Two Distinct Fractional Crystallization Mechanisms of A-Type Granites in the Nanling Range, South China: A Case Study of the Jiuyishan Complex Massif and Xianghualing Intrusive Stocks

The petrogenesis of A-type granites with different occurrences in the Nanling Range remains unclear. In this study, a case study of the Jiuyishan complex massif and Xianghualing intrusive stocks was conducted to determine this problem. The Jiuyishan complex massif is composed of four units (Jinjilin...

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Main Authors: Wenzhou Xiao, Chaoyun Liu, Kaixuan Tan, Xianzhe Duan, Kaituo Shi, Qinglin Sui, Peng Feng, Mabrouk Sami, Mohamed S. Ahmed, Feng Zi
Format: Article
Language:English
Published: MDPI AG 2023-04-01
Series:Minerals
Subjects:
Online Access:https://www.mdpi.com/2075-163X/13/5/605
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author Wenzhou Xiao
Chaoyun Liu
Kaixuan Tan
Xianzhe Duan
Kaituo Shi
Qinglin Sui
Peng Feng
Mabrouk Sami
Mohamed S. Ahmed
Feng Zi
author_facet Wenzhou Xiao
Chaoyun Liu
Kaixuan Tan
Xianzhe Duan
Kaituo Shi
Qinglin Sui
Peng Feng
Mabrouk Sami
Mohamed S. Ahmed
Feng Zi
author_sort Wenzhou Xiao
collection DOAJ
description The petrogenesis of A-type granites with different occurrences in the Nanling Range remains unclear. In this study, a case study of the Jiuyishan complex massif and Xianghualing intrusive stocks was conducted to determine this problem. The Jiuyishan complex massif is composed of four units (Jinjiling, Pangxiemu, Shaziling and Xishan). These four units have similar zircon U-Pb ages of approximately 153 Ma, with high Zr + Nb + Ce + Y contents (>350 ppm), high 10,000 Ga/Al ratios (>2.6), and a high crystallization temperature, indicating A-type affinities. They show a gradual change in lithology and geochemistry, implying a fractional crystallization process. These units also have similar εNd(t) values (−8.2 to −5.8) and zircon εHf(t) values (−7.5 to −2.2) except for the Shaziling MMEs (mafic microgranular enclaves) (−14.2 to 4.8), demonstrating their lower crustal source. However, the Shaziling unit may have contributed mantle-derived magma based on the geochemical data of its hosted MMEs. In comparison, the two Xianghualing intrusive stocks have similar geochemical features but exhibit highly evolved features (high Rb, U, Y, Ta and Nb contents and low Eu, Ba, Sr, P, Ti, Ca, Mg and Fe contents, with V-shaped REE distribution patterns). They have different zircon U-Pb ages of approximately 160 Ma and 155 Ma. The two stocks also have similar whole-rock εNd(t) values (−6.5 to −5.7) and zircon εHf(t) values (−7.6 to −2.7) and equally illustrate a lower crustal source region. Combining with their vertical zonation, they may have experienced remarkable fractional crystallization with possible assimilation processes. We propose that the Jiuyishan complex and Xianghualing stocks have two distinct fractional crystallization mechanisms during their formation. The Jiuyishan complex was formed by in situ crystal mush fractionation, while the Xianghualing stocks were formed by flowage differentiation during magma ascent or gravitational settling during magma solidification after emplacement. However, more than one mechanism affected the fractional crystallization processes of these granitic rocks.
