[2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ3N,N′,O]dichloridocopper(II)
In the title complex, [CuCl2(C24H24N2O2)], the CuII cation is N,N′,O-chelated by a 2,2′-(1,1′-binaphthyl-2,2′-diyldiimino)diethanol ligand and coordinated by two chloride anions in a distorted square-pyramidal geometry. In the diethanol ligand,...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-12-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811049828 |
| _version_ | 1819294244596088832 |
|---|---|
| author | Wan-Yun Huang Dong-Cheng Liu Han-Chang Wei Fu-Pei Liang |
| author_facet | Wan-Yun Huang Dong-Cheng Liu Han-Chang Wei Fu-Pei Liang |
| author_sort | Wan-Yun Huang |
| collection | DOAJ |
| description | In the title complex, [CuCl2(C24H24N2O2)], the CuII cation is N,N′,O-chelated by a 2,2′-(1,1′-binaphthyl-2,2′-diyldiimino)diethanol ligand and coordinated by two chloride anions in a distorted square-pyramidal geometry. In the diethanol ligand, the two naphthalene ring systems are twisted with respect to each other at a dihedral angle of 68.30 (9)°. The uncoordinated hydroxy group links with a coordinated chloride anion via an intramolecular O—H...Cl hydrogen bond. Intermolecular N—H...O and N—H...Cl hydrogen bonds occur in the crystal structure. |
| first_indexed | 2024-12-24T04:23:15Z |
| format | Article |
| id | doaj.art-8db13e865bb749de99f1abe72b042e40 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T04:23:15Z |
| publishDate | 2011-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-8db13e865bb749de99f1abe72b042e402022-12-21T17:15:43ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-12-016712m1844m184410.1107/S1600536811049828[2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ3N,N′,O]dichloridocopper(II)Wan-Yun HuangDong-Cheng LiuHan-Chang WeiFu-Pei LiangIn the title complex, [CuCl2(C24H24N2O2)], the CuII cation is N,N′,O-chelated by a 2,2′-(1,1′-binaphthyl-2,2′-diyldiimino)diethanol ligand and coordinated by two chloride anions in a distorted square-pyramidal geometry. In the diethanol ligand, the two naphthalene ring systems are twisted with respect to each other at a dihedral angle of 68.30 (9)°. The uncoordinated hydroxy group links with a coordinated chloride anion via an intramolecular O—H...Cl hydrogen bond. Intermolecular N—H...O and N—H...Cl hydrogen bonds occur in the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536811049828 |
| spellingShingle | Wan-Yun Huang Dong-Cheng Liu Han-Chang Wei Fu-Pei Liang [2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ3N,N′,O]dichloridocopper(II) Acta Crystallographica Section E |
| title | [2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ3N,N′,O]dichloridocopper(II) |
| title_full | [2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ3N,N′,O]dichloridocopper(II) |
| title_fullStr | [2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ3N,N′,O]dichloridocopper(II) |
| title_full_unstemmed | [2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ3N,N′,O]dichloridocopper(II) |
| title_short | [2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ3N,N′,O]dichloridocopper(II) |
| title_sort | 2 2 amp 8242 1 1 amp 8242 binaphthyl 2 2 amp 8242 diyldiimino diethanol amp 954 3n n amp 8242 o dichloridocopper ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811049828 |
| work_keys_str_mv | AT wanyunhuang 22amp824211amp8242binaphthyl22amp8242diyldiiminodiethanolamp9543nnamp8242odichloridocopperii AT dongchengliu 22amp824211amp8242binaphthyl22amp8242diyldiiminodiethanolamp9543nnamp8242odichloridocopperii AT hanchangwei 22amp824211amp8242binaphthyl22amp8242diyldiiminodiethanolamp9543nnamp8242odichloridocopperii AT fupeiliang 22amp824211amp8242binaphthyl22amp8242diyldiiminodiethanolamp9543nnamp8242odichloridocopperii |