STUDY OF REACTION OF TRANS-[Pt(<sup>15</sup>NH<sub>3</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>]<sup>2+</sup> WITH N-ACETYL-L-CYSTEINE
A study of the reaction between trans-[Pt(15NH3)2(H2O)2](NO3)2 and N-acetyl-L-cysteine (H3accys) was undertaken to confirm the identity of the products formed. In alkaline solution, the platinum products observed were mononuclear species, while in acidic solution, the oligomeric products were obtain...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Department of Chemistry, Universitas Gadjah Mada
2010-06-01
|
| Series: | Indonesian Journal of Chemistry |
| Online Access: | https://jurnal.ugm.ac.id/ijc/article/view/21839 |
| _version_ | 1819009837031227392 |
|---|---|
| author | Sutopo Hadi Trevor G Appleton |
| author_facet | Sutopo Hadi Trevor G Appleton |
| author_sort | Sutopo Hadi |
| collection | DOAJ |
| description | A study of the reaction between trans-[Pt(15NH3)2(H2O)2](NO3)2 and N-acetyl-L-cysteine (H3accys) was undertaken to confirm the identity of the products formed. In alkaline solution, the platinum products observed were mononuclear species, while in acidic solution, the oligomeric products were obtained. The mass spectrometry of the reaction in alkaline solution showed a sulfur-bridged dinuclear platinum(II) species, trans-[{Pt(H2accys-S)2(15NH3)2}2((-H2accys-S)]+ giving m/z 948 and the lost of two ammines was observed.
Keywords: thiolate, oligomers, 2D NMR, mass spectrometry |
| first_indexed | 2024-12-21T01:02:42Z |
| format | Article |
| id | doaj.art-8e4605c1e0d644158dc2d0e25dbe1a23 |
| institution | Directory Open Access Journal |
| issn | 1411-9420 2460-1578 |
| language | English |
| last_indexed | 2024-12-21T01:02:42Z |
| publishDate | 2010-06-01 |
| publisher | Department of Chemistry, Universitas Gadjah Mada |
| record_format | Article |
| series | Indonesian Journal of Chemistry |
| spelling | doaj.art-8e4605c1e0d644158dc2d0e25dbe1a232022-12-21T19:21:08ZengDepartment of Chemistry, Universitas Gadjah MadaIndonesian Journal of Chemistry1411-94202460-15782010-06-0151545710.22146/ijc.2183914937STUDY OF REACTION OF TRANS-[Pt(<sup>15</sup>NH<sub>3</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>]<sup>2+</sup> WITH N-ACETYL-L-CYSTEINESutopo Hadi0Trevor G Appleton1Department of Chemistry, University of Lampung Jl. S. Brojonegoro No. 1 Bandar Lampung 35145Centre for Metals in Biology, Department of Chemistry, University of Queensland Brisbane QLD 4072A study of the reaction between trans-[Pt(15NH3)2(H2O)2](NO3)2 and N-acetyl-L-cysteine (H3accys) was undertaken to confirm the identity of the products formed. In alkaline solution, the platinum products observed were mononuclear species, while in acidic solution, the oligomeric products were obtained. The mass spectrometry of the reaction in alkaline solution showed a sulfur-bridged dinuclear platinum(II) species, trans-[{Pt(H2accys-S)2(15NH3)2}2((-H2accys-S)]+ giving m/z 948 and the lost of two ammines was observed. Keywords: thiolate, oligomers, 2D NMR, mass spectrometryhttps://jurnal.ugm.ac.id/ijc/article/view/21839 |
| spellingShingle | Sutopo Hadi Trevor G Appleton STUDY OF REACTION OF TRANS-[Pt(<sup>15</sup>NH<sub>3</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>]<sup>2+</sup> WITH N-ACETYL-L-CYSTEINE Indonesian Journal of Chemistry |
| title | STUDY OF REACTION OF TRANS-[Pt(<sup>15</sup>NH<sub>3</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>]<sup>2+</sup> WITH N-ACETYL-L-CYSTEINE |
| title_full | STUDY OF REACTION OF TRANS-[Pt(<sup>15</sup>NH<sub>3</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>]<sup>2+</sup> WITH N-ACETYL-L-CYSTEINE |
| title_fullStr | STUDY OF REACTION OF TRANS-[Pt(<sup>15</sup>NH<sub>3</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>]<sup>2+</sup> WITH N-ACETYL-L-CYSTEINE |
| title_full_unstemmed | STUDY OF REACTION OF TRANS-[Pt(<sup>15</sup>NH<sub>3</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>]<sup>2+</sup> WITH N-ACETYL-L-CYSTEINE |
| title_short | STUDY OF REACTION OF TRANS-[Pt(<sup>15</sup>NH<sub>3</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>]<sup>2+</sup> WITH N-ACETYL-L-CYSTEINE |
| title_sort | study of reaction of trans pt sup 15 sup nh sub 3 sub sub 2 sub h sub 2 sub o sub 2 sub sup 2 sup with n acetyl l cysteine |
| url | https://jurnal.ugm.ac.id/ijc/article/view/21839 |
| work_keys_str_mv | AT sutopohadi studyofreactionoftransptsup15supnhsub3subsub2subhsub2subosub2subsup2supwithnacetyllcysteine AT trevorgappleton studyofreactionoftransptsup15supnhsub3subsub2subhsub2subosub2subsup2supwithnacetyllcysteine |