from the outside with a propane burner; the length of the heating zone was about 8 cm. It was found that the efficiency of methane decomposition decreases in a number of materials: Al<sub>2</sub>O<sub>3</sub> > Ni > Ti > stainless steel. The highest hydrogen yield (73.35 vol. %) was achieved in the experiment with a corundum tube with an inner diameter of 4 mm, and the lowest (27.75 vol. %) was achieved in the experiment with a stainless steel tube with a diameter of 6 mm. Nickel and titanium showed worse hydrogen yield results than corundum: for nickel, the volume content of hydrogen after pyrolysis was 71.27%, and for titanium, 41.51%.
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spelling doaj.art-8d5bdc8147e7404f933c62544f5335cf2023-12-08T15:11:19ZengMDPI AGApplied Sciences2076-34172023-11-0113231266310.3390/app132312663Thermal Decomposition of Methane in Capillary Tubes of Different Materials: Corundum, Titanium, Nickel, and Stainless SteelMikhail S. Vlaskin0Anatoly V. Grigorenko1Aleksandr O. Dudoladov2Matvey S. Galtsov-Tsientsiala3Vinod Kumar4George E. Valyano5Joint Institute for High Temperatures of the Russian Academy of Sciences, 13/2 Izhorskaya St., 125412 Moscow, RussiaJoint Institute for High Temperatures of the Russian Academy of Sciences, 13/2 Izhorskaya St., 125412 Moscow, RussiaJoint Institute for High Temperatures of the Russian Academy of Sciences, 13/2 Izhorskaya St., 125412 Moscow, RussiaJoint Institute for High Temperatures of the Russian Academy of Sciences, 13/2 Izhorskaya St., 125412 Moscow, RussiaAlgal Research and Bioenergy Lab., Department of Food Science & Technology, Graphic Era (Deemed to Be University), Dehradun 248007, IndiaJoint Institute for High Temperatures of the Russian Academy of Sciences, 13/2 Izhorskaya St., 125412 Moscow, RussiaThe effect of capillary tube material on the process of thermal decomposition of methane at 1100 °C and methane supply at a rate of 2 L/h without the use of catalysts was studied. The materials used were corundum, titanium, nickel, and stainless steel. The reactor was a capillary tube, which was heated from the outside with a propane burner; the length of the heating zone was about 8 cm. It was found that the efficiency of methane decomposition decreases in a number of materials: Al<sub>2</sub>O<sub>3</sub> > Ni > Ti > stainless steel. The highest hydrogen yield (73.35 vol. %) was achieved in the experiment with a corundum tube with an inner diameter of 4 mm, and the lowest (27.75 vol. %) was achieved in the experiment with a stainless steel tube with a diameter of 6 mm. Nickel and titanium showed worse hydrogen yield results than corundum: for nickel, the volume content of hydrogen after pyrolysis was 71.27%, and for titanium, 41.51%.https://www.mdpi.com/2076-3417/13/23/12663methane pyrolysisthermal decompositionlow-carbon hydrogencapillary tubescorundum tube
spellingShingle Mikhail S. Vlaskin
Anatoly V. Grigorenko
Aleksandr O. Dudoladov
Matvey S. Galtsov-Tsientsiala
Vinod Kumar
George E. Valyano
Thermal Decomposition of Methane in Capillary Tubes of Different Materials: Corundum, Titanium, Nickel, and Stainless Steel
Applied Sciences
methane pyrolysis
thermal decomposition
low-carbon hydrogen
capillary tubes
corundum tube
title Thermal Decomposition of Methane in Capillary Tubes of Different Materials: Corundum, Titanium, Nickel, and Stainless Steel
title_full Thermal Decomposition of Methane in Capillary Tubes of Different Materials: Corundum, Titanium, Nickel, and Stainless Steel
title_fullStr Thermal Decomposition of Methane in Capillary Tubes of Different Materials: Corundum, Titanium, Nickel, and Stainless Steel
title_full_unstemmed Thermal Decomposition of Methane in Capillary Tubes of Different Materials: Corundum, Titanium, Nickel, and Stainless Steel
title_short Thermal Decomposition of Methane in Capillary Tubes of Different Materials: Corundum, Titanium, Nickel, and Stainless Steel
title_sort thermal decomposition of methane in capillary tubes of different materials corundum titanium nickel and stainless steel
topic methane pyrolysis
thermal decomposition
low-carbon hydrogen
capillary tubes
corundum tube
url https://www.mdpi.com/2076-3417/13/23/12663
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