SO<sub>2</sub> Poisoning and Recovery of Copper-Based Activated Carbon Catalysts for Selective Catalytic Reduction of NO with NH<sub>3</sub> at Low Temperature

A series of materials based on activated carbon (AC) with copper deposited in various amounts were prepared using an incipient wetness impregnation method and tested as catalysts for selective catalytic reduction of nitrogen oxides with ammonia. The samples were poisoned with SO<sub>2</sub&...

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Bibliographic Details
Main Authors: Marwa Saad, Agnieszka Szymaszek, Anna Białas, Bogdan Samojeden, Monika Motak
Format: Article
Language:English
Published: MDPI AG 2020-12-01
Series:Catalysts
Subjects:
Online Access:https://www.mdpi.com/2073-4344/10/12/1426
Description
Summary:A series of materials based on activated carbon (AC) with copper deposited in various amounts were prepared using an incipient wetness impregnation method and tested as catalysts for selective catalytic reduction of nitrogen oxides with ammonia. The samples were poisoned with SO<sub>2</sub> and regenerated in order to analyze their susceptibility to deactivation by the harmful component of exhaust gas. NO conversion over the fresh catalyst doped with 10 wt.% of Cu reached 81% of NO conversion at 140 °C and about 90% in the temperature range of 260–300 °C. The rate of poisoning with SO<sub>2</sub> was dependent on Cu loading, but in general, it lowered NO conversion due to the formation of (NH<sub>4</sub>)<sub>2</sub>SO<sub>4</sub> deposits that blocked the active sites of the catalysts. After regeneration, the catalytic activity of the materials was restored and NO conversion exceeded 70% for all of the samples.
ISSN:2073-4344