Poly[[diaquatris(μ2-4,4′-bipyridine)bis[μ2-2-(carboxylatomethylsulfanyl)nicotinato]dicobalt(II)] 1.3-hydrate]
The title complex, [Co2(C8H5NO4S)2(C10H8N2)3(H2O)2]·1.3H2O, was synthesized under hydrothermal conditions. The CoII ion is six-coordinated in a slightly distorted octahedral environment resulting from two carboxylate O atoms of two 2-carboxymethylsulfanyl nicotinate (2-CMSN2−) ani...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2013-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813015262 |
| _version_ | 1819291365017649152 |
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| author | Rui-Qin Li Xiao-Juan Wang Yun-Long Feng |
| author_facet | Rui-Qin Li Xiao-Juan Wang Yun-Long Feng |
| author_sort | Rui-Qin Li |
| collection | DOAJ |
| description | The title complex, [Co2(C8H5NO4S)2(C10H8N2)3(H2O)2]·1.3H2O, was synthesized under hydrothermal conditions. The CoII ion is six-coordinated in a slightly distorted octahedral environment resulting from two carboxylate O atoms of two 2-carboxymethylsulfanyl nicotinate (2-CMSN2−) anions, one water molecule and three N atoms of three 4,4′-bipyridine ligands, with one 4,4′-bipyridine ligand situated on a centre of inversion. Two neighboring CoII ions are linked by two anions, giving a dinuclear [Co2(2-CMSN)2] subunit with a Co...Co separation of 6.8600 (3) Å. The dinuclear subunits are joined by bridging 4,4′-bipyridine linkers, generating a three-dimensional network structure. Disordered water molecules are situated in the free space of this network. O—H...O hydrogen bonding within and between the subunits enhances the stability of the structure. |
| first_indexed | 2024-12-24T03:37:28Z |
| format | Article |
| id | doaj.art-8e776470dbfd479a802556c9cc02b7f8 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:37:28Z |
| publishDate | 2013-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-8e776470dbfd479a802556c9cc02b7f82022-12-21T17:17:00ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-07-01697m371m37110.1107/S1600536813015262Poly[[diaquatris(μ2-4,4′-bipyridine)bis[μ2-2-(carboxylatomethylsulfanyl)nicotinato]dicobalt(II)] 1.3-hydrate]Rui-Qin LiXiao-Juan WangYun-Long FengThe title complex, [Co2(C8H5NO4S)2(C10H8N2)3(H2O)2]·1.3H2O, was synthesized under hydrothermal conditions. The CoII ion is six-coordinated in a slightly distorted octahedral environment resulting from two carboxylate O atoms of two 2-carboxymethylsulfanyl nicotinate (2-CMSN2−) anions, one water molecule and three N atoms of three 4,4′-bipyridine ligands, with one 4,4′-bipyridine ligand situated on a centre of inversion. Two neighboring CoII ions are linked by two anions, giving a dinuclear [Co2(2-CMSN)2] subunit with a Co...Co separation of 6.8600 (3) Å. The dinuclear subunits are joined by bridging 4,4′-bipyridine linkers, generating a three-dimensional network structure. Disordered water molecules are situated in the free space of this network. O—H...O hydrogen bonding within and between the subunits enhances the stability of the structure.http://scripts.iucr.org/cgi-bin/paper?S1600536813015262 |
| spellingShingle | Rui-Qin Li Xiao-Juan Wang Yun-Long Feng Poly[[diaquatris(μ2-4,4′-bipyridine)bis[μ2-2-(carboxylatomethylsulfanyl)nicotinato]dicobalt(II)] 1.3-hydrate] Acta Crystallographica Section E |
| title | Poly[[diaquatris(μ2-4,4′-bipyridine)bis[μ2-2-(carboxylatomethylsulfanyl)nicotinato]dicobalt(II)] 1.3-hydrate] |
| title_full | Poly[[diaquatris(μ2-4,4′-bipyridine)bis[μ2-2-(carboxylatomethylsulfanyl)nicotinato]dicobalt(II)] 1.3-hydrate] |
| title_fullStr | Poly[[diaquatris(μ2-4,4′-bipyridine)bis[μ2-2-(carboxylatomethylsulfanyl)nicotinato]dicobalt(II)] 1.3-hydrate] |
| title_full_unstemmed | Poly[[diaquatris(μ2-4,4′-bipyridine)bis[μ2-2-(carboxylatomethylsulfanyl)nicotinato]dicobalt(II)] 1.3-hydrate] |
| title_short | Poly[[diaquatris(μ2-4,4′-bipyridine)bis[μ2-2-(carboxylatomethylsulfanyl)nicotinato]dicobalt(II)] 1.3-hydrate] |
| title_sort | poly diaquatris 956 2 4 4 8242 bipyridine bis 956 2 2 carboxylatomethylsulfanyl nicotinato dicobalt ii 1 3 hydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813015262 |
| work_keys_str_mv | AT ruiqinli polydiaquatris9562448242bipyridinebis95622carboxylatomethylsulfanylnicotinatodicobaltii13hydrate AT xiaojuanwang polydiaquatris9562448242bipyridinebis95622carboxylatomethylsulfanylnicotinatodicobaltii13hydrate AT yunlongfeng polydiaquatris9562448242bipyridinebis95622carboxylatomethylsulfanylnicotinatodicobaltii13hydrate |