Poly[guanidinium [tri-μ-formato-κ6O:O′-formato-κ2O,O′-yttrium(III)]]
In the title coordination polymer, {(CH6N3)[Y(CHO2)4]}n, the yttrium(III) ion is coordinated by one O,O-bidentate formate ion and six μ2 bridging formate ions, generating a square-antiprismatic YO8 coordination polyhedron. The bridging formate ions connect the metal ions into an anionic, three-dimen...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814013440 |
| _version_ | 1819290554777731072 |
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| author | Mark A. Rodriguez Dorina F. Sava Gallis Tina M. Nenoff |
| author_facet | Mark A. Rodriguez Dorina F. Sava Gallis Tina M. Nenoff |
| author_sort | Mark A. Rodriguez |
| collection | DOAJ |
| description | In the title coordination polymer, {(CH6N3)[Y(CHO2)4]}n, the yttrium(III) ion is coordinated by one O,O-bidentate formate ion and six μ2 bridging formate ions, generating a square-antiprismatic YO8 coordination polyhedron. The bridging formate ions connect the metal ions into an anionic, three-dimensional network. Charge compensation is provided by guanidinium ions, which interact with the framework by way of N—H...O hydrogen bonds. The guanidine molecules reside in porous channels of 3.612 by 8.189 Å, when considering the van der Waals radii of the nearest atoms (looking down the a-axis). |
| first_indexed | 2024-12-24T03:24:36Z |
| format | Article |
| id | doaj.art-8dc0ea6d802d4d659b38968fcfc058ab |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:24:36Z |
| publishDate | 2014-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-8dc0ea6d802d4d659b38968fcfc058ab2022-12-21T17:17:22ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-07-01707m261m26210.1107/S1600536814013440bv2234Poly[guanidinium [tri-μ-formato-κ6O:O′-formato-κ2O,O′-yttrium(III)]]Mark A. Rodriguez0Dorina F. Sava Gallis1Tina M. Nenoff2PO Box 5800, MS 1411, Sandia National Laboratories, Albuquerque, NM 87185-1411, USAPO Box 5800, MS 1411, Sandia National Laboratories, Albuquerque, NM 87185-1411, USAPO Box 5800, MS 1411, Sandia National Laboratories, Albuquerque, NM 87185-1411, USAIn the title coordination polymer, {(CH6N3)[Y(CHO2)4]}n, the yttrium(III) ion is coordinated by one O,O-bidentate formate ion and six μ2 bridging formate ions, generating a square-antiprismatic YO8 coordination polyhedron. The bridging formate ions connect the metal ions into an anionic, three-dimensional network. Charge compensation is provided by guanidinium ions, which interact with the framework by way of N—H...O hydrogen bonds. The guanidine molecules reside in porous channels of 3.612 by 8.189 Å, when considering the van der Waals radii of the nearest atoms (looking down the a-axis).http://scripts.iucr.org/cgi-bin/paper?S1600536814013440 |
| spellingShingle | Mark A. Rodriguez Dorina F. Sava Gallis Tina M. Nenoff Poly[guanidinium [tri-μ-formato-κ6O:O′-formato-κ2O,O′-yttrium(III)]] Acta Crystallographica Section E |
| title | Poly[guanidinium [tri-μ-formato-κ6O:O′-formato-κ2O,O′-yttrium(III)]] |
| title_full | Poly[guanidinium [tri-μ-formato-κ6O:O′-formato-κ2O,O′-yttrium(III)]] |
| title_fullStr | Poly[guanidinium [tri-μ-formato-κ6O:O′-formato-κ2O,O′-yttrium(III)]] |
| title_full_unstemmed | Poly[guanidinium [tri-μ-formato-κ6O:O′-formato-κ2O,O′-yttrium(III)]] |
| title_short | Poly[guanidinium [tri-μ-formato-κ6O:O′-formato-κ2O,O′-yttrium(III)]] |
| title_sort | poly guanidinium tri μ formato κ6o o formato κ2o o yttrium iii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536814013440 |
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