An electrochemical study of tin oxide thin film in borate buffer solutions

The electrochemical behavior of tin polycrystals in borate buffer solutions at pH 7.5 was systematically investigated using cyclic voltammetry, EC-STM and electrochemical impedance measurements. A systematic shift to more negative values of the potentials corresponding either to the major reduction...

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Bibliographic Details
Main Authors: Díaz Raül, Díez-Pérez Ismael, Gorostiza Pau, Sanz Fausto, Morante Joan R.
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2003-01-01
Series:Journal of the Brazilian Chemical Society
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532003000400006
Description
Summary:The electrochemical behavior of tin polycrystals in borate buffer solutions at pH 7.5 was systematically investigated using cyclic voltammetry, EC-STM and electrochemical impedance measurements. A systematic shift to more negative values of the potentials corresponding either to the major reduction peak either to the hydrogen evolution was measured when the anodization potential used for film growth was increased. A discussion about the different oxides there formed was included and a reassignation of tin oxidation and tin oxides reduction processes was given.
ISSN:0103-5053