μ-Sulfido-bis{[1,1′-bis(diphenylphosphanyl)ferrocene-κ2P,P′]gold} methanol monosolvate
The gold complex in title compound, [Au2Fe(C17H14P)2S]·CH3OH, (I)·CH3OH, is closely similar to the previously reported (I)·2CHCl3, reported in the literature [Canales et al. (1996). J. Am. Chem. Soc. 118, 4839–4845]. Both crystallize in the monoclinic crystal systems but the space groups differ, P21...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2016-01-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S241431461502492X |
| _version_ | 1818352281358172160 |
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| author | Takuma Itai Tatsuhiro Kojima Takumi Konno |
| author_facet | Takuma Itai Tatsuhiro Kojima Takumi Konno |
| author_sort | Takuma Itai |
| collection | DOAJ |
| description | The gold complex in title compound, [Au2Fe(C17H14P)2S]·CH3OH, (I)·CH3OH, is closely similar to the previously reported (I)·2CHCl3, reported in the literature [Canales et al. (1996). J. Am. Chem. Soc. 118, 4839–4845]. Both crystallize in the monoclinic crystal systems but the space groups differ, P21/n for (I)·CH3OH compared to P2/n for (I)·2CHCl3. The two structures can be considered as polymorphs due to solvation differences. In (I)·CH3OH, all atoms of the methanol solvent molecule are disordered over two sets of sites with an occupancy ratio of 0.822 (12):0.178 (12). The crystal structure features O—H...S, C—H...S hydrogen bonds and C—H...π interactions that stack the complex molecules along the a-axis direction. |
| first_indexed | 2024-12-13T18:51:08Z |
| format | Article |
| id | doaj.art-8d937e67952245a588e6306455c54a37 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-13T18:51:08Z |
| publishDate | 2016-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-8d937e67952245a588e6306455c54a372022-12-21T23:34:56ZengInternational Union of CrystallographyIUCrData2414-31462016-01-0111x15249210.1107/S241431461502492Xsj4004μ-Sulfido-bis{[1,1′-bis(diphenylphosphanyl)ferrocene-κ2P,P′]gold} methanol monosolvateTakuma Itai0Tatsuhiro Kojima1Takumi Konno2Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, JapanDepartment of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, JapanDepartment of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, JapanThe gold complex in title compound, [Au2Fe(C17H14P)2S]·CH3OH, (I)·CH3OH, is closely similar to the previously reported (I)·2CHCl3, reported in the literature [Canales et al. (1996). J. Am. Chem. Soc. 118, 4839–4845]. Both crystallize in the monoclinic crystal systems but the space groups differ, P21/n for (I)·CH3OH compared to P2/n for (I)·2CHCl3. The two structures can be considered as polymorphs due to solvation differences. In (I)·CH3OH, all atoms of the methanol solvent molecule are disordered over two sets of sites with an occupancy ratio of 0.822 (12):0.178 (12). The crystal structure features O—H...S, C—H...S hydrogen bonds and C—H...π interactions that stack the complex molecules along the a-axis direction.http://scripts.iucr.org/cgi-bin/paper?S241431461502492Xcrystal structuredigold(I) moleculepseudopolymorphhydrogen bondingC—H...π interactions |
| spellingShingle | Takuma Itai Tatsuhiro Kojima Takumi Konno μ-Sulfido-bis{[1,1′-bis(diphenylphosphanyl)ferrocene-κ2P,P′]gold} methanol monosolvate IUCrData crystal structure digold(I) molecule pseudopolymorph hydrogen bonding C—H...π interactions |
| title | μ-Sulfido-bis{[1,1′-bis(diphenylphosphanyl)ferrocene-κ2P,P′]gold} methanol monosolvate |
| title_full | μ-Sulfido-bis{[1,1′-bis(diphenylphosphanyl)ferrocene-κ2P,P′]gold} methanol monosolvate |
| title_fullStr | μ-Sulfido-bis{[1,1′-bis(diphenylphosphanyl)ferrocene-κ2P,P′]gold} methanol monosolvate |
| title_full_unstemmed | μ-Sulfido-bis{[1,1′-bis(diphenylphosphanyl)ferrocene-κ2P,P′]gold} methanol monosolvate |
| title_short | μ-Sulfido-bis{[1,1′-bis(diphenylphosphanyl)ferrocene-κ2P,P′]gold} methanol monosolvate |
| title_sort | μ sulfido bis 1 1 bis diphenylphosphanyl ferrocene κ2p p gold methanol monosolvate |
| topic | crystal structure digold(I) molecule pseudopolymorph hydrogen bonding C—H...π interactions |
| url | http://scripts.iucr.org/cgi-bin/paper?S241431461502492X |
| work_keys_str_mv | AT takumaitai msulfidobis11bisdiphenylphosphanylferrocenek2ppgoldmethanolmonosolvate AT tatsuhirokojima msulfidobis11bisdiphenylphosphanylferrocenek2ppgoldmethanolmonosolvate AT takumikonno msulfidobis11bisdiphenylphosphanylferrocenek2ppgoldmethanolmonosolvate |