Noble aluminum-pigmented metallic polymers II: Effects of inorganic filler on weld- and flow-line visibility

Aluminum flakes, inorganic filler, and Acrylonitrile–butadiene–styrene (ABS) polymer were mixed to form noble aluminum-pigmented metallic polymers. The effects of inorganic filler on weld- and flow-line visibility were investigated using field-emission scanning electron microscopy and energy-dispers...

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Main Authors: Lim Jung Seop, Kwon Kwang Yeol, Hur Kyung Beom, Cho Cheol Hee, Lee Gyoo-Chul, Cheon Si-uk, Cho Sung Hwan
Format: Article
Language:English
Published: Elsevier 2022-02-01
Series:Polymer Testing
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S0142941821003652
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author Lim Jung Seop
Kwon Kwang Yeol
Hur Kyung Beom
Cho Cheol Hee
Lee Gyoo-Chul
Cheon Si-uk
Cho Sung Hwan
author_facet Lim Jung Seop
Kwon Kwang Yeol
Hur Kyung Beom
Cho Cheol Hee
Lee Gyoo-Chul
Cheon Si-uk
Cho Sung Hwan
author_sort Lim Jung Seop
collection DOAJ
description Aluminum flakes, inorganic filler, and Acrylonitrile–butadiene–styrene (ABS) polymer were mixed to form noble aluminum-pigmented metallic polymers. The effects of inorganic filler on weld- and flow-line visibility were investigated using field-emission scanning electron microscopy and energy-dispersive X-ray spectroscopy. The aluminum flakes were poorly oriented and not uniformly distributed at both hole and gate locations. Addition of inorganic filler improved flake orientation and distribution quality. Traditional flakes have relatively flat surfaces and high surface areas that reflect light in a highly angular manner, which results in a metallic appearance which varies with viewing angle. Comparatively, light reflected from polymers containing both aluminum flakes and specific filler pigments exhibits much less angular dependence, i.e., the flop effect of traditional aluminum pigments is minimized. The loading, size, and shape of the inorganic filler particles affected weld and flow line visibility. Adding a spherical filler with narrow particle size distribution can better stabilize the orientation of aluminum flakes in flow- and weld-line regions compared with irregularly shaped filler particles. The choice of inorganic pigment type and its optimum loading strongly affect the visibility of flow and weld lines.
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spelling doaj.art-8e71d8cf6a274acdaa3f02957cea953d2022-12-21T19:48:45ZengElsevierPolymer Testing0142-94182022-02-01106107422Noble aluminum-pigmented metallic polymers II: Effects of inorganic filler on weld- and flow-line visibilityLim Jung Seop0Kwon Kwang Yeol1Hur Kyung Beom2Cho Cheol Hee3Lee Gyoo-Chul4Cheon Si-uk5Cho Sung Hwan6R&D Center, Samsung Electronics Co., Ltd, 129, Samsung-ro, Yeongtong-gu, Suwon-si, Gyeonggi-do, 16677, South Korea; Corresponding author.R&D Center, Samsung Electronics Co., Ltd, 129, Samsung-ro, Yeongtong-gu, Suwon-si, Gyeonggi-do, 16677, South KoreaR&D Center, Samsung Electronics Co., Ltd, 129, Samsung-ro, Yeongtong-gu, Suwon-si, Gyeonggi-do, 16677, South KoreaR&D Center, Samsung Electronics Co., Ltd, 129, Samsung-ro, Yeongtong-gu, Suwon-si, Gyeonggi-do, 16677, South KoreaR&D Center, Samsung Electronics Co., Ltd, 129, Samsung-ro, Yeongtong-gu, Suwon-si, Gyeonggi-do, 16677, South KoreaChemical R&D Tech Center, SamYang Corp., 730, Daedeok-daero, Yuseong-gu, Daejeon, 340055, South KoreaChemical R&D Tech Center, SamYang Corp., 730, Daedeok-daero, Yuseong-gu, Daejeon, 340055, South KoreaAluminum flakes, inorganic filler, and Acrylonitrile–butadiene–styrene (ABS) polymer were mixed to form noble aluminum-pigmented metallic polymers. The effects of inorganic filler on weld- and flow-line visibility were investigated using field-emission scanning electron microscopy and energy-dispersive X-ray spectroscopy. The aluminum flakes were poorly oriented and not uniformly distributed at both hole and gate locations. Addition of inorganic filler improved flake orientation and distribution quality. Traditional flakes have relatively flat surfaces and high surface areas that reflect light in a highly angular manner, which results in a metallic appearance which varies with viewing angle. Comparatively, light reflected from polymers containing both aluminum flakes and specific filler pigments exhibits much less angular dependence, i.e., the flop effect of traditional aluminum pigments is minimized. The loading, size, and shape of the inorganic filler particles affected weld and flow line visibility. Adding a spherical filler with narrow particle size distribution can better stabilize the orientation of aluminum flakes in flow- and weld-line regions compared with irregularly shaped filler particles. The choice of inorganic pigment type and its optimum loading strongly affect the visibility of flow and weld lines.http://www.sciencedirect.com/science/article/pii/S0142941821003652Aluminum-pigmented metallic polymerInorganic fillerWeld and flow lines
spellingShingle Lim Jung Seop
Kwon Kwang Yeol
Hur Kyung Beom
Cho Cheol Hee
Lee Gyoo-Chul
Cheon Si-uk
Cho Sung Hwan
Noble aluminum-pigmented metallic polymers II: Effects of inorganic filler on weld- and flow-line visibility
Polymer Testing
Aluminum-pigmented metallic polymer
Inorganic filler
Weld and flow lines
title Noble aluminum-pigmented metallic polymers II: Effects of inorganic filler on weld- and flow-line visibility
title_full Noble aluminum-pigmented metallic polymers II: Effects of inorganic filler on weld- and flow-line visibility
title_fullStr Noble aluminum-pigmented metallic polymers II: Effects of inorganic filler on weld- and flow-line visibility
title_full_unstemmed Noble aluminum-pigmented metallic polymers II: Effects of inorganic filler on weld- and flow-line visibility
title_short Noble aluminum-pigmented metallic polymers II: Effects of inorganic filler on weld- and flow-line visibility
title_sort noble aluminum pigmented metallic polymers ii effects of inorganic filler on weld and flow line visibility
topic Aluminum-pigmented metallic polymer
Inorganic filler
Weld and flow lines
url http://www.sciencedirect.com/science/article/pii/S0142941821003652
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