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spelling doaj.art-8e91d40930ff4a01aa81f6eeabeac4e22023-11-18T02:35:58ZengMDPI AGMinerals2075-163X2023-04-0113560510.3390/min13050605Two Distinct Fractional Crystallization Mechanisms of A-Type Granites in the Nanling Range, South China: A Case Study of the Jiuyishan Complex Massif and Xianghualing Intrusive StocksWenzhou Xiao0Chaoyun Liu1Kaixuan Tan2Xianzhe Duan3Kaituo Shi4Qinglin Sui5Peng Feng6Mabrouk Sami7Mohamed S. Ahmed8Feng Zi9Hunan Key Laboratory of Rare Metal Minerals Exploitation and Geological Disposal of Wastes, School of Resource Environment and Safety Engineering, University of South China, Hengyang 421001, ChinaKey Laboratory of Metallogenic Prediction of Nonferrous Metals and Geological Environment Monitoring, Ministry of Education, School of Geosciences and Info-Physics, Central South University, Changsha 410083, ChinaHunan Key Laboratory of Rare Metal Minerals Exploitation and Geological Disposal of Wastes, School of Resource Environment and Safety Engineering, University of South China, Hengyang 421001, ChinaHunan Key Laboratory of Rare Metal Minerals Exploitation and Geological Disposal of Wastes, School of Resource Environment and Safety Engineering, University of South China, Hengyang 421001, ChinaHunan Key Laboratory of Rare Metal Minerals Exploitation and Geological Disposal of Wastes, School of Resource Environment and Safety Engineering, University of South China, Hengyang 421001, ChinaHunan Key Laboratory of Rare Metal Minerals Exploitation and Geological Disposal of Wastes, School of Resource Environment and Safety Engineering, University of South China, Hengyang 421001, ChinaHunan Key Laboratory of Rare Metal Minerals Exploitation and Geological Disposal of Wastes, School of Resource Environment and Safety Engineering, University of South China, Hengyang 421001, ChinaGeology Department, Faculty of Science, Minia University, El-Minia 61519, EgyptGeology and Geophysics Department, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi ArabiaSchool of Earth Sciences and Spatial Information Engineering, Hunan University of Science and Technology, Xiangtan 411201, ChinaThe petrogenesis of A-type granites with different occurrences in the Nanling Range remains unclear. In this study, a case study of the Jiuyishan complex massif and Xianghualing intrusive stocks was conducted to determine this problem. The Jiuyishan complex massif is composed of four units (Jinjiling, Pangxiemu, Shaziling and Xishan). These four units have similar zircon U-Pb ages of approximately 153 Ma, with high Zr + Nb + Ce + Y contents (>350 ppm), high 10,000 Ga/Al ratios (>2.6), and a high crystallization temperature, indicating A-type affinities. They show a gradual change in lithology and geochemistry, implying a fractional crystallization process. These units also have similar εNd(t) values (−8.2 to −5.8) and zircon εHf(t) values (−7.5 to −2.2) except for the Shaziling MMEs (mafic microgranular enclaves) (−14.2 to 4.8), demonstrating their lower crustal source. However, the Shaziling unit may have contributed mantle-derived magma based on the geochemical data of its hosted MMEs. In comparison, the two Xianghualing intrusive stocks have similar geochemical features but exhibit highly evolved features (high Rb, U, Y, Ta and Nb contents and low Eu, Ba, Sr, P, Ti, Ca, Mg and Fe contents, with V-shaped REE distribution patterns). They have different zircon U-Pb ages of approximately 160 Ma and 155 Ma. The two stocks also have similar whole-rock εNd(t) values (−6.5 to −5.7) and zircon εHf(t) values (−7.6 to −2.7) and equally illustrate a lower crustal source region. Combining with their vertical zonation, they may have experienced remarkable fractional crystallization with possible assimilation processes. We propose that the Jiuyishan complex and Xianghualing stocks have two distinct fractional crystallization mechanisms during their formation. The Jiuyishan complex was formed by in situ crystal mush fractionation, while the Xianghualing stocks were formed by flowage differentiation during magma ascent or gravitational settling during magma solidification after emplacement. However, more than one mechanism affected the fractional crystallization processes of these granitic rocks.https://www.mdpi.com/2075-163X/13/5/605JiuyishanXianghualingA-type granitecomplex massifintrusive stocksfractional crystallization mechanisms
spellingShingle Wenzhou Xiao
Chaoyun Liu
Kaixuan Tan
Xianzhe Duan
Kaituo Shi
Qinglin Sui
Peng Feng
Mabrouk Sami
Mohamed S. Ahmed
Feng Zi
Two Distinct Fractional Crystallization Mechanisms of A-Type Granites in the Nanling Range, South China: A Case Study of the Jiuyishan Complex Massif and Xianghualing Intrusive Stocks
Minerals
Jiuyishan
Xianghualing
A-type granite
complex massif
intrusive stocks
fractional crystallization mechanisms
title Two Distinct Fractional Crystallization Mechanisms of A-Type Granites in the Nanling Range, South China: A Case Study of the Jiuyishan Complex Massif and Xianghualing Intrusive Stocks
title_full Two Distinct Fractional Crystallization Mechanisms of A-Type Granites in the Nanling Range, South China: A Case Study of the Jiuyishan Complex Massif and Xianghualing Intrusive Stocks
title_fullStr Two Distinct Fractional Crystallization Mechanisms of A-Type Granites in the Nanling Range, South China: A Case Study of the Jiuyishan Complex Massif and Xianghualing Intrusive Stocks
title_full_unstemmed Two Distinct Fractional Crystallization Mechanisms of A-Type Granites in the Nanling Range, South China: A Case Study of the Jiuyishan Complex Massif and Xianghualing Intrusive Stocks
title_short Two Distinct Fractional Crystallization Mechanisms of A-Type Granites in the Nanling Range, South China: A Case Study of the Jiuyishan Complex Massif and Xianghualing Intrusive Stocks
title_sort two distinct fractional crystallization mechanisms of a type granites in the nanling range south china a case study of the jiuyishan complex massif and xianghualing intrusive stocks
topic Jiuyishan
Xianghualing
A-type granite
complex massif
intrusive stocks
fractional crystallization mechanisms
url https://www.mdpi.com/2075-163X/13/5/605
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