Non-Dissociative Gas Adsorption with Different Chemisorption Geometries on Nanoporous Surfaces
Isotherm equation is one of the important scientific bases for adsorbent selection. There are different isotherms that do not account for an adsorbate, different chemisorption geometries on the nanoporous surface. It is interesting to introduce a general isotherm, which considers different chemisorpt...
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| Format: | Article |
| Language: | English |
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Nanoscience and Nanotechnology Research Center, University of Kashan
2014-04-01
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| Series: | Journal of Nanostructures |
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| Online Access: | http://jns.kashanu.ac.ir/article_7777_ca8b146dc43c3f884c109ad442d5c8fe.pdf |
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| author | H. Bashiri S. Eris |
| author_facet | H. Bashiri S. Eris |
| author_sort | H. Bashiri |
| collection | DOAJ |
| description | Isotherm equation is one of the important scientific bases for adsorbent selection. There are different isotherms that do not account for an adsorbate, different chemisorption geometries on the nanoporous surface. It is interesting to introduce a general isotherm, which considers different chemisorption geometries of an adsorbate on nanoporous surfaces. In this study, an isotherm for non-dissociative gas adsorption on nanoporous surface was derived by classical thermodynamics. Theoretical study of thermodynamics of adsorption leads to the concept of a constant parameter a which shows the ratio of the number of occupied sites to the number of adsorbed molecules. The derived isotherm was analyzed by several experimental systems of non-dissociative gas adsorption on nanoporous surfaces. By using experimental data, a comparison between the derived isotherm with some famous isotherms like Langmuir, Sips, Toth and Frumkin was provided. |
| first_indexed | 2024-04-12T13:43:08Z |
| format | Article |
| id | doaj.art-8eeffd5ebebb4e97b66fa5a3ff0e51aa |
| institution | Directory Open Access Journal |
| issn | 2251-7871 2251-788X |
| language | English |
| last_indexed | 2024-04-12T13:43:08Z |
| publishDate | 2014-04-01 |
| publisher | Nanoscience and Nanotechnology Research Center, University of Kashan |
| record_format | Article |
| series | Journal of Nanostructures |
| spelling | doaj.art-8eeffd5ebebb4e97b66fa5a3ff0e51aa2022-12-22T03:30:47ZengNanoscience and Nanotechnology Research Center, University of KashanJournal of Nanostructures2251-78712251-788X2014-04-014212713210.7508/jns.2014.02.0017777Non-Dissociative Gas Adsorption with Different Chemisorption Geometries on Nanoporous SurfacesH. Bashiri0S. Eris1Department of Physical Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Iran.Department of Physical Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Iran.Isotherm equation is one of the important scientific bases for adsorbent selection. There are different isotherms that do not account for an adsorbate, different chemisorption geometries on the nanoporous surface. It is interesting to introduce a general isotherm, which considers different chemisorption geometries of an adsorbate on nanoporous surfaces. In this study, an isotherm for non-dissociative gas adsorption on nanoporous surface was derived by classical thermodynamics. Theoretical study of thermodynamics of adsorption leads to the concept of a constant parameter a which shows the ratio of the number of occupied sites to the number of adsorbed molecules. The derived isotherm was analyzed by several experimental systems of non-dissociative gas adsorption on nanoporous surfaces. By using experimental data, a comparison between the derived isotherm with some famous isotherms like Langmuir, Sips, Toth and Frumkin was provided.http://jns.kashanu.ac.ir/article_7777_ca8b146dc43c3f884c109ad442d5c8fe.pdfNanoporous surfaceAdsorptionIsothermSolid/gas interface |
| spellingShingle | H. Bashiri S. Eris Non-Dissociative Gas Adsorption with Different Chemisorption Geometries on Nanoporous Surfaces Journal of Nanostructures Nanoporous surface Adsorption Isotherm Solid/gas interface |
| title | Non-Dissociative Gas Adsorption with Different Chemisorption Geometries on Nanoporous Surfaces |
| title_full | Non-Dissociative Gas Adsorption with Different Chemisorption Geometries on Nanoporous Surfaces |
| title_fullStr | Non-Dissociative Gas Adsorption with Different Chemisorption Geometries on Nanoporous Surfaces |
| title_full_unstemmed | Non-Dissociative Gas Adsorption with Different Chemisorption Geometries on Nanoporous Surfaces |
| title_short | Non-Dissociative Gas Adsorption with Different Chemisorption Geometries on Nanoporous Surfaces |
| title_sort | non dissociative gas adsorption with different chemisorption geometries on nanoporous surfaces |
| topic | Nanoporous surface Adsorption Isotherm Solid/gas interface |
| url | http://jns.kashanu.ac.ir/article_7777_ca8b146dc43c3f884c109ad442d5c8fe.pdf |
| work_keys_str_mv | AT hbashiri nondissociativegasadsorptionwithdifferentchemisorptiongeometriesonnanoporoussurfaces AT seris nondissociativegasadsorptionwithdifferentchemisorptiongeometriesonnanoporoussurfaces |