Advanced and Functional Structured Ceramics: MgF<sub>2</sub> and ZnS

Due to difficulties in obtaining monomaterials, intensive research into the properties of ceramic compositions has been undertaken, along with developments to the properties of the compositions. These are not inferior to monomeric structures for a number of basic parameters. Among the different type...

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Main Authors: Natalia Kamanina, Andrey Toikka, Yaroslav Barnash, Pavel Kuzhakov, Dmitry Kvashnin
Format: Article
Language:English
Published: MDPI AG 2022-07-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/15/14/4780
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author Natalia Kamanina
Andrey Toikka
Yaroslav Barnash
Pavel Kuzhakov
Dmitry Kvashnin
author_facet Natalia Kamanina
Andrey Toikka
Yaroslav Barnash
Pavel Kuzhakov
Dmitry Kvashnin
author_sort Natalia Kamanina
collection DOAJ
description Due to difficulties in obtaining monomaterials, intensive research into the properties of ceramic compositions has been undertaken, along with developments to the properties of the compositions. These are not inferior to monomeric structures for a number of basic parameters. Among the different types of ceramics, magnesium fluoride and zinc sulfide occupy a special place due to their unique properties and specific applications. In this paper, we studied functional optoelectronics and modulating technique elements based on the advanced ceramics MgF<sub>2</sub> and ZnS. The results of the transmittance spectral parameters and the contact angle estimation as well as an AFM analysis of the studied ceramics, both pure and structured with carbon nanotubes, are presented. We observed that the main characteristics of the studied materials with a surface modified by carbon nanotubes could be significantly changed when an innovative laser-oriented deposition method was applied. This method permitted the CNTs to be deposited in a vertical position on the material surface. The main features of the carbon nanotubes—such as the smaller value of the refractive index, the greater strength between the carbon atoms, and the effective surface—were taken into consideration. The analytical, quantum chemical, and experimental results of the studies of the changes in the basic physical parameters of the selected model of the inorganic matrices of the ceramics are given.
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spelling doaj.art-8dedf796ec144c5fbc12ffe23cc53ef32023-12-03T11:50:37ZengMDPI AGMaterials1996-19442022-07-011514478010.3390/ma15144780Advanced and Functional Structured Ceramics: MgF<sub>2</sub> and ZnSNatalia Kamanina0Andrey Toikka1Yaroslav Barnash2Pavel Kuzhakov3Dmitry Kvashnin4Lab for Photophysics of Media with Nanoobjects, Vavilov State Optical Institute, Kadetskaya Liniya V.O., dom 5, korp.2, 199053 St. Petersburg, RussiaLab for Photophysics of Media with Nanoobjects, Vavilov State Optical Institute, Kadetskaya Liniya V.O., dom 5, korp.2, 199053 St. Petersburg, RussiaLab for Photophysics of Media with Nanoobjects, Vavilov State Optical Institute, Kadetskaya Liniya V.O., dom 5, korp.2, 199053 St. Petersburg, RussiaLab for Photophysics of Media with Nanoobjects, Vavilov State Optical Institute, Kadetskaya Liniya V.O., dom 5, korp.2, 199053 St. Petersburg, RussiaEmanuel Institute of Biochemical Physics RAS, 4 Kosigina st., 119334 Moscow, RussiaDue to difficulties in obtaining monomaterials, intensive research into the properties of ceramic compositions has been undertaken, along with developments to the properties of the compositions. These are not inferior to monomeric structures for a number of basic parameters. Among the different types of ceramics, magnesium fluoride and zinc sulfide occupy a special place due to their unique properties and specific applications. In this paper, we studied functional optoelectronics and modulating technique elements based on the advanced ceramics MgF<sub>2</sub> and ZnS. The results of the transmittance spectral parameters and the contact angle estimation as well as an AFM analysis of the studied ceramics, both pure and structured with carbon nanotubes, are presented. We observed that the main characteristics of the studied materials with a surface modified by carbon nanotubes could be significantly changed when an innovative laser-oriented deposition method was applied. This method permitted the CNTs to be deposited in a vertical position on the material surface. The main features of the carbon nanotubes—such as the smaller value of the refractive index, the greater strength between the carbon atoms, and the effective surface—were taken into consideration. The analytical, quantum chemical, and experimental results of the studies of the changes in the basic physical parameters of the selected model of the inorganic matrices of the ceramics are given.https://www.mdpi.com/1996-1944/15/14/4780advanced structured materialsmagnesium fluoridezinc sulfidecarbon nanotubeslaser-oriented deposition technique
spellingShingle Natalia Kamanina
Andrey Toikka
Yaroslav Barnash
Pavel Kuzhakov
Dmitry Kvashnin
Advanced and Functional Structured Ceramics: MgF<sub>2</sub> and ZnS
Materials
advanced structured materials
magnesium fluoride
zinc sulfide
carbon nanotubes
laser-oriented deposition technique
title Advanced and Functional Structured Ceramics: MgF<sub>2</sub> and ZnS
title_full Advanced and Functional Structured Ceramics: MgF<sub>2</sub> and ZnS
title_fullStr Advanced and Functional Structured Ceramics: MgF<sub>2</sub> and ZnS
title_full_unstemmed Advanced and Functional Structured Ceramics: MgF<sub>2</sub> and ZnS
title_short Advanced and Functional Structured Ceramics: MgF<sub>2</sub> and ZnS
title_sort advanced and functional structured ceramics mgf sub 2 sub and zns
topic advanced structured materials
magnesium fluoride
zinc sulfide
carbon nanotubes
laser-oriented deposition technique
url https://www.mdpi.com/1996-1944/15/14/4780
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AT yaroslavbarnash advancedandfunctionalstructuredceramicsmgfsub2subandzns
AT pavelkuzhakov advancedandfunctionalstructuredceramicsmgfsub2subandzns
AT dmitrykvashnin advancedandfunctionalstructuredceramicsmgfsub2subandzns