Advanced and Functional Structured Ceramics: MgF<sub>2</sub> and ZnS
Due to difficulties in obtaining monomaterials, intensive research into the properties of ceramic compositions has been undertaken, along with developments to the properties of the compositions. These are not inferior to monomeric structures for a number of basic parameters. Among the different type...
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2022-07-01
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Online Access: | https://www.mdpi.com/1996-1944/15/14/4780 |
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author | Natalia Kamanina Andrey Toikka Yaroslav Barnash Pavel Kuzhakov Dmitry Kvashnin |
author_facet | Natalia Kamanina Andrey Toikka Yaroslav Barnash Pavel Kuzhakov Dmitry Kvashnin |
author_sort | Natalia Kamanina |
collection | DOAJ |
description | Due to difficulties in obtaining monomaterials, intensive research into the properties of ceramic compositions has been undertaken, along with developments to the properties of the compositions. These are not inferior to monomeric structures for a number of basic parameters. Among the different types of ceramics, magnesium fluoride and zinc sulfide occupy a special place due to their unique properties and specific applications. In this paper, we studied functional optoelectronics and modulating technique elements based on the advanced ceramics MgF<sub>2</sub> and ZnS. The results of the transmittance spectral parameters and the contact angle estimation as well as an AFM analysis of the studied ceramics, both pure and structured with carbon nanotubes, are presented. We observed that the main characteristics of the studied materials with a surface modified by carbon nanotubes could be significantly changed when an innovative laser-oriented deposition method was applied. This method permitted the CNTs to be deposited in a vertical position on the material surface. The main features of the carbon nanotubes—such as the smaller value of the refractive index, the greater strength between the carbon atoms, and the effective surface—were taken into consideration. The analytical, quantum chemical, and experimental results of the studies of the changes in the basic physical parameters of the selected model of the inorganic matrices of the ceramics are given. |
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format | Article |
id | doaj.art-8dedf796ec144c5fbc12ffe23cc53ef3 |
institution | Directory Open Access Journal |
issn | 1996-1944 |
language | English |
last_indexed | 2024-03-09T06:18:57Z |
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publisher | MDPI AG |
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series | Materials |
spelling | doaj.art-8dedf796ec144c5fbc12ffe23cc53ef32023-12-03T11:50:37ZengMDPI AGMaterials1996-19442022-07-011514478010.3390/ma15144780Advanced and Functional Structured Ceramics: MgF<sub>2</sub> and ZnSNatalia Kamanina0Andrey Toikka1Yaroslav Barnash2Pavel Kuzhakov3Dmitry Kvashnin4Lab for Photophysics of Media with Nanoobjects, Vavilov State Optical Institute, Kadetskaya Liniya V.O., dom 5, korp.2, 199053 St. Petersburg, RussiaLab for Photophysics of Media with Nanoobjects, Vavilov State Optical Institute, Kadetskaya Liniya V.O., dom 5, korp.2, 199053 St. Petersburg, RussiaLab for Photophysics of Media with Nanoobjects, Vavilov State Optical Institute, Kadetskaya Liniya V.O., dom 5, korp.2, 199053 St. Petersburg, RussiaLab for Photophysics of Media with Nanoobjects, Vavilov State Optical Institute, Kadetskaya Liniya V.O., dom 5, korp.2, 199053 St. Petersburg, RussiaEmanuel Institute of Biochemical Physics RAS, 4 Kosigina st., 119334 Moscow, RussiaDue to difficulties in obtaining monomaterials, intensive research into the properties of ceramic compositions has been undertaken, along with developments to the properties of the compositions. These are not inferior to monomeric structures for a number of basic parameters. Among the different types of ceramics, magnesium fluoride and zinc sulfide occupy a special place due to their unique properties and specific applications. In this paper, we studied functional optoelectronics and modulating technique elements based on the advanced ceramics MgF<sub>2</sub> and ZnS. The results of the transmittance spectral parameters and the contact angle estimation as well as an AFM analysis of the studied ceramics, both pure and structured with carbon nanotubes, are presented. We observed that the main characteristics of the studied materials with a surface modified by carbon nanotubes could be significantly changed when an innovative laser-oriented deposition method was applied. This method permitted the CNTs to be deposited in a vertical position on the material surface. The main features of the carbon nanotubes—such as the smaller value of the refractive index, the greater strength between the carbon atoms, and the effective surface—were taken into consideration. The analytical, quantum chemical, and experimental results of the studies of the changes in the basic physical parameters of the selected model of the inorganic matrices of the ceramics are given.https://www.mdpi.com/1996-1944/15/14/4780advanced structured materialsmagnesium fluoridezinc sulfidecarbon nanotubeslaser-oriented deposition technique |
spellingShingle | Natalia Kamanina Andrey Toikka Yaroslav Barnash Pavel Kuzhakov Dmitry Kvashnin Advanced and Functional Structured Ceramics: MgF<sub>2</sub> and ZnS Materials advanced structured materials magnesium fluoride zinc sulfide carbon nanotubes laser-oriented deposition technique |
title | Advanced and Functional Structured Ceramics: MgF<sub>2</sub> and ZnS |
title_full | Advanced and Functional Structured Ceramics: MgF<sub>2</sub> and ZnS |
title_fullStr | Advanced and Functional Structured Ceramics: MgF<sub>2</sub> and ZnS |
title_full_unstemmed | Advanced and Functional Structured Ceramics: MgF<sub>2</sub> and ZnS |
title_short | Advanced and Functional Structured Ceramics: MgF<sub>2</sub> and ZnS |
title_sort | advanced and functional structured ceramics mgf sub 2 sub and zns |
topic | advanced structured materials magnesium fluoride zinc sulfide carbon nanotubes laser-oriented deposition technique |
url | https://www.mdpi.com/1996-1944/15/14/4780 |
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