Tris(ethylenediamine-κ2N,N′)cadmium hexafluoridogermanate
In the title compound, [Cd(C2H8N2)3](GeF6), the CdII atom, lying on a 32 symmetry site, is coordinated by six N atoms from three ethylenediamine (en) ligands in a distorted octahedral geometry. The Ge atom also lies on a 32 symmetry site and is coordinated by six F atoms. The en ligand has a twofold...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681200983X |
| Summary: | In the title compound, [Cd(C2H8N2)3](GeF6), the CdII atom, lying on a 32 symmetry site, is coordinated by six N atoms from three ethylenediamine (en) ligands in a distorted octahedral geometry. The Ge atom also lies on a 32 symmetry site and is coordinated by six F atoms. The en ligand has a twofold rotation axis passing through the mid-point of the C—C bond. The F atom is disordered over two sites with equal occupancy factors. In the crystal, the [Cd(en)3]2+ cations and [GeF6]2− anions are connected through N—H...F hydrogen bonds, forming a three-dimensional supramolecular network. |
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| ISSN: | 1600-5368 |