Preparation and Characterization of Nanoparticle-Doped Polymer Inclusion Membranes. Application to the Removal of Arsenate and Phosphate from Waters
Nanoparticle-doped polymer inclusion membranes (NP-PIMs) have been prepared and characterized as new materials for the removal of arsenate and phosphate from waters. PIMs are made of a polymer, cellulose triacetate (CTA), and an extractant, which interacts with the compound of interest. We have used...
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MDPI AG
2021-02-01
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| Series: | Materials |
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| Online Access: | https://www.mdpi.com/1996-1944/14/4/878 |
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| author | Enriqueta Anticó Ruben Vera Francisco Vázquez Clàudia Fontàs Changyong Lu Josep Ros |
| author_facet | Enriqueta Anticó Ruben Vera Francisco Vázquez Clàudia Fontàs Changyong Lu Josep Ros |
| author_sort | Enriqueta Anticó |
| collection | DOAJ |
| description | Nanoparticle-doped polymer inclusion membranes (NP-PIMs) have been prepared and characterized as new materials for the removal of arsenate and phosphate from waters. PIMs are made of a polymer, cellulose triacetate (CTA), and an extractant, which interacts with the compound of interest. We have used the ionic liquid (IL) trioctylmethylammonium chloride (Aliquat 336) as the extractant and have investigated how the addition of nanoparticles can modify membrane properties. To this end, inorganic nanoparticles, such as ferrite (Fe<sub>3</sub>O<sub>4</sub>), SiO<sub>2</sub> and TiO<sub>2</sub>, and multiwalled carbon nanotubes (MWCNTs), were blended with the polymer/extractant mixture. Scanning electron microscopy (SEM), infrared spectroscopy (FT-IR), and contact angle measurements have been used to characterize the material. Moreover, PIM stability was checked by measuring the mass loss during the experiments. Since Aliquat 336 acts as an anion exchanger, the NP-PIMs have been explored in two different applications: (i) as sorbent materials for the extraction of arsenate and phosphate anions; (ii) as an organic phase for the separation of arsenate and phosphate in a three-phase system. The presence of oleate-coated ferrite NP in the PIM formulation represents an improvement in the efficiency of NP-PIMs used as sorbents; nevertheless, a decrease in the transport efficiency for arsenate but not for phosphate was obtained. The ease with which the NP-PIMs are prepared suggests good potential for future applications in the treatment of polluted water. Future work will address three main aspects: firstly, the implementation of the Fe<sub>3</sub>O<sub>4</sub>-PIMs for the removal of As(V) in real water containing complex matrices; secondly, the study of phosphate recovery with other cell designs that allow large volumes of contaminated water to be treated; and thirdly, the investigation of the role of MWCNTs in PIM stability. |
| first_indexed | 2024-03-09T00:55:44Z |
| format | Article |
| id | doaj.art-8edfd688da134f74a051d80419c6a71f |
| institution | Directory Open Access Journal |
| issn | 1996-1944 |
| language | English |
| last_indexed | 2024-03-09T00:55:44Z |
| publishDate | 2021-02-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Materials |
| spelling | doaj.art-8edfd688da134f74a051d80419c6a71f2023-12-11T16:54:20ZengMDPI AGMaterials1996-19442021-02-0114487810.3390/ma14040878Preparation and Characterization of Nanoparticle-Doped Polymer Inclusion Membranes. Application to the Removal of Arsenate and Phosphate from WatersEnriqueta Anticó0Ruben Vera1Francisco Vázquez2Clàudia Fontàs3Changyong Lu4Josep Ros5Departament de Química, Universitat de Girona, Campus Montilivi, 17003 Girona, SpainDepartament de Química, Universitat de Girona, Campus Montilivi, 17003 Girona, SpainDepartament de Química, Universitat de Girona, Campus Montilivi, 17003 Girona, SpainDepartament de Química, Universitat de Girona, Campus Montilivi, 17003 Girona, SpainDepartment of Plants and Environmental Sciences, University of Copenhagen, DK-1871 Frederiksberg, DenmarkDepartament de Química, Universitat Autònoma de Barcelona (UAB), 08193 Cerdanyola del Vallès, SpainNanoparticle-doped polymer inclusion membranes (NP-PIMs) have been prepared and characterized as new materials for the removal of arsenate and phosphate from waters. PIMs are made of a polymer, cellulose triacetate (CTA), and an extractant, which interacts with the compound of interest. We have used the ionic liquid (IL) trioctylmethylammonium chloride (Aliquat 336) as the extractant and have investigated how the addition of nanoparticles can modify membrane properties. To this end, inorganic nanoparticles, such as ferrite (Fe<sub>3</sub>O<sub>4</sub>), SiO<sub>2</sub> and TiO<sub>2</sub>, and multiwalled carbon nanotubes (MWCNTs), were blended with the polymer/extractant mixture. Scanning electron microscopy (SEM), infrared spectroscopy (FT-IR), and contact angle measurements have been used to characterize the material. Moreover, PIM stability was checked by measuring the mass loss during the experiments. Since Aliquat 336 acts as an anion exchanger, the NP-PIMs have been explored in two different applications: (i) as sorbent materials for the extraction of arsenate and phosphate anions; (ii) as an organic phase for the separation of arsenate and phosphate in a three-phase system. The presence of oleate-coated ferrite NP in the PIM formulation represents an improvement in the efficiency of NP-PIMs used as sorbents; nevertheless, a decrease in the transport efficiency for arsenate but not for phosphate was obtained. The ease with which the NP-PIMs are prepared suggests good potential for future applications in the treatment of polluted water. Future work will address three main aspects: firstly, the implementation of the Fe<sub>3</sub>O<sub>4</sub>-PIMs for the removal of As(V) in real water containing complex matrices; secondly, the study of phosphate recovery with other cell designs that allow large volumes of contaminated water to be treated; and thirdly, the investigation of the role of MWCNTs in PIM stability.https://www.mdpi.com/1996-1944/14/4/878polymer inclusion membranesnanoparticlesmultiwalled carbon nanotubesarsenatephosphateremoval |
| spellingShingle | Enriqueta Anticó Ruben Vera Francisco Vázquez Clàudia Fontàs Changyong Lu Josep Ros Preparation and Characterization of Nanoparticle-Doped Polymer Inclusion Membranes. Application to the Removal of Arsenate and Phosphate from Waters Materials polymer inclusion membranes nanoparticles multiwalled carbon nanotubes arsenate phosphate removal |
| title | Preparation and Characterization of Nanoparticle-Doped Polymer Inclusion Membranes. Application to the Removal of Arsenate and Phosphate from Waters |
| title_full | Preparation and Characterization of Nanoparticle-Doped Polymer Inclusion Membranes. Application to the Removal of Arsenate and Phosphate from Waters |
| title_fullStr | Preparation and Characterization of Nanoparticle-Doped Polymer Inclusion Membranes. Application to the Removal of Arsenate and Phosphate from Waters |
| title_full_unstemmed | Preparation and Characterization of Nanoparticle-Doped Polymer Inclusion Membranes. Application to the Removal of Arsenate and Phosphate from Waters |
| title_short | Preparation and Characterization of Nanoparticle-Doped Polymer Inclusion Membranes. Application to the Removal of Arsenate and Phosphate from Waters |
| title_sort | preparation and characterization of nanoparticle doped polymer inclusion membranes application to the removal of arsenate and phosphate from waters |
| topic | polymer inclusion membranes nanoparticles multiwalled carbon nanotubes arsenate phosphate removal |
| url | https://www.mdpi.com/1996-1944/14/4/878 |
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